scholarly journals The catalytic and radical mechanism for ethanol oxidation to acetic acid

2019 ◽  
Vol 55 (79) ◽  
pp. 11833-11836 ◽  
Author(s):  
Sotiria Mostrou ◽  
Andreas Nagl ◽  
Marco Ranocchiari ◽  
Karin Föttinger ◽  
Jeroen A. van Bokhoven
Keyword(s):  
Acetic Acid ◽  
Liquid Phase ◽  
Ethanol Oxidation ◽  
Acid Formation ◽  
Radical Mechanism ◽  
Acid Proceeds ◽  
Acetic Acid Formation

Liquid-phase ethanol oxidation to acetic acid proceeds in two steps: catalytic ethanol oxidation and non-catalytic acetaldehyde autoxidation. The balance between the two-steps coincides in the acetic acid formation and provides information for designing selective catalysts.

Competitive C–C and C–H bond scission in the ethanol oxidation reaction on Cu(100) and the effect of an alkaline environment

2017 ◽  
Vol 19 (23) ◽  
pp. 15444-15453 ◽  
Author(s):  
Zhipeng Wu ◽  
Minhua Zhang ◽  
Haoxi Jiang ◽  
Chuan-Jian Zhong ◽  
Yifei Chen ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Acid Formation ◽  
Ethanol Oxidation Reaction ◽  
Alkaline Environment ◽  
Acetic Acid Formation ◽  
Bond Scission ◽  
Alkaline Conditions

C–C bond scission in EOR on Cu(100) will occur in CH2CO but acetic acid formation will preside under alkaline conditions.

Stereochemistry of acetic acid formation from 5-methyltetrahydrofolate by Clostridium thermoaceticum

1987 ◽  
Vol 109 (10) ◽  
pp. 3173-3174 ◽  
Author(s):  
H. Lebertz ◽  
H. Simon ◽  
L. F. Courtney ◽  
S. J. Benkovic ◽  
L. D. Zydowsky ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Acid Formation ◽  
Clostridium Thermoaceticum ◽  
Acetic Acid Formation

scholarly journals Synthesis and Characterization of Titanium Supported on High Order Nanoporous Silica and Application for Direct Oxidation of Benzene to Phenol

2009 ◽  
Vol 6 (s1) ◽  
pp. S324-S328 ◽  
Author(s):  
Alireza Badiei ◽  
Javad Gholami ◽  
Yeganeh Khaniani
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Liquid Phase ◽  
Maximum Yield ◽  
Synthesis And Characterization ◽  
Nanoporous Silica ◽  
Radical Mechanism ◽  
Direct Oxidation ◽  
Oxidation Of Benzene

Direct oxidation of benzene to phenol in liquid phase by H2O2peroxide was examined over Ti/ LUS-1 catalyst in methanol and acetic acid as solvents. The maximum yield and selectivity of the phenol produced was obtained in the presence of acetic acid. It can be attributed to the stabilization of H2O2as peroxy acetic acid species in the radical mechanism for this reaction. Acetic acid interacts with hydrogen peroxide over Ti/LUS-1 and produces acetoxy radicals.

Acetic Acid Formation by Selective Aerobic Oxidation of Aqueous Ethanol over Heterogeneous Ruthenium Catalysts

ACS Catalysis ◽  
2012 ◽  
Vol 2 (4) ◽  
pp. 604-612 ◽  
Author(s):  
Yury Y. Gorbanev ◽  
Søren Kegnæs ◽  
Christopher W. Hanning ◽  
Thomas W. Hansen ◽  
Anders Riisager
Keyword(s):  
Acetic Acid ◽  
Aqueous Ethanol ◽  
Aerobic Oxidation ◽  
Ruthenium Catalysts ◽  
Acid Formation ◽  
Acetic Acid Formation ◽  
Selective Aerobic Oxidation

Indolyl-3-acetic acid formation byAzotobacter chroococcum

1970 ◽  
Vol 32 (1-3) ◽  
pp. 250-253 ◽  
Author(s):  
Margaret E. Brown ◽  
N. Walker
Keyword(s):  
Acetic Acid ◽  
Acid Formation ◽  
Acetic Acid Formation

Unique Temperature Dependence of Acetic Acid Formation in CO2Hydrogenation on Ag-promoted Rh/SiO2Catalyst

1994 ◽  
Vol 23 (2) ◽  
pp. 263-264 ◽  
Author(s):  
Noriyuki Ikehara ◽  
Kouji Hara ◽  
Atsushi Satsuma ◽  
Tadashi Hattori ◽  
Yuichi Murakami
Keyword(s):  
Acetic Acid ◽  
Temperature Dependence ◽  
Acid Formation ◽  
Acetic Acid Formation

Relationship among lipoperoxides, jasmonates and indole-3-acetic acid formation in potato tuber after wounding

2005 ◽  
Vol 39 (6) ◽  
pp. 637-647 ◽  
Author(s):  
Massimo Reverberi ◽  
Corrado Fanelli ◽  
Slaven Zjalic ◽  
Stefania Briganti ◽  
Mauro Picardo ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Potato Tuber ◽  
Acid Formation ◽  
Acetic Acid Formation ◽  
Indole 3 Acetic Acid
Sign in / Sign up

Export Citation Format

Share Document