scholarly journals Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes

2019 ◽  
Vol 55 (66) ◽  
pp. 9849-9852
Author(s):  
Dominique Leckie ◽  
Nadia T. Stephaniuk ◽  
Ana Arauzo ◽  
Javier Campo ◽  
Jeremy M. Rawson
Keyword(s):  
Exchange Coupling ◽  
Molecular Packing ◽  
Magnetic Exchange ◽  
Metal Radical

Coordination of the dithiazolyl radical MBDTA leads to strong intramolecular metal–radical magnetic exchange but the strength of the intermolecular exchange coupling is strongly dependent on molecular packing.

Probing through-space and through-bond magnetic exchange couplings in a new benzotriazinyl radical and its metal complexes

2019 ◽  
Vol 48 (37) ◽  
pp. 14189-14200 ◽  
Author(s):  
Rajendar Nasani ◽  
Thulaseedharan Nair Sailaja Sidharth ◽  
Subhadip Roy ◽  
Arpan Mondal ◽  
Jeremy M. Rawson ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Exchange Coupling ◽  
Ferromagnetic Metal ◽  
Antiferromagnetic Exchange ◽  
Magnetic Exchange ◽  
Radical Coupling ◽  
Metal Radical

A new Blatter radical and its Zn(ii) (1), Ni(ii) (2) and Co(ii) (3) complexes were isolated. Complex 1 exhibited radical⋯radical antiferromagnetic exchange coupling, whereas complexes 2 and 3 showed ferromagnetic metal–radical coupling.

Probing the strong magnetic exchange behaviour of transition metal–radical complexes: a DFT case study

2020 ◽  
Vol 49 (14) ◽  
pp. 4539-4548 ◽  
Author(s):  
Mukesh Kumar Singh
Keyword(s):  
Transition Metal ◽  
Exchange Coupling ◽  
Structural Parameters ◽  
Fine Tuning ◽  
Magnetic Exchange ◽  
Magnetic Exchange Coupling ◽  
Exchange Behaviour ◽  
Metal Radical ◽  
The Way

Alteration of the structural parameters of metal–radical complexes may pave the way forward for fine tuning the magnetic exchange coupling value as high as >−500 cm−1 – a much sought-after parameter in the area of SMMs.

A novel and facile route to in-situ formation of composites with dual coupling interactions for considerable millimeter-wave absorption performance

2021 ◽  
Author(s):  
Chuyang Liu ◽  
Tao Jiang ◽  
Tian Gao ◽  
Guangxian Xia ◽  
Yufan Cao ◽  
...  
Keyword(s):  
Millimeter Wave ◽  
Exchange Coupling ◽  
Ferromagnetic Coupling ◽  
Soft Magnetic ◽  
Magnetic Exchange ◽  
Magnetic Exchange Coupling ◽  
Absorption Performance ◽  
In Situ Formation ◽  
Facile Route

It is well known that both hard/soft magnetic exchange-coupling and ferroelectric-ferromagnetic coupling could facilitate the microwave absorption behavior. Herein, we propose the BaZrxFe12-xO19/Fe3O4/BaZrO3 composites to integrate the advantages of the...

scholarly journals Transferrable property relationships between magnetic exchange coupling and molecular conductance

2020 ◽  
Vol 11 (42) ◽  
pp. 11425-11434
Author(s):  
Martin L. Kirk ◽  
Ranjana Dangi ◽  
Diana Habel-Rodriguez ◽  
Jing Yang ◽  
David A. Shultz ◽  
...  
Keyword(s):  
Exchange Coupling ◽  
Semiquinone Radical ◽  
Magnetic Exchange ◽  
Magnetic Exchange Coupling ◽  
Coupling Parameters ◽  
Molecular Conductance

Calculated conductance through Aun–S–Bridge–S–Aun constructs are compared to experimental magnetic exchange coupling parameters in TpCum,MeZn(SQ–Bridge–NN) complexes, where SQ = semiquinone radical and NN = nitronylnitroxide radical.

Magnetic exchange coupling in tetranuclear copper clusters of the type [Cu4(μ4O)Cl6−nBrnL4]

2001 ◽  
Vol 344 (3-4) ◽  
pp. 305-309 ◽  
Author(s):  
Roman Boča ◽  
L'ubor Dlháň ◽  
Darina Makáňová ◽  
Jerzi Mrozinski ◽  
Gregor Ondrejovič ◽  
...  
Keyword(s):  
Exchange Coupling ◽  
Magnetic Exchange ◽  
Copper Clusters ◽  
Magnetic Exchange Coupling

scholarly journals Magnetic exchange-coupling effects in asymmetric trilayer structures of MBE-grown Co/Cr/Fe

1996 ◽  
Vol 53 (17) ◽  
pp. 11613-11620 ◽  
Author(s):  
Katharina Theis-Bröhl ◽  
Rainer Scheidt ◽  
Thomas Zeidler ◽  
Frank Schreiber ◽  
Hartmut Zabel ◽  
...  
Keyword(s):  
Exchange Coupling ◽  
Coupling Effects ◽  
Magnetic Exchange ◽  
Magnetic Exchange Coupling

scholarly journals Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with UIV–E–UIV cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange

2017 ◽  
Vol 8 (9) ◽  
pp. 6207-6217 ◽  
Author(s):  
Benedict M. Gardner ◽  
David M. King ◽  
Floriana Tuna ◽  
Ashley J. Wooles ◽  
Nicholas F. Chilton ◽  
...  
Keyword(s):  
Crystal Field ◽  
Exchange Coupling ◽  
Magnetic Interactions ◽  
Magnetic Exchange ◽  
Field Effects

Analysis of UIV–E–UIV (E = S, Se, Te) complexes reveals their behaviour is due to crystal field effects and not exchange coupling.

Magnetostructural relationship for μ2-phenoxido bridged ferric dimers

2017 ◽  
Vol 46 (13) ◽  
pp. 4317-4324 ◽  
Author(s):  
Fei Yu ◽  
Zi-Heng Cao ◽  
Jing-Yuan Ge ◽  
Yi-Chen Sun ◽  
Zhong-Wen Ouyang ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Exchange Coupling ◽  
Crossover Point ◽  
Magnetic Exchange ◽  
Structural Correlation ◽  
Magnetic Exchange Coupling ◽  
Epr Measurements

The magneto-structural correlation between μ2-phenoxido bridged iron(iii) complexes are studied by structural analyses, magnetic, HF-EPR measurements, and DFT calculations. The magnetic exchange coupling is governed by the Fe–O–Fe angle and the crossover point from AF to F interactions is θ at 97.83°.

Heat-activated magnetic exchange coupling across Ge barriers and Ge/Si heterostructures

1995 ◽  
Vol 51 (11) ◽  
pp. 7303-7306 ◽  
Author(s):  
B. Briner ◽  
U. Ramsperger ◽  
M. Landolt
Keyword(s):  
Exchange Coupling ◽  
Magnetic Exchange ◽  
Magnetic Exchange Coupling
Sign in / Sign up

Export Citation Format

Share Document