A painted layer for high-rate and high-capacity solid-state lithium–metal batteries

2019 ◽  
Vol 55 (47) ◽  
pp. 6704-6707 ◽  
Author(s):  
Bin Sun ◽  
Yang Jin ◽  
Jialiang Lang ◽  
Kai Liu ◽  
Minghao Fang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
High Capacity ◽  
High Rate ◽  
Lithium Metal ◽  
Alloy Anode ◽  
Lithium Metal Batteries ◽  
Spraying Method ◽  
Painted Layer

Based on a garnet solid electrolyte, an electron/ion dual-conductive framework established by a spraying method enabled an alloy anode that realized a high-rate operation.

scholarly journals An Electron/Ion Dual‐Conductive Alloy Framework for High‐Rate and High‐Capacity Solid‐State Lithium‐Metal Batteries

2018 ◽  
Vol 31 (3) ◽  
pp. 1804815 ◽  
Author(s):  
Chunpeng Yang ◽  
Hua Xie ◽  
Weiwei Ping ◽  
Kun Fu ◽  
Boyang Liu ◽  
...  
Keyword(s):  
Solid State ◽  
High Capacity ◽  
High Rate ◽  
Lithium Metal ◽  
Lithium Metal Batteries

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

High-performance polymeric ionic liquid–silica hybrid ionogel electrolytes for lithium metal batteries

2016 ◽  
Vol 4 (36) ◽  
pp. 13822-13829 ◽  
Author(s):  
Xiaowei Li ◽  
Sijian Li ◽  
Zhengxi Zhang ◽  
Jun Huang ◽  
Li Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
High Performance ◽  
High Capacity ◽  
Electrochemical Stability ◽  
Rate Performance ◽  
Lithium Metal ◽  
Polymeric Ionic Liquid ◽  
Lithium Metal Batteries ◽  
Silica Hybrid

Hybrid ionogel electrolytes have high thermal and electrochemical stability, good ionic conductivity, and potential to suppress Li dendrite formation. Solid-state lithium metal batteries with hybrid electrolytes reveal high capacity and remarkable rate performance.

A flexible composite solid electrolyte with a highly stable interphase for dendrite-free and durable all-solid-state lithium metal batteries

2020 ◽  
Vol 8 (35) ◽  
pp. 18043-18054
Author(s):  
Dechao Zhang ◽  
Xijun Xu ◽  
Xinyue Huang ◽  
Zhicong Shi ◽  
Zhuosen Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Synergistic Effect ◽  
Electrochemical Properties ◽  
Solid Electrolyte ◽  
Lithium Metal ◽  
Inorganic Complex ◽  
Lithium Metal Batteries ◽  
Composite Solid Electrolyte ◽  
Composite Solid ◽  
Superior Electrochemical Properties

A flexible composite solid electrolyte has been successfully designed. Benefitting from the synergistic effect of the organic–inorganic complex, such PBL-CSE membrane shows superior electrochemical properties and interface stability.

Flexible hybrid solid electrolyte incorporating ligament-shaped Li6.25Al0.25La3Zr2O12 filler for all-solid-state lithium-metal batteries

2021 ◽  
Vol 366 ◽  
pp. 137348
Author(s):  
Shimelis Lemma Beshahwured ◽  
Yi-Shiuan Wu ◽  
She-huang Wu ◽  
Wen-Chen Chien ◽  
Rajan Jose ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Metastable Chloride Solid Electrolyte with High Formability for Rechargeable All-Solid-State Lithium Metal Batteries

2020 ◽  
Vol 2 (8) ◽  
pp. 880-886 ◽  
Author(s):  
Naoto Tanibata ◽  
Shuta Takimoto ◽  
Koki Nakano ◽  
Hayami Takeda ◽  
Masanobu Nakayama ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Lithium Metal ◽  
Lithium Metal Batteries

A Flexible Ceramic/Polymer Hybrid Solid Electrolyte for Solid‐State Lithium Metal Batteries

2020 ◽  
Vol 32 (17) ◽  
pp. 2000399 ◽  
Author(s):  
Kecheng Pan ◽  
Lan Zhang ◽  
Weiwei Qian ◽  
Xiangkun Wu ◽  
Kun Dong ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Lithium Metal ◽  
Polymer Hybrid ◽  
Lithium Metal Batteries

A new high-Li+-conductivity Mg-doped Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte with enhanced electrochemical performance for solid-state lithium metal batteries

2020 ◽  
Vol 8 (48) ◽  
pp. 26055-26065
Author(s):  
Yosef Nikodimos ◽  
Ljalem Hadush Abrha ◽  
Haile Hisho Weldeyohannes ◽  
Kassie Nigus Shitaw ◽  
Nigusu Tiruneh Temesgen ◽  
...  
Keyword(s):  
Solid State ◽  
Electrochemical Performance ◽  
Solid Electrolyte ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Enhanced Electrochemical Performance ◽  
Mg Doped

Compared to LAGP, an LAMGP sample shows better lithium diffusivity and improved densification, leading to better electrochemical performance.

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