Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes

Eugen Weisheim; Simon Weigel; Beate Neumann; Hans-Georg Stammler; Norbert W. Mitzel

doi:10.1039/c9cc02315a

Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes

Chemical Communications ◽

10.1039/c9cc02315a ◽

2019 ◽

Vol 55 (34) ◽

pp. 4985-4988 ◽

Cited By ~ 1

Author(s):

Eugen Weisheim ◽

Simon Weigel ◽

Beate Neumann ◽

Hans-Georg Stammler ◽

Norbert W. Mitzel

Keyword(s):

Cage Compounds ◽

Organometallic Frameworks

All-cis-1,3,5-triethynyl-1,3,5-triorganyl-1,3,5-trisilacyclohexanes offer flexible scaffolds with three concordantly oriented ethynyl groups that can be lithiated and transformed into a range of other cage-like compounds, like the trimercury cage compounds [CH2Si(R)C2HgC2(R)SiCH2]3 shown in the picture.

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An Expedient Synthesis and Screening for Antiacetylcholinesterase Activity of Piperidine Embedded Novel Pentacyclic Cage Compounds

Medicinal Chemistry ◽

10.2174/157340641002140131170054 ◽

2014 ◽

Vol 10 (2) ◽

pp. 228-236 ◽

Cited By ~ 13

Author(s):

Raju Kumar ◽

Abdulrahman Almansour ◽

Natarajan Arumugam ◽

Hasnah Osman ◽

Mohamed Ali ◽

...

Keyword(s):

Cage Compounds

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Double Porphyrin Cage Compounds

European Journal of Organic Chemistry ◽

10.1002/ejoc.202001211 ◽

2020 ◽

Vol 2020 (45) ◽

pp. 7087-7100

Author(s):

Kathleen Stout ◽

Theo P. J. Peters ◽

Mathijs F. J. Mabesoone ◽

Fabian L. L. Visschers ◽

Eline M. Meijer ◽

...

Keyword(s):

Cage Compounds

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LiEC(SiMe3)3 (E = Se, Te) as a new donor of chalcogen atoms for the generation of binary [(RxGey)Ez] cage compounds with unique structural features

Dalton Transactions ◽

10.1039/d0dt04280c ◽

2021 ◽

Vol 50 (7) ◽

pp. 2663-2670

Author(s):

Tanja Kunz ◽

Orhan Şahin ◽

Claudio Schrenk ◽

Andreas Schnepf

Keyword(s):

Structural Features ◽

Cage Compounds

LiEC(SiMe3)3 (E = Se, Te) acts as a donor of chalcogen atoms and as a substituent to give binary [(RxGey)Ez] cage compounds by the reaction with GeCl2·dioxane. These cage compounds show unique structural features within Ge/E cage compounds.

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ChemInform Abstract: Polycyclic Cage Compounds: Reagents, Substrates, and Materials for the 21st Century

ChemInform ◽

10.1002/chin.199628312 ◽

2010 ◽

Vol 27 (28) ◽

pp. no-no

Author(s):

A. P. MARCHAND

Keyword(s):

21St Century ◽

Cage Compounds ◽

Polycyclic Cage Compounds

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New Functionalized Derivatives of Sulfur- and Oxygen-Containing Hexacyclic Cage Compounds.

ChemInform ◽

10.1002/chin.200444080 ◽

2004 ◽

Vol 35 (44) ◽

Author(s):

J. Ramanski ◽

A. P. Marchand

Keyword(s):

Cage Compounds ◽

Derivatives Of

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SMALL METALLOBORON CAGE COMPOUNDS AS ANALOGUES OF METAL CLUSTERS. UNIFYING CONCEPTS OF BONDING*

Annals of the New York Academy of Sciences ◽

10.1111/j.1749-6632.1974.tb25326.x ◽

1974 ◽

Vol 239 (1) ◽

pp. 180-192 ◽

Cited By ~ 40

Author(s):

Russell N. Grimes

Keyword(s):

Metal Clusters ◽

Cage Compounds

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ChemInform Abstract: CHEMISTRY OF POLYFUNCTIONAL MOLECULES. 90. CAGE COMPOUNDS WITH ADAMANTANE-, NORADAMANTANE- AND NORTRICYCLANE-STRUCTURE CONTAINING ANTIMONY, OXYGEN, SULFUR AND SELENIUM

Chemischer Informationsdienst ◽

10.1002/chin.198546235 ◽

1985 ◽

Vol 16 (46) ◽

Author(s):

J. ELLERMANN ◽

A. VEIT

Keyword(s):

Cage Compounds

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Cation-templated cyanometallate-based supramolecular rectangular cage compounds showing dielectric transitions

Inorganic Chemistry Frontiers ◽

10.1039/c7qi00218a ◽

2017 ◽

Vol 4 (8) ◽

pp. 1304-1310 ◽

Cited By ~ 4

Author(s):

Yu-Ling Liu ◽

Wen Zhang

Keyword(s):

Monovalent Cation ◽

Cage Compounds ◽

Thermal Vibrations

Relatively small displacements or thermal vibrations of the polar guests in Cd(ii)–Co(iii) cyanometallate frameworks A2{H(CdCl2)[Co(CN)6]} (A = monovalent cation) induce dielectric transitions and relaxations.

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