Immobilization of amidase into a magnetic hierarchically porous metal–organic framework for efficient biocatalysis

2019 ◽  
Vol 55 (40) ◽  
pp. 5697-5700 ◽  
Author(s):  
Chaoping Lin ◽  
Kongliang Xu ◽  
Renchao Zheng ◽  
Yuguo Zheng

A novel core–shell magnetic hierarchically porous MOF has been designed and used for amidase immobilization, which demonstrated excellent catalytic performance.

RSC Advances ◽  
2016 ◽  
Vol 6 (99) ◽  
pp. 97399-97403 ◽  
Author(s):  
Rui Kuang ◽  
Luyi Zheng ◽  
Ethan Cottrill ◽  
Ning Pan ◽  
Yanhui Chi ◽  
...  

A hierarchical porous MOF nanocrystal, hpCuL (L = 2,4,6-tris(3,5-dicarboxylatephenylamino)-1,3,5-triazine) was prepared via a facile gel-aging process. This nanocomposite exhibits high catalytic activity and stability for the reduction of 4-nitrophenol.


2020 ◽  
Vol 581 ◽  
pp. 119281
Author(s):  
Jingwen Qiu ◽  
Xue Li ◽  
Karine Steenkeste ◽  
Nadine Barroca-Aubry ◽  
Caroline Aymes-Chodur ◽  
...  

2015 ◽  
Vol 51 (39) ◽  
pp. 8292-8295 ◽  
Author(s):  
Yu-Xiao Zhou ◽  
Yu-Zhen Chen ◽  
Lina Cao ◽  
Junling Lu ◽  
Hai-Long Jiang

A Co-based metal–organic framework undergoes pyrolysis to afford Co–CoO@N-doped porous carbon, which exhibits excellent catalytic performance toward the direct oxidation of alcohols to esters.


NANO ◽  
2018 ◽  
Vol 13 (12) ◽  
pp. 1850145 ◽  
Author(s):  
Shuquan Chang ◽  
Chengcheng Liu ◽  
Heliang Fu ◽  
Zheng Li ◽  
Xian Wu ◽  
...  

In this study, a double-solvent radiation method is proposed to prepare silver nanoparticles in the pores of metal-organic framework MIL-101(Cr). The results reveal that well-dispersed silver nanoparticles with a diameter of about 2[Formula: see text]nm were successfully fabricated in the cages of monodisperse octahedral MIL-101(Cr) with a particle size of about 400[Formula: see text]nm. The structure of MIL-101(Cr) was not destroyed during the chemical treatment and irradiation. The resulting Ag/MIL-101 exhibits excellent catalytic performance for the reduction of 4-nitrophenol. This method can be extended to prepare other single or bimetallic components inside porous materials.


2020 ◽  
Vol 49 (41) ◽  
pp. 14656-14664
Author(s):  
Hongxiao Lv ◽  
Hongtai Chen ◽  
Liming Fan ◽  
Xiutang Zhang

A robust double-walled honeycomb material {[EuIIIZnII(HPTTBA)(H2O)]·4DMF·3H2O}n with excellent catalytic performance for the chemical fixation of CO2 was presented by utilizing a ligand-directed synthetic strategy.


2018 ◽  
Vol 6 (22) ◽  
pp. 10441-10446 ◽  
Author(s):  
Zhou Yu ◽  
Yu Bai ◽  
Shimin Zhang ◽  
Yuxuan Liu ◽  
Naiqing Zhang ◽  
...  

Zn0.975Co0.025S/CoS2 embedded in N,S-codoped carbon nanotube/nanopolyhedra can be prepared from MOFs and shows excellent catalytic performance for water splitting.


2016 ◽  
Vol 45 (16) ◽  
pp. 6998-7003 ◽  
Author(s):  
Yu Cao ◽  
Zhuofu Wu ◽  
Tao Wang ◽  
Yu Xiao ◽  
Qisheng Huo ◽  
...  

Bacillus subtilislipase (BSL2) has been successfully immobilized into a Cu-BTC based hierarchically porous MOF material for the first time. The immobilized BSL2 presents high enzymatic activity and perfect reusability during the esterification reaction.


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