Light-driven catalytic hydrogenation of carbon dioxide at low-pressure by a trinuclear iridium polyhydride complex

2019 ◽  
Vol 55 (35) ◽  
pp. 5087-5090 ◽  
Author(s):  
Shoji Shitaya ◽  
Kotohiro Nomura ◽  
Akiko Inagaki

Under irradiation conditions, low-pressure and room-temperature hydrogenation of carbon dioxide (CO2) has been achieved using a trinuclear iridium hexahydride complex 1.

2014 ◽  
Vol 18 (10) ◽  
pp. 1335-1345 ◽  
Author(s):  
Xuecheng Yan ◽  
Han Guo ◽  
Dongjiang Yang ◽  
Shilun Qiu ◽  
Xiangdong Yao

1995 ◽  
Vol 21 (3) ◽  
pp. 444-450 ◽  
Author(s):  
Tetsuya Imai ◽  
Kennosuke Kuroda ◽  
Masaki Hirano ◽  
Toru Akano

1993 ◽  
Vol 19 (5) ◽  
pp. 870-877 ◽  
Author(s):  
Hidehiro Iizuka ◽  
Shinichi Ichikawa ◽  
Eiji Ando ◽  
Ryoetsu Hase

2015 ◽  
Vol 44 (14) ◽  
pp. 6560-6570 ◽  
Author(s):  
Subrata Chakraborty ◽  
Olivier Blacque ◽  
Heinz Berke

Molybdenum and tungsten amides M(NO)(CO)(PNP) {M = Mo, 3a; W, 3b; PNP = (iPr2PCH2CH2)2N} can activate CO2 at room temperature forming carbamate species M(NO)(CO)(PNP)(OCO) (M = Mo, 4a(trans); W = 4b(trans). Employing 3a,b stoichiometric hydrogenation of carbon dioxide could be demonstrated.


2014 ◽  
Vol 628 ◽  
pp. 16-19
Author(s):  
Long Zhou ◽  
Li Ping Ma ◽  
Ze Cheng Zi ◽  
Jun Ma ◽  
Jian Tao Chen

Catalyst by different carriers prepared of carbon dioxide conversion sequence is: Ni/TiO2> Ni/γ-Al2O3> Ni/MgO > Ni/SiO2. Second metal, Co, Mn, Cu, La and Ce, was significantly enhanced the activity of methanation nickel-based catalysts in the carbon dioxide methanation reaction, but second metal of Cu was bad for the activity of methanation. The 10%Ni/Al2O3 and 2.5%Ce-10%Ni/Al2O3 catalysts were characterized by TG and H2-TPR,it was revealed to Ce which is benefit for reduce NiO reduction temperature and the optimal reduction temperature of the catalysts in between 400°C and 500 °C


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