Chelate chemistry governs ion-specific stiffening of Bacillus subtilis B-1 and Azotobacter vinelandii biofilms

2020 ◽  
Vol 8 (7) ◽  
pp. 1923-1933
Author(s):  
Martin Kretschmer ◽  
Oliver Lieleg

Depending on the main polymer component of the biofilms studied, chelate complexes with metal ions can be formed that entail an increase in biofilm stiffness.

Drug Research ◽  
2021 ◽  
Author(s):  
Anuroop Kumar ◽  
Netrapal Singh ◽  
Mordhwaj Kumar ◽  
Uma Agarwal

AbstractThis article reports an amide based Chemosensor used for selective detection of divalent Cu+2 and Ni+2 ions via Fluorescence turn off. The selective sensing ability of Chemosensor was investigated in presence of different metal ions Mg2+, Ag+, Fe2+, K+, Cu2+, Ni2+, Hg2+, Pb2+, Mn2+, Pd2+, Cd2+ and Mn3+ as competitive ions. The receptor i. e. Chemosensor formed complexes with metal ions in 1:1 stoichiometric ratio. The detection limit and binding constant calculated as 1.92×10–4 and 1.4×10–4 M and 2.16×103 M−1 and 3.09×103 M−1 for Cu2+ and Ni2+ions respectively. The complexes were characterized by UV/visible, FT-IR, 13C NMR and 1H NMR spectroscopy. Further the structure and Crystallinity were calculated by P-XRD spectral analysis. The crystallinity found to be 65.27 and 67.87% respectively


Author(s):  
Meichun Chen ◽  
Meixia Zheng ◽  
Yanping Chen ◽  
Rongfeng Xiao ◽  
Xuefang Zheng ◽  
...  

1987 ◽  
Vol 65 (7) ◽  
pp. 1485-1490 ◽  
Author(s):  
M. N. Bakola-Christianopoulou ◽  
P. D. Akrivos ◽  
M. Baumgarten

Homobinuclear metal chelate complexes having 1,4-dihydroxy-9,10-anthracenedione (quinizarin) as a bridging unit have been prepared with four bivalent first row transition elements, namely cobalt, nickel, copper, and zinc. The coordination spheres of the metal ions consist of two nearly equivalent six-membered rings with oxygen donor atoms derived from the quinizarin and the terminal ligands which are either β-diketones or salicylic aldehyde. TG, spectroscopic (ir, uv–vis, epr), and magnetic measurements have been applied to an investigation of the geometry adopted by the MO4 chromophores. The results are consistent with varying degrees of distortion from the ideal square planar toward a tetrahedral arrangement around the metal ions, closely related to the specific metal center involved.


2013 ◽  
Vol 183 (3) ◽  
pp. 512-518 ◽  
Author(s):  
Balasundaresan Dhakshnamoorthy ◽  
Hiroshi Mizuno ◽  
Penmetcha K.R. Kumar

1992 ◽  
Vol 195 (1) ◽  
pp. 89-93 ◽  
Author(s):  
Istvan Lazar ◽  
Ravichandran Ramasamy ◽  
Erno Brücher ◽  
Carlos F.G.C. Geraldes ◽  
A.Dean Sherry

2015 ◽  
Vol 85 (7) ◽  
pp. 1706-1712 ◽  
Author(s):  
L. D. Popov ◽  
S. A. Borodkin ◽  
Yu. P. Tupolova ◽  
M. E. Kletskii ◽  
O. N. Burov ◽  
...  

1990 ◽  
Vol 39 (4) ◽  
pp. 307-316 ◽  
Author(s):  
Olga Markopoulou ◽  
John Markopoulos ◽  
David Nicholls

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