A low-cost microplasma generation unit allowing for the on-site processing of ZnO-based gas sensors

The Analyst ◽  
2019 ◽  
Vol 144 (22) ◽  
pp. 6653-6659
Author(s):  
Fei-Hung Huang ◽  
Sz-Yun Lin ◽  
Cheng-Che Hsu

In this study, a low-cost gas-sensing device that integrates a zinc-oxide (ZnO)-based gas sensor with a microplasma generation unit is presented.

2011 ◽  
Vol 335-336 ◽  
pp. 478-482 ◽  
Author(s):  
Xin Liang Cao

For different gas sensing, the preparation of Zinc Oxide (ZnO) thin film gas sensor has its particularity. In this paper, three kinds of preparation methods, fitting for CO and methane and CO2 sensing, are introduced. Moreover, the sensitivity is respectively analyzed as gas sensors. The reference is provided for the preparation and applications of ZnO thin film gas sensor.


Author(s):  
Priya Gupta ◽  
Savita Maurya ◽  
Narendra Kumar Pandey ◽  
Vernica Verma

: This review paper encompasses a study of metal-oxide and their composite based gas sensors used for the detection of ammonia (NH3) gas. Metal-oxide has come into view as an encouraging choice in the gas sensor industry. This review paper focuses on the ammonia sensing principle of the metal oxides. It also includes various approaches adopted for increasing the gas sensitivity of metal-oxide sensors. Increasing the sensitivity of the ammonia gas sensor includes size effects and doping by metal or other metal oxides which will change the microstructure and morphology of the metal oxides. Different parameters that affect the performances like sensitivity, stability, and selectivity of gas sensors are discussed in this paper. Performances of the most operated metal oxides with strengths and limitations in ammonia gas sensing application are reviewed. The challenges for the development of high sensitive and selective ammonia gas sensor are also discussed.


2009 ◽  
Vol 2009 ◽  
pp. 1-24 ◽  
Author(s):  
Yun Wang ◽  
John T. W. Yeow

Gas sensors have attracted intensive research interest due to the demand of sensitive, fast response, and stable sensors for industry, environmental monitoring, biomedicine, and so forth. The development of nanotechnology has created huge potential to build highly sensitive, low cost, portable sensors with low power consumption. The extremely high surface-to-volume ratio and hollow structure of nanomaterials is ideal for the adsorption of gas molecules. Particularly, the advent of carbon nanotubes (CNTs) has fuelled the inventions of gas sensors that exploit CNTs' unique geometry, morphology, and material properties. Upon exposure to certain gases, the changes in CNTs' properties can be detected by various methods. Therefore, CNTs-based gas sensors and their mechanisms have been widely studied recently. In this paper, a broad but yet in-depth survey of current CNTs-based gas sensing technology is presented. Both experimental works and theoretical simulations are reviewed. The design, fabrication, and the sensing mechanisms of the CNTs-based gas sensors are discussed. The challenges and perspectives of the research are also addressed in this review.


2013 ◽  
Vol 201 ◽  
pp. 131-158 ◽  
Author(s):  
Ravi Chand Singh ◽  
Manmeet Pal Singh ◽  
Hardev Singh Virk

Gas detection instruments are increasingly needed for industrial health and safety, environmental monitoring, and process control. To meet this demand, considerable research into new sensors is underway, including efforts to enhance the performance of traditional devices, such as resistive metal oxide sensors, through nanoengineering. The resistance of semiconductors is affected by the gaseous ambient. The semiconducting metal oxides based gas sensors exploit this phenomenon. Physical chemistry of solid metal surfaces plays a dominant role in controlling the gas sensing characteristics. Metal oxide sensors have been utilized for several decades for low-cost detection of combustible and toxic gases. Recent advances in nanomaterials provide the opportunity to dramatically increase the response of these materials, as their performance is directly related to exposed surface volume. Proper control of grain size remains a key challenge for high sensor performance. Nanoparticles of SnO2have been synthesized through chemical route at 5, 25 and 50°C. The synthesized particles were sintered at 400, 600 and 800°C and their structural and morphological analysis was carried out using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The reaction temperature is found to be playing a critical role in controlling nanostructure sizes as well as agglomeration. It has been observed that particle synthesized at 5 and 50°C are smaller and less agglomerated as compared to the particles prepared at 25°C. The studies revealed that particle size and agglomeration increases with increase in sintering temperature. Thick films gas sensors were fabricated using synthesized tin dioxide powder and sensing response of all the sensors to ethanol vapors was investigated at different temperatures and concentrations. The investigations revealed that sensing response of SnO2nanoparticles is size dependent and smaller particles display higher sensitivity. Table of Contents


2013 ◽  
Vol 431 ◽  
pp. 306-311
Author(s):  
Xiang Tao Ran ◽  
Zhi Wang ◽  
Li Yang

With the increasing needs for high-performance gas sensors in industrial production, environmental monitoring and so on, the research on gas sensors is becoming more and more important. In this paper, the electric field intensity distribution simulation process of the interdigital microelectrodes (IMEs) is discussed in details to get the proper electrode structural parameters. The IMEs on the ITO surface with a minimum gap of about 4μm are achieved by lithography, which provides a reliable, low-cost manufacturing method. Sensitive components are made of the multi-walled carbon nanotubes modified materials. The gas-sensing property of the sensor is detected for ammonia. The experiment result shows that the performance of the nanomodified sensor is obviously improved.


NANO ◽  
2014 ◽  
Vol 09 (07) ◽  
pp. 1450071 ◽  
Author(s):  
HONGWEI CHE ◽  
AIFENG LIU ◽  
XIAOLIANG ZHANG ◽  
JUNXIAN HOU ◽  
JINGBO MU ◽  
...  

In this paper, three-dimensional (3D) Co 3 O 4 flower-like microspheres have been successfully synthesized via a facile ethylene glycol (EG)-mediated solvothermal method followed by calcination. The as-prepared flower-like precursors microspheres are formed from the assembly of 2D nanosheets in the presence of hexadecyltrimethylammonium bromide (CTAB). The flower-like architectures of the prepared precursors could be tailored by changing the amount of CTAB. Furthermore, when evaluated as a gas sensor, the obtained Co 3 O 4 flower-like microspheres exhibit a good response and sensitivity toward ethanol gas, suggesting their promising potential for gas sensors application.


2015 ◽  
Vol 654 ◽  
pp. 94-98 ◽  
Author(s):  
Roman Yatskiv ◽  
María Verde ◽  
Jan Grym

Arrays of vertically well aligned ZnO nanorods (NRs) were prepared on nanostructured ZnO films using a low temperature hydrothermal method. We propose the use of the low cost, environmentally friendly electrophoretic deposition technique (EPD) as seeding procedure, which allows the obtaining of homogeneous, well oriented nanostructured ZnO thin films. ZnO nanorod arrays were covered with graphite in order to prepare graphite/ZnO NRs junctions. These nanostructured junctions showed promising current-voltage rectifying characteristics and gas sensing properties at room temperature.


2009 ◽  
Vol 1204 ◽  
Author(s):  
Paolo Bondavalli ◽  
Louis Gorintin ◽  
Pierre Legagneux ◽  
Didier Pribat ◽  
Laurent Caillier ◽  
...  

AbstractThe first paper showing the great potentiality of Carbon Nanotubes Field Effect transistors (CNTFETs) for gas sensing applications was published in 2000 [1]. It has been demonstrated that the performances of this kind of sensors are extremely interesting: a sensitivity of around 100ppt (e.g. for NO2 [2]) has been achieved in 2003 and several techniques to improve selectivity have been tested with very promising results [2]. The main issues that have not allowed, up to now, these devices to strike more largely the market of sensors, have been the lack of an industrial method to obtain low-cost devices, a demonstration of their selectivity in relevant environments and finally a deeper study on the effect of humidity and the possible solutions to reduce it. This contribution deals with CNTFETs based sensors fabricated using air-brush technique deposition on large surfaces. Compared to our last contribution [3], we have optimized the air-brush technique in order to obtain high performances transistors (Log(Ion)/Log(Ioff) ∼ 5/6) with highly reproducible characteristics : this is a key point for the industrial exploitation. We have developed a machine which allows us the dynamic deposition on heated substrates of the SWCNT solutions, improving dramatically the uniformity of the SWCNT mats. We have performed tests using different solvents that could be adapted as a function of the substrates (e.g. flexible substrates). Moreover these transistors have been achieved using different metal electrodes (patented approach [4]) in order to improve selectivity. Results of tests using NO2, NH3 with concentrations between ∼ 1ppm and 10ppm will be shown during the meeting.


Chemosensors ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 225
Author(s):  
Qingting Li ◽  
Yanqiong Li ◽  
Wen Zeng

Since MXene (a two-dimensional material) was discovered in 2011, it has been favored in all aspects due to its rich surface functional groups, large specific surface area, high conductivity, large porosity, rich organic bonds, and high hydrophilicity. In this paper, the preparation of MXene is introduced first. HF etching was the first etching method for MXene; however, HF is corrosive, resulting in the development of the in situ HF method (fluoride + HCl). Due to the harmful effects of fluorine terminal on the performance of MXene, a fluorine-free preparation method was developed. The increase in interlayer spacing brought about by adding an intercalator can affect MXene’s performance. The usual preparation methods render MXene inevitably agglomerate and the resulting yields are insufficient. Many new preparation methods were researched in order to solve the problems of agglomeration and yield. Secondly, the application of MXene-based materials in gas sensors was discussed. MXene is often regarded as a flexible gas sensor, and the detection of ppb-level acetone at room temperature was observed for the first time. After the formation of composite materials, the increasing interlayer spacing and the specific surface area increased the number of active sites of gas adsorption and the gas sensitivity performance improved. Moreover, this paper discusses the gas-sensing mechanism of MXene. The gas-sensing mechanism of metallic MXene is affected by the expansion of the lamellae and will be doped with H2O and oxygen during the etching process in order to become a p-type semiconductor. A p-n heterojunction and a Schottky barrier forms due to combinations with other semiconductors; thus, the gas sensitivities of composite materials are regulated and controlled by them. Although there are only several reports on the application of MXene materials to gas sensors, MXene and its composite materials are expected to become materials that can effectively detect gases at room temperature, especially for the detection of NH3 and VOC gas. Finally, the challenges and opportunities of MXene as a gas sensor are discussed.


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