Using ultra-fast spectroscopy to probe the excited state dynamics of a reported highly efficient thermally activated delayed fluorescence chromophore

2019 ◽  
Vol 7 (14) ◽  
pp. 4210-4221 ◽  
Author(s):  
Ricardo Javier Vázquez ◽  
Hyungjun Kim ◽  
Paul M. Zimmerman ◽  
Theodore Goodson
Keyword(s):  
Excited State ◽  
Quantum Chemical ◽  
Delayed Fluorescence ◽  
Spectroscopic Techniques ◽  
Thermally Activated Delayed Fluorescence ◽  
Excited State Dynamics ◽  
Thermally Activated ◽  
Highly Efficient

Multiple ultrafast spectroscopic techniques and quantum chemical simulations (QCS) were used to investigate the excited state dynamics of BCC-TPTA.

Highly Efficient Near‐Infrared Electrofluorescence from a Thermally‐Activated Delayed Fluorescence Molecule

2021 ◽  
Author(s):  
Umamahesh Balijapalli ◽  
Ryo Nagata ◽  
Nishiki Yamada ◽  
Hajime Nakanotani ◽  
Masaki Tanaka ◽  
...  
Keyword(s):  
Near Infrared ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient

scholarly journals Regioisomeric Effect on the Excited-State Fate Leading to Room-Temperature Phosphorescence or Thermally Activated Delayed Fluorescence in a Dibenzophenazine-Cored Donor–Acceptor–Donor System

2021 ◽  
Author(s):  
Takumi Hosono ◽  
Nicolas Oliveira Decarli ◽  
Paola Zimmermann Crocomo ◽  
Tsuyoshi Goya ◽  
Leonardo Evaristo de Sousa ◽  
...  
Keyword(s):  
Excited State ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Quantum Yields ◽  
Room Temperature Phosphorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Emission Behavior

Exploring design principle for switching thermally activated dealyed fluorescecne (TADF) and room temperature phosphorescence (RTP) is a fundamentally imporant research in developing triplet-mediated photofunctional organic materials. Herein systematic studies on the regioisomeric and substituents effects in a twisted donor–acceptor–donor (D–A–D) scaffold (A = dibenzo[a,j]phenazine; D = dihydrophenazasiline) on the fate of the excited state have been performed. The study revealed that the regiosiomerism clearly affects the emission behavior of the D–A–D compounds. Distinct difference in TADF, dual TADF & RTP, and dual RTP were observed, depending on the host used. Furthermore, OLED organic light-emitting diodes (OLEDs) fabricated with the developed emitters achieved high external quantum yields for RTP-based OLEDS up to 7.4%.

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