Above-room-temperature switching of quadratic nonlinear optical properties in a Bi–halide organic–inorganic hybrid

2018 ◽  
Vol 6 (35) ◽  
pp. 9532-9536 ◽  
Author(s):  
Zhenyue Wu ◽  
Xitao Liu ◽  
Chengmin Ji ◽  
Lina Li ◽  
Sasa Wang ◽  
...  

A lead-free Bi-based organic–inorganic hybrid shows attractive above-room-temperature NLO switching behaviors with a superior contrast of ∼35.

2018 ◽  
Vol 54 (44) ◽  
pp. 5614-5617 ◽  
Author(s):  
Jing Zhang ◽  
Shiguo Han ◽  
Xitao Liu ◽  
Zhenyue Wu ◽  
Chengmin Ji ◽  
...  

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2− polyanionic zigzag chains, which shows above-temperature switching of quadratic nonlinear optical (NLO) properties.


NANO ◽  
2013 ◽  
Vol 08 (04) ◽  
pp. 1350035
Author(s):  
TAO-YU ZHOU ◽  
HUI WANG ◽  
XIAO-PING KANG ◽  
XIN-QUAN XIN

A novel tree-like nano-cadmium sulfide (CdS) with the fractal feature is synthesized by solid-state reaction at room temperature from complex precursor with aminotrimethylenephosphonic acid (ATMP) as ligand. The obtained sample is the crystalline cubic beta cadmium sulfide. The tree is composed of nanorods with an average diameter of ca. 95 nm and a length of up to 100–650 nm. The nanorods grow in the asymmetrical "Y" shape. The amount of ATMP plays an important role in the formation of fractal structure. Nonlinear optical (NLO) measurements by the Z-scan technique exhibit that the tree-like fractal nano- CdS has the third-order nonlinear optical properties of both NLO absorption and NLO refraction with self-focusing effect and the optical limiting performance.


2018 ◽  
Vol 124 (10) ◽  
Author(s):  
Sai Pavan Prashanth Sadhu ◽  
P. W. Jaschin ◽  
Sreekanth Perumbilavil ◽  
Anitta Rose Thomas ◽  
V. Sai Muthukumar ◽  
...  

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