Self-assembly of luminescent 12-metal Zn–Ln planar nanoclusters with sensing properties towards nitro explosives

2018 ◽  
Vol 6 (31) ◽  
pp. 8513-8521 ◽  
Author(s):  
Dongmei Jiang ◽  
Xiaoping Yang ◽  
Xiaohui Zheng ◽  
Le Bo ◽  
Ting Zhu ◽  
...  

Two types of Zn–Ln nanoclusters (Ln = Nd and Sm) were constructed using one long Schiff base ligand with a naphthyl backbone, and the 12-metal Zn–Sm cluster shows interesting visible and NIR luminescence sensing of nitro explosives with high sensitivity to 1,4-DNB and TNT at the ppb level.

2019 ◽  
Vol 6 (2) ◽  
pp. 550-555 ◽  
Author(s):  
Hongfen Chen ◽  
Xiaoping Yang ◽  
Dongmei Jiang ◽  
Desmond Schipper ◽  
Richard A. Jones

A Nd(iii) nanocluster with long Schiff base ligand shows interesting NIR luminescent sensing of both metal cations and nitro explosives, and exhibits high sensitivity to Cd2+, Zn2+, Cu2+, Co2+ ions and explosive HMX at the ppm level.


2018 ◽  
Vol 42 (9) ◽  
pp. 7241-7246 ◽  
Author(s):  
Le Bo ◽  
Shiqing Wang ◽  
Desmond Schipper ◽  
Xiaoping Yang ◽  
Ting Zhu ◽  
...  

Two Zn–Ln rectangular nanoclusters [Zn8Ln4L8(OAc)8](OH)4 (Ln = Sm (1) and Nd (2)) with sizes of 9 × 19 × 28 Å were constructed using a long-chain Schiff base ligand built around a flexible (CH2)3O(CH2)2O(CH2)3 backbone, and their visible and NIR luminescence properties were determined.


2006 ◽  
Vol 2006 (1) ◽  
pp. 144-149 ◽  
Author(s):  
Violetta Patroniak ◽  
Artur R. Stefankiewicz ◽  
Jean-Marie Lehn ◽  
Maciej Kubicki ◽  
Marcin Hoffmann

2019 ◽  
Vol 7 (43) ◽  
pp. 13425-13431 ◽  
Author(s):  
Dongliang Shi ◽  
Xiaoping Yang ◽  
Hongfen Chen ◽  
Yanan Ma ◽  
Desmond Schipper ◽  
...  

Two 42-metal lanthanide nanowheels [Ln42L14(OH)28(OAc)84] (Ln = Yb (1), Sm (2)) with a NIR luminescent response towards metal ions and nitro explosives were constructed.


2017 ◽  
Vol 46 (6) ◽  
pp. 1748-1752 ◽  
Author(s):  
Shiqing Wang ◽  
Xiaoping Yang ◽  
Jinjie Qian ◽  
Qipeng Li ◽  
Zhongning Chen ◽  
...  

Two classes of magnetic Ni–Ln clusters with 7-metal cone-like and 13-metal sandwich architectures were constructed using a flexible long-chain Schiff base ligand.


RSC Advances ◽  
2021 ◽  
Vol 11 (62) ◽  
pp. 39270-39277
Author(s):  
Muhammad Asad ◽  
Ya-Jie Wang ◽  
Shan Wang ◽  
Qing-Guo Dong ◽  
Lin-Ke Li ◽  
...  

A novel H-COP was synthesized through Schiff-base condensation reaction, which shows high sensitivity (Ksv ∼ 106 M−1) and selectivity (μM level) towards nitro-explosives.


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