In situ catalytic formation of graphene-like graphitic layer decoration on Na3V2−xGax(PO4)3 (0 ≤ x ≤ 0.6) for ultrafast and high energy sodium storage

2019 ◽  
Vol 7 (9) ◽  
pp. 4660-4667 ◽  
Author(s):  
Qiao Hu ◽  
Jia-Ying Liao ◽  
Xiao-Dong He ◽  
Shuo Wang ◽  
Li-Na Xiao ◽  
...  

A series of Na3V2−xGax(PO4)3 (x = 0, 0.1, 0.2, 0.4 and 0.6) with in situ catalytic formation of graphene-like graphitic layer decoration are synthesized via a solid-state reaction process.

2020 ◽  
Vol 62 (4) ◽  
pp. 621
Author(s):  
Р.Р. Алтунин ◽  
Е.Т. Моисеенко ◽  
С.М. Жарков

Based on the study of a solid-state reaction process in Al/Ag thin films (the atomic ratio being Al:Ag=1:3) carried out by in situ electron diffraction method and electrical resistivity measurements, the reaction initiation temperature has been determined and a model of structural phase transitions occurring during the solid-state reaction has been proposed. The solid-state reaction begins at 70°C with the formation of an Al-Ag solid solution at the interface of aluminum and silver nanolayers. It has been found that in the reaction process intermetallic compounds γ-Ag2Al => µ-Ag3Al are successively formed. It has been established that for the formation of the µ-Ag3Al phase in thin films (up to 100 nm) the following is necessary: first, significant excess of silver over aluminum in the atomic composition, second, the formation of the µ-Ag3Al phase begins only after all the FCC aluminum has reacted. The work was supported by the Russian Science Foundation (grant #18-13-00080).


2021 ◽  
Vol 227 ◽  
pp. 111014
Author(s):  
Chien-Chung Hsu ◽  
Sheng-Min Yu ◽  
Kun-Mu Lee ◽  
Chuan-Jung Lin ◽  
Hao-Chien Cheng ◽  
...  

2011 ◽  
Vol 21 (15) ◽  
pp. 5604 ◽  
Author(s):  
Zonghai Chen ◽  
Yang Ren ◽  
Yan Qin ◽  
Huiming Wu ◽  
Shengqian Ma ◽  
...  

2013 ◽  
Vol 423-426 ◽  
pp. 426-429
Author(s):  
Xin Ze Wang ◽  
Zhong Xin Liu ◽  
Hong Jian Gao ◽  
Yani Jing ◽  
Chang Lin Li ◽  
...  

LiTaO3: Tm3+, Yb3+powders were synthesized by a high-energy ball-milling (HEB) method compared with the conventional solid-state reaction (SSR) method. Under the excitation of 980 nm laser, the strong blue emission (477 nm) band is observed and attributed to1G4-3H6of Tm3+. Because of it causing high local temperature and narrow particles size, increasing the contact area between the particles and improved crystallinity of the host, synthesis by high-energy ball milling show higher photoluminescence (PL) intensity compared to the solid state reaction method. In the process of mechanical milling, Tm3+, Yb3+co-doped LiTaO3phosphors with high photoluminescence property could be achieved at a relatively low reaction temperature.


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