Thermal vacuum de-oxygenation and post oxidation of TiO2 nanorod arrays for enhanced photoelectrochemical properties

2019 ◽  
Vol 7 (10) ◽  
pp. 5434-5441 ◽  
Author(s):  
Chao Huang ◽  
Juncao Bian ◽  
Yao Guo ◽  
Miaoyan Huang ◽  
Rui-Qin Zhang

Black TiO2−x NRAs fabricated using a thermal vacuum de-oxygen method yielded an almost doubled photocurrent due to the reduced band gap, lowered charge transport and transfer resistance and improved solar conversion efficiency. Post oxidation process further boosted the NRAs' PEC performance.

2016 ◽  
Vol 42 (10) ◽  
pp. 11716-11723 ◽  
Author(s):  
Jiajia Tao ◽  
Zezhou Gong ◽  
Guang Yao ◽  
Yunlang Cheng ◽  
Miao Zhang ◽  
...  

2019 ◽  
Vol 465 ◽  
pp. 192-200 ◽  
Author(s):  
Baoshun Liu ◽  
Jingjing Yang ◽  
Jiangyan Wang ◽  
Xiujian Zhao ◽  
Kazuya Nakata

2017 ◽  
Vol 41 (12) ◽  
pp. 4820-4827 ◽  
Author(s):  
Minmin Han ◽  
Hongjian Guo ◽  
Bo Li ◽  
Junhong Jia ◽  
Wenzhen Wang

Through varying the laser ablation pulses, the controlled coverage of Bi2S3 QDs on nanorods is realized and an optimal energy conversion efficiency of 3.06% is obtained under one sun illumination.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1791 ◽  
Author(s):  
Jingyang Wang ◽  
Xiantao Wang ◽  
Jun Yan ◽  
Qi Tan ◽  
Guijie Liang ◽  
...  

A novel Ti3+ self-doped branched rutile TiO2 nanorod arrays (NRAs) was successfully grown on an F-doped tin oxide (FTO) transparent conductive glass by a combined hydrothermal and magnetron sputtering method. Surface morphology, structure, optical properties, and photoelectrochemical behavior of the branched TiO2 NRAs are determined. Using TiO2 nanoparticles (NPs) deposited on the top of the nanorods as seeds, TiO2 nanobranches can easily grow on the top of the nanorods. Moreover, the Ti3+ defects in the TiO2 NPs and associated oxygen vacancies, and the nanobranches expend the optical absorption edge of the TiO2 NRAs from 400 nm to 510 nm. Branched TiO2 NRAs exhibit excellent photoelectrochemical properties compared to the pure TiO2 NRAs, as revealed by photoelectrochemical measurements. This enhanced photoelectrochemical properties is induced by the increased surface area and expanded optical absorption range. Due to their favorable characteristics, these novel branched TiO2 NRAs will provide a new path to the fabrication of hierarchical nanostructured materials.


2018 ◽  
Vol 47 (9) ◽  
pp. 5251-5258 ◽  
Author(s):  
Yulong Zhao ◽  
Xiuquan Gu ◽  
Rong He ◽  
Lei Zhu ◽  
Yinghuai Qiang

1989 ◽  
Author(s):  
James B. McNeely ◽  
Gerald H. Negley ◽  
Allen M. Barnett

2021 ◽  
Vol 56 (18) ◽  
pp. 11059-11070
Author(s):  
Xichen Yu ◽  
Qingqing Xing ◽  
Xiaoping Zhang ◽  
Hanlin Jiang ◽  
Fengren Cao

Author(s):  
Liang Zhao ◽  
Ding Chen ◽  
Shang Xu ◽  
Zhi Fang ◽  
Lin Wang ◽  
...  

Fast surface charge recombination and poor light capture capability are regarded as the two critical factors that hamper the photoelectrochemical (PEC) performance of photoanodes. In the present work, we employed...


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