Hexagonal prism arrays constructed using ultrathin porous nanoflakes of carbon doped mixed-valence Co–Mn–Fe phosphides for ultrahigh areal capacitance and remarkable cycling stability

2019 ◽  
Vol 7 (9) ◽  
pp. 4431-4437 ◽  
Author(s):  
Richao Niu ◽  
Gengjie Wang ◽  
Yuying Ding ◽  
Shaochun Tang ◽  
Xuemin Hu ◽  
...  

With novel hierarchical hexagonal prism arrays, a carbon-doped mixed-valence Co–Mn–Fe phosphide electrode shows high capacitance, rate capability and cycling stability.

Nanoscale ◽  
2020 ◽  
Vol 12 (45) ◽  
pp. 23213-23224
Author(s):  
Yue Jiao ◽  
Caichao Wan ◽  
Yiqiang Wu ◽  
Jingquan Han ◽  
Wenhui Bao ◽  
...  

A novel cathode material, composed of biomass-derived nanoporous carbon network and V2O5 sub-micron bricks, delivers a high areal capacitance of 786 mF cm−2 at 0.2 mA cm−2 and superior cycling stability.


2019 ◽  
Vol 166 (4) ◽  
pp. A658-A666 ◽  
Author(s):  
Zhenya Wang ◽  
Limei Sun ◽  
Wenyun Yang ◽  
Jinbo Yang ◽  
Kai Sun ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Shouxiang Ding ◽  
Mingzheng Zhang ◽  
Runzhi Qin ◽  
Jianjun Fang ◽  
Hengyu Ren ◽  
...  

AbstractRecent years have witnessed a booming interest in grid-scale electrochemical energy storage, where much attention has been paid to the aqueous zinc ion batteries (AZIBs). Among various cathode materials for AZIBs, manganese oxides have risen to prominence due to their high energy density and low cost. However, sluggish reaction kinetics and poor cycling stability dictate against their practical application. Herein, we demonstrate the combined use of defect engineering and interfacial optimization that can simultaneously promote rate capability and cycling stability of MnO2 cathodes. β-MnO2 with abundant oxygen vacancies (VO) and graphene oxide (GO) wrapping is synthesized, in which VO in the bulk accelerate the charge/discharge kinetics while GO on the surfaces inhibits the Mn dissolution. This electrode shows a sustained reversible capacity of ~ 129.6 mAh g−1 even after 2000 cycles at a current rate of 4C, outperforming the state-of-the-art MnO2-based cathodes. The superior performance can be rationalized by the direct interaction between surface VO and the GO coating layer, as well as the regulation of structural evolution of β-MnO2 during cycling. The combinatorial design scheme in this work offers a practical pathway for obtaining high-rate and long-life cathodes for AZIBs.


2021 ◽  
Vol 35 (5) ◽  
pp. 4570-4576
Author(s):  
Najeeb ur Rehman Lashari ◽  
Mingshu Zhao ◽  
Qingyang Zheng ◽  
Xinhai He ◽  
Irfan Ahmed ◽  
...  

2021 ◽  
pp. 2100808
Author(s):  
Bo Yin ◽  
Shuquan Liang ◽  
Dongdong Yu ◽  
Boshi Cheng ◽  
Ishioma L. Egun ◽  
...  

2021 ◽  
pp. 161885
Author(s):  
Limin Zhu ◽  
Chunliang Pan ◽  
Qing Han ◽  
Yongxia Miao ◽  
Xinli Yang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.


RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.


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