DNA-directed amphiphilic self-assembly as a chemifunctional/multiscale-structuring strategy for high-performance Li–S batteries

2019 ◽  
Vol 7 (8) ◽  
pp. 4084-4092 ◽  
Author(s):  
Seok-Kyu Cho ◽  
Sung-Ju Cho ◽  
Seong-Sun Lee ◽  
Keun-Ho Choi ◽  
Sang-Young Lee
Keyword(s):  
Self Assembly ◽  
Potential Application ◽  
High Performance ◽  
New Class

DNA-directed amphiphilic self-assembly is presented as a new class of a chemifunctional/multiscale-structuring strategy and its potential application to Li–S cathode was explored.

Self-assembled sulfur/reduced graphene oxide nanoribbon paper as a free-standing electrode for high performance lithium–sulfur batteries

2016 ◽  
Vol 52 (87) ◽  
pp. 12825-12828 ◽  
Author(s):  
Yang Liu ◽  
Xuzhen Wang ◽  
Yanfeng Dong ◽  
Yongchao Tang ◽  
Luxiang Wang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Self Assembly ◽  
Potential Application ◽  
High Performance ◽  
Free Standing ◽  
Reduced Graphene ◽  
Lithium Sulfur Batteries ◽  
Evaporation Induced Self Assembly ◽  
Lithium Sulfur

Graphene nanoribbon based paper fabricated through S2− reduction and evaporation induced self-assembly processes shows potential application in lithium–sulfur batteries.

A Bottom-Up Approach to Solution-Processed, Atomically Precise Graphitic Cylinders on Surfaces

2018 ◽  
Author(s):  
Erik Leonhardt ◽  
Jeff M. Van Raden ◽  
David Miller ◽  
Lev N. Zakharov ◽  
Benjamin Aleman ◽  
...  
Keyword(s):  
Self Assembly ◽  
Carbon Nanostructures ◽  
Carbon Nanomaterials ◽  
Circle Packing ◽  
Pyrolytic Graphite ◽  
Building Blocks ◽  
Bottom Up ◽  
Casting Technique ◽  
New Class ◽  
Solution Casting Technique

Extended carbon nanostructures, such as carbon nanotubes (CNTs), exhibit remarkable properties but are difficult to synthesize uniformly. Herein, we present a new class of carbon nanomaterials constructed via the bottom-up self-assembly of cylindrical, atomically-precise small molecules. Guided by supramolecular design principles and circle packing theory, we have designed and synthesized a fluorinated nanohoop that, in the solid-state, self-assembles into nanotube-like arrays with channel diameters of precisely 1.63 nm. A mild solution-casting technique is then used to construct vertical “forests” of these arrays on a highly-ordered pyrolytic graphite (HOPG) surface through epitaxial growth. Furthermore, we show that a basic property of nanohoops, fluorescence, is readily transferred to the bulk phase, implying that the properties of these materials can be directly altered via precise functionalization of their nanohoop building blocks. The strategy presented is expected to have broader applications in the development of new graphitic nanomaterials with π-rich cavities reminiscent of CNTs.

Interfacial self-assembly engineering for constructing a 2D flexible superlattice polyoxometalate/rGO heterojunction for high-performance photovoltaic devices

2020 ◽  
Vol 49 (12) ◽  
pp. 3766-3774 ◽  
Author(s):  
Jianping Li ◽  
Dai Wu ◽  
Chunlei Wang ◽  
Ding Liu ◽  
Weilin Chen ◽  
...  
Keyword(s):  
Conversion Efficiency ◽  
Self Assembly ◽  
High Performance ◽  
Photoelectric Conversion Efficiency ◽  
Photovoltaic Devices ◽  
Photoelectric Conversion

The strategy of constructing a 2D flexible superlattice polyoxometalate/rGO heterojunction is proposed to improve the photoelectric conversion efficiency of photovoltaic devices.

New Class of Trimetallic Oxide Hierarchical Mesoporous Array on Woven Fabric: Electrode for high-Performance and Stable battery type Ultracapacitor

2021 ◽  
Vol 35 ◽  
pp. 102249
Author(s):  
S. Thakur ◽  
S. Maiti ◽  
K. Sardar ◽  
N. Besra ◽  
P. Bairi ◽  
...  
Keyword(s):  
High Performance ◽  
Woven Fabric ◽  
New Class

Self-assembly enabled nano-intercalation for stable high-performance MXene membranes

2021 ◽  
pp. 119464
Author(s):  
Qingwu Long ◽  
Shuaifei Zhao ◽  
Jiexin Chen ◽  
Zhe Zhang ◽  
Guangxian Qi ◽  
...  
Keyword(s):  
Self Assembly ◽  
High Performance

Rational strategies for proton-conductive metal–organic frameworks

2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa
Keyword(s):  
Solid State ◽  
Potential Application ◽  
High Performance ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Solid State Electrolytes

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.

scholarly journals Environmentally Friendly, High-Performance Fire Retardant Made from Cellulose and Graphite

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2400
Author(s):  
Leandra P. Santos ◽  
Douglas S. da Silva ◽  
Thais H. Morari ◽  
Fernando Galembeck
Keyword(s):  
High Performance ◽  
Raw Materials ◽  
Fire Retardant ◽  
Visual Observation ◽  
Flame Resistance ◽  
New Developments ◽  
New Class ◽  
New Material ◽  
Accredited Laboratory ◽  
Materials Used

Many materials and additives perform well as fire retardants and suppressants, but there is an ever-growing list of unfulfilled demands requiring new developments. This work explores the outstanding dispersant and adhesive performances of cellulose to create a new effective fire-retardant: exfoliated and reassembled graphite (ERG). This is a new 2D polyfunctional material formed by drying aqueous dispersions of graphite and cellulose on wood, canvas, and other lignocellulosic materials, thus producing adherent layers that reduce the damage caused by a flame to the substrates. Visual observation, thermal images and surface temperature measurements reveal fast heat transfer away from the flamed spots, suppressing flare formation. Pinewood coated with ERG underwent standard flame resistance tests in an accredited laboratory, reaching the highest possible class for combustible substrates. The fire-retardant performance of ERG derives from its thermal stability in air and from its ability to transfer heat to the environment, by conduction and radiation. This new material may thus lead a new class of flame-retardant coatings based on a hitherto unexplored mechanism for fire retardation and showing several technical advantages: the precursor dispersions are water-based, the raw materials used are commodities, and the production process can be performed on commonly used equipment with minimal waste.

scholarly journals Direct Patterning and Spontaneous Self-Assembly of Graphene Oxide via Electrohydrodynamic Jet Printing for Energy Storage and Sensing

Micromachines ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 13 ◽  
Author(s):  
Bin Zhang ◽  
Jaehyun Lee ◽  
Mincheol Kim ◽  
Naeeung Lee ◽  
Hyungdong Lee ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Energy Storage ◽  
Self Assembly ◽  
High Performance ◽  
Three Dimensional ◽  
Chemical Properties ◽  
Layer By Layer ◽  
Energy Storage Devices ◽  
Laminar Structure ◽  
Jet Printing

The macroscopic assembly of two-dimensional materials into a laminar structure has received considerable attention because it improves both the mechanical and chemical properties of the original materials. However, conventional manufacturing methods have certain limitations in that they require a high temperature process, use toxic solvents, and are considerably time consuming. Here, we present a new system for the self-assembly of layer-by-layer (LBL) graphene oxide (GO) via an electrohydrodynamic (EHD) jet printing technique. During printing, the orientation of GO flakes can be controlled by the velocity distribution of liquid jet and electric field-induced alignment spontaneously. Closely-packed GO patterns with an ordered laminar structure can be rapidly realized using an interfacial assembly process on the substrates. The surface roughness and electrical conductivity of the LBL structure were significantly improved compared with conventional dispensing methods. We further applied this technique to fabricate a reduced graphene oxide (r-GO)-based supercapacitor and a three-dimensional (3D) metallic grid hybrid ammonia sensor. We present the EHD-assisted assembly of laminar r-GO structures as a new platform for preparing high-performance energy storage devices and sensors.

Synthesis of PMMA-b-PS Block Copolymer by Emulsion ATRP and its Self-Assembly Property

2013 ◽  
Vol 705 ◽  
pp. 115-119
Author(s):  
Bao Yong Tian ◽  
Er Jun Tang ◽  
Miao Yuan ◽  
Rui Xia Hao ◽  
Cun Man Li ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Block Copolymer ◽  
Self Assembly ◽  
Potential Application ◽  
Morphological Characteristic ◽  
Living Polymerization ◽  
The Self ◽  
Emulsion System ◽  
Copolymer Concentration ◽  
Ft Ir

The well-defined block copolymer PMMA-b-PS was prepared by two-step ATRP in emulsion system. GPC results indicate that Mn increased linearly with conversion and polydispersity remained relatively narrow. It presents the characteristics of living polymerization in emulsion system. FT-IR demonstrated that block copolymer PMMA-b-PS could be successfully synthesized by ATRP with macroinitiator PMMA-Cl in emulsion system. The morphological characteristic of the self-assembly depends on the block copolymer concentration and transforms between spheres and rodlike micelles. The property indicates a perfect potential application in drug delivery materials.

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