Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO2 uptake

2019 ◽  
Vol 7 (13) ◽  
pp. 7867-7874 ◽  
Author(s):  
Hao Li ◽  
Kecheng Wang ◽  
Zhigang Hu ◽  
Ying-Pin Chen ◽  
Wolfgang Verdegaal ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Polar Solvent ◽  
Metal Organic Frameworks ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Organic ◽  
Loading Amount

Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO2 uptake than when prepared in a more polar solvent (dichloromethane).

Enhanced water stability and high CO2 storage capacity of Lewis basic sites containing zirconium metal–organic framework

2021 ◽  
Author(s):  
Selcuk Demir ◽  
Nuray Bilgin ◽  
H. Merve Cepni ◽  
Hiroyasu Furukawa ◽  
Fatih Yilmaz ◽  
...  
Keyword(s):  
Metal Ions ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
High Co2 ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Selection Of

Metal–organic frameworks (MOFs) are an emerging class of materials employed for custom-designed purposes by judicious selection of the linker and the metal ions. Among the MOFs composed of carboxylate linkers,...

Three N–H Functionalized Metal–Organic Frameworks with Selective CO2 Uptake, Dye Capture, and Catalysis

2014 ◽  
Vol 53 (14) ◽  
pp. 7692-7699 ◽  
Author(s):  
Yu Zhu ◽  
Yan-Mei Wang ◽  
Sheng-Yun Zhao ◽  
Pan Liu ◽  
Chao Wei ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Co2 Uptake ◽  
Metal Organic

Polymer functionalization to enhance interface quality of mixed matrix membranes for high CO2/CH4 gas separation

2015 ◽  
Vol 3 (29) ◽  
pp. 15202-15213 ◽  
Author(s):  
Nguyen Tien-Binh ◽  
Hoang Vinh-Thang ◽  
Xiao Yuan Chen ◽  
Denis Rodrigue ◽  
Serge Kaliaguine
Keyword(s):  
Gas Separation ◽  
Metal Organic Frameworks ◽  
Molar Ratio ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Interface Quality ◽  
High Co2 ◽  
Metal Organic ◽  
Matrix Membranes

Hydroxyl-functionalized homo- and co-polyimides 6FDA–(DAM)x–(HAB)y (with x : y molar ratio of 1 : 0; 2 : 1; 1 : 1; 1 : 2) and two metal–organic frameworks (MOFs), MIL-53(Al) and NH2-MIL-53(Al) were synthesized for preparation of mixed matrix membranes (MMMs).

Two Microporous Metal–Organic Frameworks with Suitable Pore Size Displaying the High CO2/CH4 Selectivity

2015 ◽  
Vol 15 (11) ◽  
pp. 5382-5387 ◽  
Author(s):  
Jiang Li ◽  
Guo-Ping Yang ◽  
Shi-Long Wei ◽  
Rui-Cheng Gao ◽  
Nan-Nan Bai ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
High Co2 ◽  
Metal Organic

Three stable dinuclear [M2(OH)0.5(NO3)0.5(RCOO)2(RN)4] (M = Cu, Ni) based metal–organic frameworks with high CO2 adsorption and selective separation for O2/N2 and C3H8/CH4

2020 ◽  
Vol 7 (3) ◽  
pp. 731-736 ◽  
Author(s):  
Liang Kan ◽  
Lan Li ◽  
Guanghua Li ◽  
Lirong Zhang ◽  
Yunling Liu
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Selective Separation ◽  
High Density ◽  
High Co2 ◽  
Metal Organic

Three isostructural and stable MOFs have been constructed. All the three compounds with high-density OMSs exhibit high performances for CO2 capture and selective separation.

Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3378-3384 ◽  
Author(s):  
Cheng He ◽  
Chao Hou ◽  
Yu Min Wang ◽  
Xue Yong Gong ◽  
Hong Li Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Basic Site ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Site ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Excellent Selectivity ◽  
Organic Framework

A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.

Glucose Oxidase Decorated Fluorescent Metal-Organic Frameworks as Biomimetic Cascade Nanozymes for Glucose Detection Through Inner Filter Effect

The Analyst ◽  
2021 ◽  
Author(s):  
Xiaohong Li ◽  
Wenjie Jing ◽  
Fanbo Kong ◽  
Sijia Tian ◽  
Mincong Yu ◽  
...  
Keyword(s):  
Glucose Oxidase ◽  
Metal Organic Frameworks ◽  
Inner Filter Effect ◽  
Glucose Detection ◽  
Peroxidase Mimic ◽  
Filter Effect ◽  
Metal Organic ◽  
One Step ◽  
Loading Amount

The metal-organic frameworks (MOFs) as a peroxidase mimic was applied for integrating glucose oxidase (GOx) to achieve one-step glucose detection. However, limited by the loading amount of GOx, the performance...

Solvent effects on the structures and magnetic properties of two doubly interpenetrated metal–organic frameworks

2015 ◽  
Vol 44 (14) ◽  
pp. 6593-6599 ◽  
Author(s):  
Fu-Ping Huang ◽  
Cheng Yang ◽  
Hai-Ye Li ◽  
Peng-Fei Yao ◽  
Xiao-Huan Qin ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Solvent Effects ◽  
Metal Organic Frameworks ◽  
Metal Organic

Two doubly interpenetrated Co(ii) coordination polymers were obtained, and the solvent effects on the structures and magnetic properties were investigated.

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