Manganese ion pre-intercalated hydrated vanadium oxide as a high-performance cathode for magnesium ion batteries

2019 ◽  
Vol 7 (17) ◽  
pp. 10644-10650 ◽  
Author(s):  
Xuanwei Deng ◽  
Yanan Xu ◽  
Qinyou An ◽  
Fangyu Xiong ◽  
Shuangshuang Tan ◽  
...  

The development of rechargeable magnesium ion batteries (MIBs) has received increasing attention due to its low cost, high theoretical volumetric capacities, environmental friendliness and good safety.

Author(s):  
Xue Bai ◽  
Dianxue Cao ◽  
Zhu wu Jiang ◽  
Hongyu Zhang

Aqueous batteries with the characteristic of low cost, high safety and environmental friendliness are secondary battery energy storage systems that use inorganic salt solutions as electrolytes. The researchers explore firstly...


2020 ◽  
Vol 392 ◽  
pp. 123652 ◽  
Author(s):  
Yongquan Zhang ◽  
Guang Liu ◽  
Changhai Zhang ◽  
Qingguo Chi ◽  
Tiandong Zhang ◽  
...  

Inorganics ◽  
2019 ◽  
Vol 7 (6) ◽  
pp. 69 ◽  
Author(s):  
Yichao Cai ◽  
Yunpeng Hou ◽  
Yong Lu ◽  
Jun Chen

Rechargeable aprotic lithium-oxygen (Li-O2) batteries have attracted significant interest in recent years owing to their ultrahigh theoretical capacity, low cost, and environmental friendliness. However, the further development of Li-O2 batteries is hindered by some ineluctable issues, such as severe parasitic reactions, low energy efficiency, poor rate capability, short cycling life and potential safety hazards, which mainly stem from the high charging overpotential in the positive electrode side. Thus, it is of great significance to develop high-performance catalysts for the positive electrode in order to address these issues and to boost the commercialization of Li-O2 batteries. In this review, three main categories of catalyst for the positive electrode of Li-O2 batteries, including carbon materials, noble metals and their oxides, and transition metals and their oxides, are systematically summarized and discussed. We not only focus on the electrochemical performance of batteries, but also pay more attention to understanding the catalytic mechanism of these catalysts for the positive electrode. In closing, opportunities for the design of better catalysts for the positive electrode of high-performance Li-O2 batteries are discussed.


Author(s):  
Guixiang Wang ◽  
Haitao Zou ◽  
Xiaobo Zhu ◽  
Mei Ding ◽  
Chuankun Jia

Abstract Zinc-based redox flow batteries (ZRFBs) have been considered as ones of the most promising large-scale energy storage technologies owing to their low cost, high safety, and environmental friendliness. However, their commercial application is still hindered by a few key problems. First, the hydrogen evolution and zinc dendrite formation cause poor cycling life, of which needs to ameliorated or overcome by finding suitable anolytes. Second, the stability and energy density of catholytes are unsatisfactory due to oxidation, corrosion, and low electrolyte concentration. Meanwhile, highly catalytic electrode materials remain to be explored and the ion selectivity and cost efficiency of membrane materials demands further improvement. In this review, we summarize different types of ZRFBs according to their electrolyte environments including ZRFBs using neutral, acidic, and alkaline electrolytes, then highlight the advances of key materials including electrode and membrane materials for ZRFBs, and finally discuss the challenges and perspectives for the future development of high-performance ZRFBs.


Nanoscale ◽  
2019 ◽  
Vol 11 (33) ◽  
pp. 15472-15478 ◽  
Author(s):  
Donghai Wu ◽  
Baocheng Yang ◽  
Houyang Chen ◽  
Eli Ruckenstein

Tensile and compressive strains are effective ways for charge redistribution to reactivate adsorption sites on electrode materials.


2020 ◽  
Vol 8 (28) ◽  
pp. 14277-14286 ◽  
Author(s):  
Amol Bhairuba Ikhe ◽  
Su Cheol Han ◽  
S. J. Richard Prabakar ◽  
Woon Bae Park ◽  
Kee-Sun Sohn ◽  
...  

3Mg/Mg2Sn composed of intermetallic Mg2Sn and extra Mg is used as a high-performance anode in conventional electrolytes for magnesium-ion batteries.


2018 ◽  
Vol 6 (18) ◽  
pp. 8210-8214 ◽  
Author(s):  
Shi Tao ◽  
Weifeng Huang ◽  
Yushen Liu ◽  
Shuangming Chen ◽  
Bin Qian ◽  
...  

Uniform tetragonal-spinel MgMn2O4(T-MgMn2O4) hollow spheres with a micro/nanostructure are synthesized by using a simple and template-free method and they exhibit outstanding electrochemical performance as the cathode material for magnesium ion batteries.


2021 ◽  
Vol 11 (1) ◽  
pp. 105-119
Author(s):  
Guangyu Qin ◽  
Xiaoxiao Huang ◽  
Xu Yan ◽  
Yunfei He ◽  
Yuhao Liu ◽  
...  

AbstractWood-derived carbon has a 3D porous framework composed of through channels along the growth direction, which is a suitable matrix for preparing electromagnetic wave (EMW) absorbing materials with low cost, light weight, and environmental friendliness. Herein, the carbonized wood decorated by short cone-like NiCo2O4 (NiCo2O4@CW) with highly ordered straight-channel architecture was successfully manufactured through a facile calcination procedure. The horizontal arrangement of the through channels of NiCo2O4@CW (H-NiCo2O4@CW) exhibits a strong reflection loss value of -64.0 dB at 10.72 GHz with a thickness of 3.62 mm and a low filling ratio of 26 wt% (with the density of 0.98 g·cm-3), and the effective absorption bandwidth (EAB) is 8.08 GHz (9.92–18.0 GHz) at the thickness of 3.2 mm. The excellent microwave absorption (MA) property was ascribed to the ordered-channel structure with abundant interfaces and defects from NiCo2O4@CW, which could promote the interfacial polarization and dipole polarization. What is more, this advantageous structure increased the multiple reflections and scattering. Finite element analysis (FEA) simulation is carried out to detect the interaction between the prepared material and EMW when the ordered channels are arranged in different directions. This research provides a low-cost, sustainable, and environmentally friendly strategy for using carbonized wood to fabricate microwave absorbers with strong attenuation capabilities and light weight.


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