A two-dimensional ion-pump of a vanadium pentoxide nanofluidic membrane

2019 ◽  
Vol 7 (17) ◽  
pp. 10552-10560 ◽  
Author(s):  
Raj Kumar Gogoi ◽  
Arindom Bikash Neog ◽  
Tukhar Jyoti Konch ◽  
Neelam Sarmah ◽  
Kalyan Raidongia
Keyword(s):  
Crystal Structure ◽  
Vanadium Pentoxide ◽  
Concentration Gradient ◽  
Layered Crystal ◽  
Ion Pump ◽  
Two Dimensional ◽  
Reactive Surface ◽  
Layered Crystal Structure

The reactive surface and layered crystal structure of vanadium pentoxide (V2O5) are exploited here to prepare a two-dimensional (2D) ion pump that transports ions against their concentration gradient.

Wafer-scale synthesis of ultrathin CoO nanosheets with enhanced electrochemical catalytic properties

2017 ◽  
Vol 5 (19) ◽  
pp. 9060-9066 ◽  
Author(s):  
Fei Wang ◽  
Yanhao Yu ◽  
Xin Yin ◽  
Peng Tian ◽  
Xudong Wang
Keyword(s):  
Crystal Structure ◽  
Catalytic Properties ◽  
Grand Challenge ◽  
Layered Crystal ◽  
Two Dimensional ◽  
Large Area ◽  
Wafer Scale ◽  
Layered Crystal Structure ◽  
2D Nanomaterials

Large area synthesis of two dimensional (2D) nanomaterials with a non-layered crystal structure remains a grand challenge.

Poly[aqua(μ2-4,4′-bipyridyl-κ2 N:N′)(μ2-3-phosphonatobenzenesulfonato-κ2 O:O′)copper(II)]

2007 ◽  
Vol 63 (11) ◽  
pp. m2766-m2767 ◽  
Author(s):  
Zi-Yi Du ◽  
Yong-Rong Xie ◽  
He-Rui Wen
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Water Molecule ◽  
Membered Ring ◽  
Layered Crystal ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Metal Centre ◽  
One Dimensional ◽  
Layered Crystal Structure

The title polymer, [Cu(C6H5O6PS)(C10H8N2)(H2O)] n , was synthesized by a hydrothermal method. The CuII ion is five-coordinated by one phosphonate O atom, one sulfonate O atom, two N atoms of the bipyridyl ligand and one water molecule. The coordination geometry around the metal centre can be described as slightly distorted square-pyramidal. The CuII ions are connected by bidentate bridging phosphonato-benzenesulfonate ligands, forming one-dimensional helical chains along [010], which are further bridged by bidentate 4,4′-bipyridyl ligands, generating a two-dimensional layered crystal structure. The layered structure features an eight-membered ring including four CuII ions, two [O3S–C6H4–PO3H]2− anions and two 4,4′-bipyridyl ligands. Hydrogen bonds involving aqua ligands, phosphonate O and sulfonate O atoms are observed between the layers,

scholarly journals The layered crystal structure of bis(theophyllinium) hexachloridostannate (IV), C14H18N8O8SnCl6

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Guido J. Reiss ◽  
Maik Wyshusek
Keyword(s):  
Crystal Structure ◽  
Layered Crystal ◽  
Layered Crystal Structure

Abstract C14H18N8O8SnCl6, monoclinic, P21/n (no. 14), a = 8.1810(2) Å, b = 12.6195(3) Å, c = 11.3811(2) Å, β = 90.258(2)°, Z = 2, V = 1174.97(5) Å3, R gt(F) = 0.0266, wR ref = 0.0620, T = 290 K.

Crystal structure of oxybutynin hydrochloride hemihydrate, C22H32NO3Cl(H2O)0.5

2019 ◽  
Vol 34 (1) ◽  
pp. 50-58
Author(s):  
James A. Kaduk ◽  
Nicholas C. Boaz ◽  
Amy M. Gindhart ◽  
Thomas N. Blanton
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Powder Diffraction ◽  
Density Functional ◽  
Hydroxyl Group ◽  
Layered Crystal ◽  
Powder Diffraction File ◽  
X Ray ◽  
Layered Crystal Structure ◽  
Oxybutynin Hydrochloride

The crystal structure of oxybutynin hydrochloride hemihydrate has been solved and refined using synchrotron X-ray powder diffraction data, and optimized using density functional techniques. Oxybutynin hydrochloride hemihydrate crystallizes in space group I2/a (#15) with a = 14.57266(8), b = 8.18550(6), c = 37.16842(26) Å, β = 91.8708(4)°, V = 4421.25(7) Å3, and Z = 8. The compound exhibits X-ray-induced photoreduction of the triple bond. Prominent in the layered crystal structure is the N–H⋅⋅⋅Cl hydrogen bond between the cation and anion, as well as O–H⋅⋅⋅Cl hydrogen bonds from the water molecule and hydroxyl group of the oxybutynin cation. C–H⋅⋅⋅Cl hydrogen bonds also contribute to the crystal energy, and help determine the conformation of the cation. The powder pattern is included in the Powder Diffraction File™ as entry 00-068-1305.

scholarly journals Study of anisotropic thermal conductivity in textured thermoelectric alloys by Raman spectroscopy

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 24456-24465
Author(s):  
Rapaka S. C. Bose ◽  
K. Ramesh
Keyword(s):  
Crystal Structure ◽  
Thermal Conductivity ◽  
Raman Spectroscopy ◽  
Transport Properties ◽  
Thermal Transport ◽  
Layered Crystal ◽  
Layered Crystal Structure ◽  
Thermal Transport Properties ◽  
Anisotropic Thermal Conductivity ◽  
P Type

Polycrystalline p-type Sb1.5Bi0.5Te3 (SBT) and n-type Bi2Te2.7Se0.3 (BTS) compounds possessing layered crystal structure show anisotropic electronic and thermal transport properties.

Synthesis, crystal and electronic structure of BaLi2Cd2Ge2

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sviatoslav Baranets ◽  
Alexander Ovchinnikov ◽  
Svilen Bobev
Keyword(s):  
Crystal Structure ◽  
Electronic Structure ◽  
Fermi Level ◽  
Structure Type ◽  
Layered Crystal ◽  
Electronic Density ◽  
Electronic Band ◽  
Cell Parameters ◽  
Layered Crystal Structure ◽  
Electronic Band Gap

Abstract A new quaternary germanide has been synthesized and structurally characterized. BaLi2Cd2Ge2 adopts the rhombohedral CaCu4P2 structure type (Pearson code hR7; space group R 3 ‾ m $R‾{3}m$ , Z = 3) with unit cell parameters a = 4.5929(6) and c = 26.119(5) Å. Structure refinements from single-crystal X-ray diffraction data demonstrate that the layered crystal structure can be regarded as an ordered quaternary variant of the ternary archetype; structural parallels to layered pnictides and binary germanides can also be drawn. The layered crystal structure is characterized by the absence of direct Ge–Ge and Cd–Cd homoatomic bonds, which suggests that BaLi2Cd2Ge2 should be classified as a Zintl phase, according to the formulation (Ba2+)(Li+)2(Cd2+)2(Ge4−)2. Electronic structure calculations show that the Fermi level crosses a distinct peak in the DOS, although the presence of an electronic band gap or a dip in the electronic density of states at the Fermi level is expected based on the electron partitioning.

An old material in the nanoworld: organic-inorganic hybrid nanotubes based onγ-titanium phosphate layered crystal structure

2009 ◽  
Vol 6 (10) ◽  
pp. 2190-2194 ◽  
Author(s):  
Jesús A. Blanco ◽  
Sergei A. Khainakov ◽  
Olena Khainakova ◽  
José R. García ◽  
S. García-Granda
Keyword(s):  
Crystal Structure ◽  
Titanium Phosphate ◽  
Layered Crystal ◽  
Inorganic Hybrid ◽  
Layered Crystal Structure
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