Unassisted solar water splitting with 9.8% efficiency and over 100 h stability based on Si solar cells and photoelectrodes catalyzed by bifunctional Ni–Mo/Ni

2019 ◽  
Vol 7 (5) ◽  
pp. 2200-2209 ◽  
Author(s):  
Ronglei Fan ◽  
Shaobo Cheng ◽  
Guanping Huang ◽  
Yongjie Wang ◽  
Yazhou Zhang ◽  
...  

Designing a highly efficient and stable photoelectrochemical (PEC) tandem cell for unassisted solar water splitting is considered a promising approach for large-scale solar energy storage.

Author(s):  
Dingwang Huang ◽  
Kang Wang ◽  
Lintao Li ◽  
Kuang Feng ◽  
Na An ◽  
...  

3.17% efficient Cu2ZnSnS4–BiVO4 integrated tandem cell and a large scale 5 × 5 cm integrated CZTS–BiVO4 tandem device for standalone overall solar water splitting was assembled for the first time.


Nano Energy ◽  
2017 ◽  
Vol 42 ◽  
pp. 1-7 ◽  
Author(s):  
Hakhyeon Song ◽  
Seungtaeg Oh ◽  
Hyun Yoon ◽  
Ka-Hyun Kim ◽  
Sangwoo Ryu ◽  
...  

Solar Energy ◽  
2018 ◽  
Vol 173 ◽  
pp. 1323
Author(s):  
Shahid Ali ◽  
Ibrahim Khan ◽  
Safyan A. Khan ◽  
Manzar Sohail ◽  
Zain H. Yamani ◽  
...  

2018 ◽  
Vol 8 (9) ◽  
pp. 1526 ◽  
Author(s):  
Sangmo Kim ◽  
Nguyen Nguyen ◽  
Chung Bark

Over the past few decades, solar water splitting has evolved into one of the most promising techniques for harvesting hydrogen using solar energy. Despite the high potential of this process for hydrogen production, many research groups have encountered significant challenges in the quest to achieve a high solar-to-hydrogen conversion efficiency. Recently, ferroelectric materials have attracted much attention as promising candidate materials for water splitting. These materials are among the best candidates for achieving water oxidation using solar energy. Moreover, their characteristics are changeable by atom substitute doping or the fabrication of a new complex structure. In this review, we describe solar water splitting technology via the solar-to-hydrogen conversion process. We will examine the challenges associated with this technology whereby ferroelectric materials are exploited to achieve a high solar-to-hydrogen conversion efficiency.


NANO ◽  
2019 ◽  
Vol 14 (11) ◽  
pp. 1950146
Author(s):  
Jia Liu ◽  
Yinghua Zhang ◽  
Zhiming Bai ◽  
Zhian Huang ◽  
Yukun Gao ◽  
...  

An integrated tandem photoelectrochemical (PEC) cell, composed of a three-dimensional (3D) ZnO/CdS/NiFe layered double hydroxide (LDH) core/shell/hierarchical nanowire arrays (NWAs) photoanode and a [Formula: see text]-Cu2O photocathode, was designed for unassisted overall solar water splitting in this study. The optical and photoelectrochemical characteristics of ZnO-based photoanodes and Cu2O photocathode were investigated. The results show that ZnO/CdS/NiFe LDH nanostructures offer significantly enhanced performances with a photocurrent density reaching 5.8[Formula: see text]mA[Formula: see text][Formula: see text][Formula: see text]cm[Formula: see text] at 0.9[Formula: see text]V and an onset potential as early as 0.1[Formula: see text]V (versus RHE). The enhancement can be attributed to the existence of CdS nanoparticles (NPs) which boosts the light absorption in visible region and enhances charge separation. Moreover, the introduction of NiFe LDH nanoplates, with unique hierarchical mesoporous architecture, promotes electrochemical reactions by providing more active sites as co-catalyst. On the above basis, the ZnO/CdS/NiFe LDH–Cu2O two-electrode tandem cell system was established. At zero bias, the device shows a photocurrent density of 0.4[Formula: see text]mA[Formula: see text][Formula: see text][Formula: see text]cm[Formula: see text] along with the corresponding solar-to-hydrogen (STH) conversion efficiency reaching 0.50%. Our results indicate that the tandem PEC cells consisting of metal–oxide–semiconductor photoelectrodes based on Earth-abundant and low-cost materials hold promising application potential for overall solar water splitting.


Joule ◽  
2019 ◽  
Vol 3 (12) ◽  
pp. 2930-2941 ◽  
Author(s):  
Jing Gao ◽  
Florent Sahli ◽  
Chenjuan Liu ◽  
Dan Ren ◽  
Xueyi Guo ◽  
...  

2020 ◽  
Vol 8 (7) ◽  
pp. 3845-3850 ◽  
Author(s):  
Meirong Huang ◽  
Wenhai Lei ◽  
Min Wang ◽  
Shuji Zhao ◽  
Changli Li ◽  
...  

Large-scale BiVO4 photoanodes were prepared for solar water splitting. A photocurrent density of water oxidation of ∼2.23 mA cm−2 at 1.23 VRHE and ∼0.83% conversion efficiency at 0.65 VRHE were achieved, with <4% decay after 5 h of operation under harsh conditions.


Solar Energy ◽  
2016 ◽  
Vol 135 ◽  
pp. 821-826 ◽  
Author(s):  
Sang Youn Chae ◽  
Se Jin Park ◽  
Oh-Shim Joo ◽  
Byoung Koun Min ◽  
Yun Jeong Hwang

2016 ◽  
Vol 9 (1) ◽  
pp. 145-154 ◽  
Author(s):  
Félix Urbain ◽  
Vladimir Smirnov ◽  
Jan-Philipp Becker ◽  
Andreas Lambertz ◽  
Florent Yang ◽  
...  

Bias-free solar water splitting is demonstrated using thin film silicon based triple and quadruple junction solar cells with solar-to-hydrogen efficiencies up to 9.5%.


Author(s):  
Christos Trompoukis ◽  
Jan-Willem Schüttauf ◽  
Tom Bosserez ◽  
Ji-Yu Feng ◽  
Aimi Abass ◽  
...  

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