Supercapacitor with extraordinary cycling stability and high rate from nano-architectured polyaniline/graphene on Janus nanofibrous film with shape memory

2018 ◽  
Vol 6 (42) ◽  
pp. 21064-21077 ◽  
Author(s):  
Ali Khosrozadeh ◽  
Gurankit Singh ◽  
Quan Wang ◽  
Gaoxing Luo ◽  
Malcolm Xing

Layer-by-layer polyaniline–graphene on multifunctional polyvinyl alcohol nanofibers leads to extremely stable flexible electrodes with high power and rate capability.

Nanoscale ◽  
2019 ◽  
Vol 11 (18) ◽  
pp. 8882-8897 ◽  
Author(s):  
Akshay Kumar Budumuru ◽  
Benadict Rakesh ◽  
Chandran Sudakar

Defects in MoS2 nanosheets improve the rate capability and cycling stability in the intercalation regime. Li adsorbed at defect sites facilitates a high power density.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Shouxiang Ding ◽  
Mingzheng Zhang ◽  
Runzhi Qin ◽  
Jianjun Fang ◽  
Hengyu Ren ◽  
...  

AbstractRecent years have witnessed a booming interest in grid-scale electrochemical energy storage, where much attention has been paid to the aqueous zinc ion batteries (AZIBs). Among various cathode materials for AZIBs, manganese oxides have risen to prominence due to their high energy density and low cost. However, sluggish reaction kinetics and poor cycling stability dictate against their practical application. Herein, we demonstrate the combined use of defect engineering and interfacial optimization that can simultaneously promote rate capability and cycling stability of MnO2 cathodes. β-MnO2 with abundant oxygen vacancies (VO) and graphene oxide (GO) wrapping is synthesized, in which VO in the bulk accelerate the charge/discharge kinetics while GO on the surfaces inhibits the Mn dissolution. This electrode shows a sustained reversible capacity of ~ 129.6 mAh g−1 even after 2000 cycles at a current rate of 4C, outperforming the state-of-the-art MnO2-based cathodes. The superior performance can be rationalized by the direct interaction between surface VO and the GO coating layer, as well as the regulation of structural evolution of β-MnO2 during cycling. The combinatorial design scheme in this work offers a practical pathway for obtaining high-rate and long-life cathodes for AZIBs.


Nanoscale ◽  
2019 ◽  
Vol 11 (16) ◽  
pp. 7761-7770 ◽  
Author(s):  
Muhammad Tahir ◽  
Liang He ◽  
Waqas Ali Haider ◽  
Wei Yang ◽  
Xufeng Hong ◽  
...  

Microstructuring of the PEDOT–CNT composite for microsupercapacitors with high rate capability and excellent cycling stability.


2019 ◽  
Vol 48 (3) ◽  
pp. 833-838 ◽  
Author(s):  
Xuejiao Liu ◽  
Shixiong Li ◽  
Jiantao Zai ◽  
Ying Jin ◽  
Peng Zhan ◽  
...  

The enormous volume expansion during cycling and poor electron conductivity of SnS2 limit its cycling stability and high rate capability.


Nanoscale ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 520-531 ◽  
Author(s):  
Dongdong Wang ◽  
Zhongqiang Shan ◽  
Jianhua Tian ◽  
Zheng Chen

Ultrathin mesoporous Li4Ti5O12 nanosheets, which offer high capacity, high rate capability and excellent cycling stability, were synthesized in a controlled fashion.


2013 ◽  
Vol 1 (37) ◽  
pp. 11397 ◽  
Author(s):  
Wei He ◽  
Dingding Yuan ◽  
Jiangfeng Qian ◽  
Xinping Ai ◽  
Hanxi Yang ◽  
...  

2014 ◽  
Vol 267 ◽  
pp. 874-880 ◽  
Author(s):  
Xue-Hui Liu ◽  
Li-Qin Kou ◽  
Ting Shi ◽  
Kun Liu ◽  
Li Chen

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