Role of the Mn substituent in Na3V2(PO4)3 for high-rate sodium storage

2018 ◽  
Vol 6 (34) ◽  
pp. 16627-16637 ◽  
Author(s):  
Jae-Sang Park ◽  
Jongsoon Kim ◽  
Jae Hyeon Jo ◽  
Seung-Taek Myung
Keyword(s):  
Electron Transfer ◽  
Electrochemical Performance ◽  
Band Gap ◽  
Electric Conductivity ◽  
Carbon Coating ◽  
Band Gap Energy ◽  
High Rate ◽  
Gap Energy ◽  
Sodium Storage

C/NVMP allowed high electrochemical performance supported by the replace V by the Mn promoted the easier electron transfer through lower band gap energy than Mn-free NVP and carbon coating increase the electric conductivity up to 2 × 10−3 s cm−1, which led to superior electrode performance.

The role of solvents in framework dimensionality and their effect on band gap energy

2015 ◽  
Vol 44 (3) ◽  
pp. 1009-1016 ◽  
Author(s):  
K. S. Asha ◽  
P. R. Kavyasree ◽  
Anu George ◽  
Sukhendu Mandal
Keyword(s):  
Band Gap ◽  
Crucial Role ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Framework Materials ◽  
Hybrid Framework

Solvents play a crucial role towards the dimensionality and band gap energy of hybrid framework materials.

scholarly journals Investigating the Photoelectrochemical Performance of WO3-TiO2 Nanorod Photoanodes in Water Splitting

2021 ◽  
Author(s):  
Armin Hariri ◽  
Neda Gilani ◽  
Javad Vahabzadeh Pasikhani
Keyword(s):  
Optical Properties ◽  
Band Gap ◽  
Hydrogen Generation ◽  
Band Gap Energy ◽  
Pure Tio2 ◽  
High Rate ◽  
Photoelectrochemical Performance ◽  
One Pot ◽  
Gap Energy ◽  
Tio2 Nanorod

TiO2 nanorod as a superior nanostructure has attracted a lot of attention to exert in the photocatalytic and photoelectrocatlytic applications in recent years. Nevertheless, its practical usage is restricted by a number of limitations such as the large band gap energy, the low rate of photo-induced carriers generation and the high rate of charge carriers recombination. Therefore in this study, incorporation of TiO2 nanorod with WO3 is proposed as a suitable approach to overcome these defects. In this regard, WO3-TiO2 nanorod was constructed by a facile one pot hydrothermal method in two incessant steps and was then employed as a potent photoanode for photoelectrocatalytic hydrogen generation. The morphology, elemental compositions and optical properties were characterized by the FESEM, EDS and DRS analysis, respectively. Furthermore, voltammetry analyses were performed to assay the photoelectrochemical features of WO3-TiO2 nanorod. The results confirmed that the incorporation of TiO2 nanorod with WO3 not only significantly made the band gap energy narrower (from 3eV to 2eV), but also dramatically intensified the photocurrent density and photoconversion efficiency from 1mA.cm-2 to 1.8mA.cm-2 and from 0.3% to 0.45%, respectively. As a consequence of improving optical properties and photoelectrochemical features, WO3-TiO2 nanorod could generate 2.43 mmol H2 during 100 min under UV irradiation, which was 1.71 times more than hydrogen generated over pure TiO2 nanorod

Role of nitrogen in the reduced temperature dependence of band-gap energy in GaNAs

2000 ◽  
Vol 77 (19) ◽  
pp. 3021-3023 ◽  
Author(s):  
I. Suemune ◽  
K. Uesugi ◽  
W. Walukiewicz
Keyword(s):  
Temperature Dependence ◽  
Band Gap ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Reduced Temperature

scholarly journals Crystal-seeds induced construction of ZnO–ZnFe2O4 micro-cubic composites as excellent anode materials for lithium ion battery

RSC Advances ◽  
2018 ◽  
Vol 8 (29) ◽  
pp. 16187-16192 ◽  
Author(s):  
Pei Pan ◽  
Ting Wang ◽  
Lihui Chen ◽  
Feng Wang ◽  
Xiong Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Electrochemical Performance ◽  
Metal Oxides ◽  
Band Gap ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
Lithium Ion ◽  
Band Gap Energy ◽  
Hetero Structure ◽  
Gap Energy

This work aims at designing a fine assembly of two different transition metal oxides with a distinct band-gap energy into a bi-component-active hetero-structure to improve electrochemical performance.

Pressure-dependent modifications in the optical and electronic properties of Fe(IO3)3: The role of Fe 3d and I 5p lone-pair electrons

2021 ◽  
Author(s):  
Akun Liang ◽  
Placida Rodríguez-Hernandez ◽  
Alfonso Munoz ◽  
Saqib Raman ◽  
Alfredo Segura ◽  
...  
Keyword(s):  
Optical Absorption ◽  
Band Gap ◽  
Electronic Properties ◽  
Lone Pair ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Optical And Electronic Properties ◽  
Indirect Band Gap ◽  
Lone Pair Electrons

We have determined by means of optical-absorption experiments that Fe(IO3)3 is an indirect band-gap material with a band-gap energy of 2.1 eV. This makes this compound the iodate with the...

Modification of optical properties of PC-PBT/Cr2O3 and PC-PBT/CdS nanocomposites by gamma irradiation

2020 ◽  
Vol 92 (2) ◽  
pp. 20402
Author(s):  
Kaoutar Benthami ◽  
Mai ME. Barakat ◽  
Samir A. Nouh
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Band Gap ◽  
Color Difference ◽  
Band Gap Energy ◽  
Polybutylene Terephthalate ◽  
Γ Irradiation ◽  
Gap Energy ◽  
Vis Spectroscopy ◽  
Oxygen Atoms

Nanocomposite (NCP) films of polycarbonate-polybutylene terephthalate (PC-PBT) blend as a host material to Cr2O3 and CdS nanoparticles (NPs) were fabricated by both thermolysis and casting techniques. Samples from the PC-PBT/Cr2O3 and PC-PBT/CdS NCPs were irradiated using different doses (20–110 kGy) of γ radiation. The induced modifications in the optical properties of the γ irradiated NCPs have been studied as a function of γ dose using UV Vis spectroscopy and CIE color difference method. Optical dielectric loss and Tauc's model were used to estimate the optical band gaps of the NCP films and to identify the types of electronic transition. The value of optical band gap energy of PC-PBT/Cr2O3 NCP was reduced from 3.23 to 3.06 upon γ irradiation up to 110 kGy, while it decreased from 4.26 to 4.14 eV for PC-PBT/CdS NCP, indicating the growth of disordered phase in both NCPs. This was accompanied by a rise in the refractive index for both the PC-PBT/Cr2O3 and PC-PBT/CdS NCP films, leading to an enhancement in their isotropic nature. The Cr2O3 NPs were found to be more effective in changing the band gap energy and refractive index due to the presence of excess oxygen atoms that help with the oxygen atoms of the carbonyl group in increasing the chance of covalent bonds formation between the NPs and the PC-PBT blend. Moreover, the color intensity, ΔE has been computed; results show that both the two synthesized NCPs have a response to color alteration by γ irradiation, but the PC-PBT/Cr2O3 has a more response since the values of ΔE achieved a significant color difference >5 which is an acceptable match in commercial reproduction on printing presses. According to the resulting enhancement in the optical characteristics of the developed NCPs, they can be a suitable candidate as activate materials in optoelectronic devices, or shielding sheets for solar cells.

Stability Investigation in the Optical Properties of Thermally Evaporated Ge5Se95-x Znx Thin Films

2015 ◽  
Vol 7 (3) ◽  
pp. 1923-1930
Author(s):  
Austine Amukayia Mulama ◽  
Julius Mwakondo Mwabora ◽  
Andrew Odhiambo Oduor ◽  
Cosmas Mulwa Muiva ◽  
Boniface Muthoka ◽  
...  
Keyword(s):  
Thin Films ◽  
Band Gap ◽  
Optical Band Gap ◽  
Thermal Evaporation ◽  
Optical Transition ◽  
Bulk Material ◽  
Band Gap Energy ◽  
Optical Absorbance ◽  
Gap Energy ◽  
Constituent Elements

 Selenium-based chalcogenides are useful in telecommunication devices like infrared optics and threshold switching devices. The investigated system of Ge5Se95-xZnx (0.0 ≤ x ≤ 4 at.%) has been prepared from high purity constituent elements. Thin films from the bulk material were deposited by vacuum thermal evaporation. Optical absorbance measurements have been performed on the as-deposited thin films using transmission spectra. The allowed optical transition was found to be indirect and the corresponding band gap energy determined. The variation of optical band gap energy with the average coordination number has also been investigated based on the chemical bonding between the constituents and the rigidity behaviour of the system’s network.

scholarly journals Polymer Thermal Treatment Production of Cerium Doped Willemite Nanoparticles: An Analysis of Structure, Energy Band Gap and Luminescence Properties

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1118
Author(s):  
Ibrahim Mustapha Alibe ◽  
Khamirul Amin Matori ◽  
Mohd Hafiz Mohd Zaid ◽  
Salisu Nasir ◽  
Ali Mustapha Alibe ◽  
...  
Keyword(s):  
Solid State ◽  
Thermal Treatment ◽  
Band Gap ◽  
Optical Band Gap ◽  
Dopant Concentration ◽  
Blue Emission ◽  
Green Emission ◽  
Band Gap Energy ◽  
Solid State Lighting ◽  
Gap Energy

The contemporary market needs for enhanced solid–state lighting devices has led to an increased demand for the production of willemite based phosphors using low-cost techniques. In this study, Ce3+ doped willemite nanoparticles were fabricated using polymer thermal treatment method. The special effects of the calcination temperatures and the dopant concentration on the structural and optical properties of the material were thoroughly studied. The XRD analysis of the samples treated at 900 °C revealed the development and or materialization of the willemite phase. The increase in the dopant concentration causes an expansion of the lattice owing to the replacement of larger Ce3+ ions for smaller Zn2+ ions. Based on the FESEM and TEM micrographs, the nanoparticles size increases with the increase in the cerium ions. The mean particles sizes were estimated to be 23.61 nm at 1 mol% to 34.02 nm at 5 mol% of the cerium dopant. The optical band gap energy of the doped samples formed at 900 °C decreased precisely by 0.21 eV (i.e., 5.21 to 5.00 eV). The PL analysis of the doped samples exhibits a strong emission at 400 nm which is ascribed to the transition of an electron from localized Ce2f state to the valence band of O2p. The energy level of the Ce3+ ions affects the willemite crystal lattice, thus causing a decrease in the intensity of the green emission at 530 nm and the blue emission at 485 nm. The wide optical band gap energy of the willemite produced is expected to pave the way for exciting innovations in solid–state lighting applications.

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