Pillar-layered MOFs: functionality, interpenetration, flexibility and applications

2018 ◽  
Vol 6 (40) ◽  
pp. 19288-19329 ◽  
Author(s):  
Farnoosh ZareKarizi ◽  
Monika Joharian ◽  
Ali Morsali
Keyword(s):  
Metal Organic Frameworks ◽  
Crystalline Materials ◽  
Research Areas ◽  
Metal Organic

Pillar-layered metal–organic frameworks (MOFs) are among the most interesting research areas in crystalline materials.

scholarly journals Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

2021 ◽  
Vol 7 (2) ◽  
pp. 47
Author(s):  
Flávio Figueira ◽  
Filipe A. Almeida Paz
Keyword(s):  
Chemical Composition ◽  
Carbon Material ◽  
Metal Organic Frameworks ◽  
Electrochemical Reactions ◽  
Porous Carbon Material ◽  
Important Class ◽  
Porous Carbons ◽  
Preparation Methods ◽  
Crystalline Materials ◽  
Metal Organic

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.

A series of porous 3D inorganic–organic hybrid framework crystalline materials based on 5-aminoisophthalic acid for photocatalytic degradation of crystal violet

2021 ◽  
Vol 45 (7) ◽  
pp. 3432-3440
Author(s):  
Yu Xin ◽  
Jun Zhou ◽  
Yong Heng Xing ◽  
Feng Ying Bai ◽  
Li Xian Sun
Keyword(s):  
Photocatalytic Degradation ◽  
Crystal Violet ◽  
Metal Organic Frameworks ◽  
Synthetic Method ◽  
Crystalline Materials ◽  
Organic Hybrid ◽  
Hybrid Framework ◽  
Metal Organic ◽  
Degradation Properties

Seven 3D metal-organic frameworks have been designed and synthesized by the hydrothermal synthetic method based on the ligand 5-aminoisophthalic acid. Complexes 1-4 have better photocatalytic degradation properties for dyes CV.

Polymorphism in a Two-Dimensional Copper(I) Metal-Organic Framework with the ligand bis(4-pyridylthio)methane

CrystEngComm ◽  
2021 ◽  
Author(s):  
Olaya Paz Gomez ◽  
Rosa Carballo ◽  
Ana Belen Lago ◽  
Ezequiel M. Vazquez-Lopez
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Common Phenomenon ◽  
Two Dimensional ◽  
Structure Property ◽  
Crystalline Materials ◽  
Metal Organic ◽  
Organic Framework

Polymorphism is a common phenomenon in crystalline materials but it has barely been studied in the field of metal organic frameworks. The study of polymorphism is useful to investigate structure–property...

scholarly journals Landscape of Research Areas for Zeolites and Metal-Organic Frameworks Using Computational Classification Based on Citation Networks

Materials ◽  
2017 ◽  
Vol 10 (12) ◽  
pp. 1428 ◽  
Author(s):  
Takaya Ogawa ◽  
Kenta Iyoki ◽  
Tomohiro Fukushima ◽  
Yuya Kajikawa
Keyword(s):  
Metal Organic Frameworks ◽  
Citation Networks ◽  
Research Areas ◽  
Metal Organic

scholarly journals Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition

Inorganics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 81
Author(s):  
Alessia Tombesi ◽  
Claudio Pettinari
Keyword(s):  
Carbon Dioxide ◽  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Species ◽  
Olefin Epoxidation ◽  
Crystalline Materials ◽  
Recent Developments ◽  
Metal Organic ◽  
New Research

Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO2 consuming reactions.

MOF/COF-based materials using 3D printing technology: Application in water treatment, gas removal, biomedical, and electronic industries

2021 ◽  
Author(s):  
Shadpour Mallakpour ◽  
Elham Azadi ◽  
Chaudhery Mustansar Hussain
Keyword(s):  
Water Treatment ◽  
3D Printing ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Crystalline Materials ◽  
Technology Application ◽  
3D Printing Technology ◽  
The Past ◽  
Gas Removal ◽  
Metal Organic

Over the past decade, porous crystalline materials such as covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) with unique features such as intrinsic porosity, well-defined topology, diverse functionalities, large surface...

scholarly journals Flexibility in Metal–Organic Frameworks: A Basic Understanding

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 512 ◽  
Author(s):  
Noor Aljammal ◽  
Christia Jabbour ◽  
Somboon Chaemchuen ◽  
Tatjána Juzsakova ◽  
Francis Verpoort
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Flexibility ◽  
Logical Basis ◽  
Research Areas ◽  
Research Activities ◽  
Basic Understanding ◽  
Fundamental Understanding ◽  
Metal Organic ◽  
And Behavior ◽  
External Stimuli

Much has been written about the fundamental aspects of the metal–organic frameworks (MOFs). Still, details concerning the MOFs with structural flexibility are not comprehensively understood. However, a dramatic increase in research activities concerning rigid MOFs over the years has brought deeper levels of understanding for their properties and applications. Nonetheless, robustness and flexibility of such smart frameworks are intriguing for different research areas such as catalysis, adsorption, etc. This manuscript overviews the different aspects of framework flexibility. The review has touched lightly on several ideas and proposals, which have been demonstrated within the selected examples to provide a logical basis to obtain a fundamental understanding of their synthesis and behavior to external stimuli.

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