Simultaneous conversion of carbon dioxide and methane to syngas using an oxygen transport membrane in pure CO2and CH4atmospheres

2018 ◽  
Vol 6 (29) ◽  
pp. 14246-14254 ◽  
Author(s):  
Jeong Hwan Park ◽  
Young-il Kwon ◽  
Gyeong Duk Nam ◽  
Jong Hoon Joo
Keyword(s):  
Carbon Dioxide ◽  
Partial Oxidation ◽  
Oxygen Transport ◽  
Partial Oxidation Of Methane ◽  
Oxidation Of Methane ◽  
Oxygen Transport Membrane

The utilization of CO2, coupled with partial oxidation of methane (POM) by using an oxygen transport membrane, has been investigated.

scholarly journals A CO2-stable reduction-tolerant Nd-containing dual phase membrane for oxyfuel CO2 capture

2014 ◽  
Vol 2 (21) ◽  
pp. 7780-7787 ◽  
Author(s):  
Huixia Luo ◽  
Tobias Klande ◽  
Zhengwen Cao ◽  
Fangyi Liang ◽  
Haihui Wang ◽  
...  
Keyword(s):  
Partial Oxidation ◽  
Co2 Capture ◽  
Oxygen Transport ◽  
Synthesis Gas ◽  
Dual Phase ◽  
Membrane Material ◽  
Oxidation Of Methane ◽  
Oxygen Transport Membrane ◽  
Stable Reduction ◽  
Harsh Conditions

We report a novel CO2-stable reduction-tolerant dual-phase oxygen transport membrane 40 wt% Nd0.6Sr0.4FeO3−δ–60 wt% Ce0.9Nd0.1O2−δ. This membrane material shows good reversibility of the oxygen permeation fluxes, good stability in a CO2 atmosphere and under the harsh conditions of partial oxidation of methane to synthesis gas up to 950 °C.

Dual Role of Perovskite Hollow Fiber Membrane in the Methane Oxidation Reactions

2016 ◽  
pp. 385-430
Author(s):  
Serbia M. Rodulfo-Baechler
Keyword(s):  
Carbon Dioxide ◽  
Methane Oxidation ◽  
Partial Oxidation ◽  
Hollow Fiber Membrane ◽  
Hollow Fibre ◽  
Dual Role ◽  
Partial Oxidation Of Methane ◽  
Oxygen Flux ◽  
Oxidation Reactions ◽  
Oxidation Of Methane

The Mixed Ionic and Electronic Conducting (MIEC) membrane reactors are of interest because they have the potential to produce high purity oxygen from air at lower costs and provide a continuous oxygen supply to reactions or/and industrial processes. The study of the dual role oxygen flux and catalytic performance of the unmodified and Ni-coated La0.6Sr0.4Co0.2Fe0.8O3-d hollow fibre membranes (LSCF6428 HFM) in the methane oxidation reactions (i.e., partial oxidation of methane and methane combustion) by using air on lumen side and methane on shell side are shown in this chapter. The LSCF6428 HFM participates not only in the oxygen flux but also in the methane conversion to C2. A Ni-coated LSCF6428 HFM under lean O2/CH4 gradient (i.e., 0.5) showed the production of syngas, carbon dioxide and C2 products in agreement with the thermodynamic calculation. At rich O2/CH4 gradient (i.e., 1.0), the formation of carbon dioxide was facilitated. The main catalytic pathway at lean O2/CH4 gradient and H2 reduction treatment was partial oxidation of methane to C2 and syngas.

Partial oxidation of methane to synthesis gas using carbon dioxide

Nature ◽  
1991 ◽  
Vol 352 (6332) ◽  
pp. 225-226 ◽  
Author(s):  
A. T. Ashcroft ◽  
A. K. Cheetham ◽  
M. L. H. Green ◽  
P. D. F. Vernon
Keyword(s):  
Carbon Dioxide ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Partial Oxidation Of Methane ◽  
Oxidation Of Methane
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