scholarly journals Molecular blends of methylated-poly(ethylenimine) and amorphous porous organic cages for SO2 adsorption

2018 ◽  
Vol 6 (44) ◽  
pp. 22043-22052 ◽  
Author(s):  
Guanghui Zhu ◽  
Jan-Michael Y. Carrillo ◽  
Achintya Sujan ◽  
Claudia N. Okonkwo ◽  
Sangjae Park ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Mass Transfer ◽  
Composite Material ◽  
Ethylene Imine ◽  
Molecular Mixing ◽  
So2 Adsorption ◽  
Poly Ethylene ◽  
Thermal Stability Of ◽  
Hazardous Gas

Porous organic cage (POCs) are explored as a support for hazardous gas sorbents. The molecular mixing between the POC and methylated poly(ethylene imine) was observed and resulted in the improvement of mass transfer and thermal stability of the composite material.

Thermal stability of surfactants with amino and imido groups in poly(ethylene terephthalate)/clay composites

2008 ◽  
Vol 109 (6) ◽  
pp. 4112-4120 ◽  
Author(s):  
Xuepei Yuan ◽  
Chuncheng Li ◽  
Guohu Guan ◽  
Yaonan Xiao ◽  
Dong Zhang
Keyword(s):  
Thermal Stability ◽  
Ethylene Terephthalate ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene ◽  
Thermal Stability Of

scholarly journals Sizing and Thermal Stability of Prepared Tetraaminophthalocyaninatocopper(II) Derivatives-grafted Polymers

2016 ◽  
Vol 13 (2) ◽  
pp. 221-234
Author(s):  
Baghdad Science Journal
Keyword(s):  
Thermal Stability ◽  
Ethylene Glycol ◽  
Group Analysis ◽  
Condensation Polymerization ◽  
Grafted Polymers ◽  
Poly Ethylene Glycol ◽  
Molecular Weights ◽  
Poly Ethylene ◽  
Thermal Stability Of ◽  
End Group

Different polymers were prepared by condensation polymerization of sebacic anhydride and adipic anhydride with ethylene glycol and poly(ethylene glycol). Their number average molecular weights were determined by end group analysis. Then, they were grafted on the prepared phthalocyaninatocopper(II) compounds with the general formula (NH2)4PcCu(II) having amino groups of 3,3',3'',3'''- or 4,4',4'',4'''- positions. All prepared polymers, compounds, and phthalocyaninatocopper(II)-grafted polymers were characterized by FTIR. The sizing measurements were carried out in 3,3',3'',3'''- (NH2)4PcCu(II) and 4,4',4'',4'''- (NH2)4PcCu(II) compounds with and without grafting polymers. The results showed that the grafting process led to decreasing in particle size and increasing in surface area. The grafting process was reflected positively on the thermal degradation of 3,3',3'',3'''- (NH2)4PcCu(II) and 4,4',4'',4'''- (NH2)4PcCu(II) grafted polymers. They had higher thermal stability accompanied with higher char residue and T50% weight loss with 3,3',3'',3'''-(NH2)4PcCu(II) and their grafted polymers being the best.

Application of ionic liquid [bmim]PF6 as green plasticizer for poly(L-lactide)

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Puyu Zhang ◽  
Lichao Peng ◽  
Wenbin Li
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Ionic Liquid ◽  
Glass Transition ◽  
Transition Temperature ◽  
Poly Ethylene Glycol ◽  
Scanning Calorimetry ◽  
Poly Ethylene ◽  
Thermal Stability Of ◽  
Better Than

AbstractIonic liquid [bmim]PF6 (1-butyl-3-methylimidazolium hexafluoro phosphate) was synthesized and characterized. It was used as the plasticizer for poly(L-lactide) (PLLA). The glass transition temperature (Tg) and the thermal stability of the plasticized PLLA samples were measured by thermogravimetry (TG) and differential scanning calorimetry (DSC). Compared with poly(ethylene glycol) having Mw of 300 g/mol (PEG300), TG results showed that the thermal stability of PLLA plasticized with ionic liquid was better than that of PLLA plasticized with PEG300. The Tg of plasticized PLLA decrease with increasing the content of ionic liquid [bmim]PF6 from 2 wt.% to 10 wt.%. The Tg of PLLA can be reduced to 40°C when the content of ionic liquid [bmim]PF6 was 10 wt.%. The materials of PLLA with plasticizer were also investigated using polarizing microscope (POM), the results of which indicate that the movements of PLLA chains were improved when ionic liquid plasticizer was used.

Effects of Halloysite Nanotubes on Mechanical and Thermal Stability of Poly(Ethylene Terephthalate)/Polycarbonate Nanocomposites

2015 ◽  
Vol 735 ◽  
pp. 8-12
Author(s):  
Nurul Ain Jamaludin ◽  
Azman Hassan ◽  
Norhayani Othman ◽  
Mohammad Jawaid
Keyword(s):  
Thermal Stability ◽  
Ethylene Terephthalate ◽  
Flexural Modulus ◽  
Halloysite Nanotubes ◽  
Mechanical And Thermal Properties ◽  
Poly Ethylene Terephthalate ◽  
Twin Screw ◽  
Poly Ethylene ◽  
The Impact ◽  
Thermal Stability Of

The objective of this study is to investigate the effect of halloysite nanotubes (HNTs) loading on mechanical and thermal properties of poly(ethylene terephthalate)/polycarbonate (PET/PC) nanocomposites. Nanocomposites containing 70PET/30PC and 2-8 phr HNTs were prepared by twin screw extruder followed by injection moulding. As the percentage of HNTs increased, the flexural modulus increased. However, the flexural strength decreased with increasing HNTs content. The impact strength also decreased when HNTs increased. Thermogravimetry analysis of PET/PC/HNTs nanocomposites showed higher thermal stability at high HNTs content. However, on further addition of HNTs up to 8 phr, thermal stability of the nanocomposites decreased due to the poor dispersion of HNTs.

Epoxy Resin (EP) / Nano-SiO2 Composite Material Preparation by Two Processes

2013 ◽  
Vol 652-654 ◽  
pp. 127-130
Author(s):  
Ying Na Zhao ◽  
Xiong Feng Zeng ◽  
Wen Li Zhang
Keyword(s):  
Thermal Stability ◽  
Composite Material ◽  
Comprehensive Evaluation ◽  
Sol Gel ◽  
Curing Agent ◽  
Spectra Analysis ◽  
Nano Sio2 ◽  
Ep Matrix ◽  
Material Preparation ◽  
Thermal Stability Of

Ultrasonic wave (UW) and sol-gel (SG) technology were using to preprocess the nano-SiO2, and the SiO2/EP composites were prepared by adding coupling agent KH-550, curing agent T-31 and different contents SiO2 into EP matrix. Using infrared spectra analysis tested the samples’ structures and the thermal stability of two preparation processes were tested by TG. The results indicated that, the thermal stability of the SiO2/EP composites by UW preprocess was improved about 25 oC -60 oC when compared with pure EP and the SiO2/EP composites by SG. Comparing to the comprehensive evaluation of thermal stability of different SiO2 contents SiO2/EP composites, the most optimum additive of nano-SiO2 was about 10 wt. % by UW process.

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