Tunable pseudocapacitance storage of MXene by cation pillaring for high performance sodium-ion capacitors

2018 ◽  
Vol 6 (17) ◽  
pp. 7794-7806 ◽  
Author(s):  
Jianmin Luo ◽  
Cong Fang ◽  
Chengbin Jin ◽  
Huadong Yuan ◽  
Ouwei Sheng ◽  
...  

2D transition metal carbide materials called MXene have attracted significant interest in the field of electrochemical energy storage due to their high electrical conductivity and high volumetric capacity.

ACS Nano ◽  
2019 ◽  
Vol 13 (8) ◽  
pp. 8804-8810 ◽  
Author(s):  
Yajie Yang ◽  
Jaeho Jeon ◽  
Jin-Hong Park ◽  
Mun Seok Jeong ◽  
Byoung Hun Lee ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Xining Zang ◽  
Cuiying Jian ◽  
Taishan Zhu ◽  
Zheng Fan ◽  
Wanlin Wang ◽  
...  

2016 ◽  
Vol 3 (5) ◽  
pp. 689-693 ◽  
Author(s):  
Chang E. Ren ◽  
Meng-Qiang Zhao ◽  
Taron Makaryan ◽  
Joseph Halim ◽  
Muhammad Boota ◽  
...  

ACS Nano ◽  
2020 ◽  
Vol 14 (9) ◽  
pp. 10834-10864 ◽  
Author(s):  
Kang Rui Garrick Lim ◽  
Albertus D. Handoko ◽  
Srinivasa Kartik Nemani ◽  
Brian Wyatt ◽  
Hai-Ying Jiang ◽  
...  

2016 ◽  
Vol 3 (5) ◽  
pp. 847-847 ◽  
Author(s):  
Chang E. Ren ◽  
Meng-Qiang Zhao ◽  
Taron Makaryan ◽  
Joseph Halim ◽  
Muhammad Boota ◽  
...  

2018 ◽  
Vol 5 (5) ◽  
pp. 999-1015 ◽  
Author(s):  
Shelby Boyd ◽  
Veronica Augustyn

This work illustrates the obstacles that must be overcome and the benefits offered by aqueous rechargeable Na+ electrochemical energy storage.


2021 ◽  
Vol 118 (22) ◽  
pp. e2025044118
Author(s):  
Arghya Patra ◽  
Jerome Davis ◽  
Saran Pidaparthy ◽  
Manohar H. Karigerasi ◽  
Beniamin Zahiri ◽  
...  

We introduce an intermediate-temperature (350 °C) dry molten sodium hydroxide-mediated binder-free electrodeposition process to grow the previously electrochemically inaccessible air- and moisture-sensitive layered sodium transition metal oxides, NaxMO2 (M = Co, Mn, Ni, Fe), in both thin and thick film form, compounds which are conventionally synthesized in powder form by solid-state reactions at temperatures ≥700 °C. As a key motivation for this work, several of these oxides are of interest as cathode materials for emerging sodium-ion–based electrochemical energy storage systems. Despite the low synthesis temperature and short reaction times, our electrodeposited oxides retain the key structural and electrochemical performance observed in high-temperature bulk synthesized materials. We demonstrate that tens of micrometers thick >75% dense NaxCoO2 and NaxMnO2 can be deposited in under 1 h. When used as cathodes for sodium-ion batteries, these materials exhibit near theoretical gravimetric capacities, chemical diffusion coefficients of Na+ ions (∼10−12 cm2⋅s−1), and high reversible areal capacities in the range ∼0.25 to 0.76 mA⋅h⋅cm−2, values significantly higher than those reported for binder-free sodium cathodes deposited by other techniques. The method described here resolves longstanding intrinsic challenges associated with traditional aqueous solution-based electrodeposition of ceramic oxides and opens a general solution chemistry approach for electrochemical processing of hitherto unexplored air- and moisture-sensitive high valent multinary structures with extended frameworks.


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