Hypercrosslinked mesoporous poly(ionic liquid)s with high ionic density for efficient CO2 capture and conversion into cyclic carbonates

2018 ◽  
Vol 6 (15) ◽  
pp. 6660-6666 ◽  
Author(s):  
Yaqiang Xie ◽  
Jun Liang ◽  
Yawen Fu ◽  
Mengting Huang ◽  
Xun Xu ◽  
...  

Hypercrosslinked MPILs with high ionic density and excellent textural properties were prepared for efficient simultaneous CO2 adsorption and cycloaddition.

2017 ◽  
Vol 5 (48) ◽  
pp. 25594-25600 ◽  
Author(s):  
Yaqiang Xie ◽  
Qing Sun ◽  
Yawen Fu ◽  
Lei Song ◽  
Jun Liang ◽  
...  

Novel sponge-like ammonium-based PILs with rich exposed anion, excellent textural properties, and CO2 adsorption were prepared for efficient CO2 cycloaddition.


Author(s):  
Haibin Gou ◽  
Xifei Ma ◽  
Qian Su ◽  
Lei Liu ◽  
Ting Ying ◽  
...  

The development of metal-free, high effective and recyclable catalysts plays a pivotal role in transforming CO2 into high value-added products such as cyclic carbonates. In this paper, we have introduced...


2021 ◽  
Author(s):  
Alaa F. Eftaiha ◽  
Abdussalam K. Qaroush ◽  
Areej K. Hasan ◽  
Khaleel I. Assaf ◽  
Feda'a Al-Qaisi ◽  
...  

CO2 is the most influential greenhouse gas with its drastic effects all over the world. Meanwhile, global warming is considered as a hot topic to different slices of scientists dealing...


2019 ◽  
Vol 16 ◽  
pp. 39-46 ◽  
Author(s):  
Xianjing Zhou ◽  
Jens Weber ◽  
Jiayin Yuan

Author(s):  
Yizhen Zou ◽  
Yuansheng Ge ◽  
Qiang Zhang ◽  
Wei Liu ◽  
Xiaoguang Li ◽  
...  

Global warming is becoming a challenging issue due to the emissions of large number of greenhouse gases, mainly CO2. The transformation of CO2 into chemicals with high additional value is...


2015 ◽  
Vol 6 (12) ◽  
pp. 6916-6924 ◽  
Author(s):  
Xiaochen Wang ◽  
Yu Zhou ◽  
Zengjing Guo ◽  
Guojian Chen ◽  
Jing Li ◽  
...  

Meso-macroporous hierarchical poly(ionic liquid)s are ionothermally synthesized through self-polymerization of the new divinylimidazole IL, exhibiting enhanced CO2 capture and excellent activity in the cycloaddition of CO2 to epoxides.


2021 ◽  
Vol 23 (1) ◽  
pp. 200
Author(s):  
Raquel V. Barrulas ◽  
Clara López-Iglesias ◽  
Marcileia Zanatta ◽  
Teresa Casimiro ◽  
Gonzalo Mármol ◽  
...  

CO2 levels in the atmosphere are increasing exponentially. The current climate change effects motivate an urgent need for new and sustainable materials to capture CO2. Porous materials are particularly interesting for processes that take place near atmospheric pressure. However, materials design should not only consider the morphology, but also the chemical identity of the CO2 sorbent to enhance the affinity towards CO2. Poly(ionic liquid)s (PILs) can enhance CO2 sorption capacity, but tailoring the porosity is still a challenge. Aerogel’s properties grant production strategies that ensure a porosity control. In this work, we joined both worlds, PILs and aerogels, to produce a sustainable CO2 sorbent. PIL-chitosan aerogels (AEROPILs) in the form of beads were successfully obtained with high porosity (94.6–97.0 %) and surface areas (270–744 m2/g). AEROPILs were applied for the first time as CO2 sorbents. The combination of PILs with chitosan aerogels generally increased the CO2 sorption capability of these materials, being the maximum CO2 capture capacity obtained (0.70 mmol g−1, at 25 °C and 1 bar) for the CHT:P[DADMA]Cl30% AEROPIL.


Carbon ◽  
2017 ◽  
Vol 124 ◽  
pp. 730
Author(s):  
Lei Liu ◽  
Juan Lu ◽  
Yi-xin Zhang ◽  
Meng Liu ◽  
Yi-feng Yu ◽  
...  

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