3D printing multifunctional fluorinated nanocomposites: tuning electroactivity, rheology and chemical reactivity

2018 ◽  
Vol 6 (26) ◽  
pp. 12308-12315 ◽  
Author(s):  
Jose A. Bencomo ◽  
Scott T. Iacono ◽  
Jena McCollum
Keyword(s):  
3D Printing ◽  
Methyl Methacrylate ◽  
Flow Rate ◽  
Fused Deposition Modeling ◽  
Vinylidene Fluoride ◽  
Chemical Reactivity ◽  
Melt Flow Rate ◽  
Fused Deposition ◽  
Poly Vinylidene Fluoride ◽  
Deposition Modeling

Poly(methyl methacrylate) (PMMA) was added to aluminum/poly(vinylidene fluoride) (Al/PVDF) energetic blends to enhance melt flow rate and adhesion in a fused deposition modeling (FDM) manufacturing scenario.

scholarly journals Proper Blends of Biodegradable Polycaprolactone and Natural Rubber for 3D Printing

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2416
Author(s):  
Thossapit Wissamitanan ◽  
Charoenyutr Dechwayukul ◽  
Ekwipoo Kalkornsurapranee ◽  
Wiriya Thongruang
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Natural Rubber ◽  
Shape Recovery ◽  
Fused Deposition Modeling ◽  
Melt Flow ◽  
Melt Flow Rate ◽  
Fused Deposition ◽  
Compression Set ◽  
Deposition Modeling

Flexible thermoplastic elastomers (TPE) were prepared for fused deposition modeling (FDM) or 3D printing. These materials can be used for medical purposes such as disposable soft splints and other flexible devices. Blends of 50% epoxidized natural rubber (ENR-50) and block rubber (Standard Thai Rubber 5L (STR5L)) with polycaprolactone (PCL) were produced and compared. The purpose of this study was to investigate the properties of natural rubber (NR) and PCL in simple blends with PCL contents of 40%, 50%, and 60% by weight (except at 75% for morphology study) in the base mixture (NR/PCL). The significant flow factors for FDM materials, such as melting temperature (Tm) and melt flow rate (MFR), were observed by differential scanning calorimetry (DSC) and via the melt flow index (MFI). In addition, the following mechanical properties were also determined: tensile strength, compression set, and hardness. The results from DSC showed that the melting temperature changed slightly (1–2 °C) with amount of PCL used, and there was a suspicious point in the 50/50 blends with both types of rubber. The lowest melting enthalpy of both blends was found at the 50/50 blended composition. The MFI results showed that PCL significantly affected the melt flow rate of both blends. The ENR-50/PCL blend flowed better than the STR5L/PCL blend. The conclusion was that this was due to the morphology of its phase structure having better uniformity than that of the STR5L/PCL blend. In compression set testing or measuring shape recovery, rubber directly influenced the recovery in all blends. The ENR-50/PCL blend had less recovery than the STR5L/PCL blend, probably due to the functional effects of epoxide groups and polarity mismatch. The hard phase PCL significantly affected the hardness of samples but improved shape recovery of the material. The ENR-50/PCL blend had better tensile properties than the STR5L/PCL blend. The elongation at break of both blends improved with a high rubber content. Hence, the ENR-50/PCL blend was superior to STR5L/PCL for printing purposes due to its better miscibility, uniformity, and flow, which are the keys to success for optimizing the fused deposition modeling conditions as well as the overall mechanical properties of products. Most blends in this study were only slightly different, but the 50/50 blend of ENR-50/PCL seemed to be near optimal for 3D printing.

scholarly journals Filament Extrusion and Its 3D Printing of Poly(Lactic Acid)/Poly(Styrene-co-Methyl Methacrylate) Blends

2019 ◽  
Vol 9 (23) ◽  
pp. 5153 ◽  
Author(s):  
Luis Enrique Solorio-Rodríguez ◽  
Alejandro Vega-Rios
Keyword(s):  
Thermal Decomposition ◽  
Lactic Acid ◽  
3D Printing ◽  
Methyl Methacrylate ◽  
Fused Deposition Modeling ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Rheological Characterization ◽  
Fused Deposition ◽  
Deposition Modeling

Herein, we report the melt blending of amorphous poly(lactide acid) (PLA) with poly(styrene-co-methyl methacrylate) (poly(S-co-MMA)). The PLAx/poly(S-co-MMA)y blends were made using amorphous PLA compositions from 50, 75, and 90wt.%, namely PLA50/poly(S-co-MMA)50, PLA75/poly(S-co-MMA)25, and PLA90/poly(S-co-MMA)10, respectively. The PLAx/poly(S-co-MMA)y blend pellets were extruded into filaments through a prototype extruder at 195 °C. The 3D printing was done via fused deposition modeling (FDM) at the same temperature and a 40 mm/s feed rate. Furthermore, thermogravimetric curves of the PLAx/poly(S-co-MMA)y blends showed slight thermal decomposition with less than 0.2% mass loss during filament extrusion and 3D printing. However, the thermal decomposition of the blends is lower when compared to amorphous PLA and poly(S-co-MMA). On the contrary, the PLAx/poly(S-co-MMA)y blend has a higher Young’s modulus (E) than amorphous PLA, and is closer to poly(S-co-MMA), in particular, PLA90/poly(S-co-MMA)10. The PLAx/poly(S-co-MMA)y blends proved improved properties concerning amorphous PLA through mechanical and rheological characterization.

Biodegradable 3D Printed Polymer Microneedles for Transdermal Drug Delivery

2018 ◽  
Author(s):  
Michael A. Luzuriaga ◽  
Danielle R. Berry ◽  
John C. Reagan ◽  
Ronald A. Smaldone ◽  
Jeremiah J. Gassensmith
Keyword(s):  
Drug Delivery ◽  
3D Printing ◽  
Transdermal Drug Delivery ◽  
Fused Deposition Modeling ◽  
Fused Deposition ◽  
Modeling Software ◽  
Deposition Modeling ◽  
3D Printed ◽  
Microfabrication Technique ◽  
Mechanical Strengths

Biodegradable polymer microneedle (MN) arrays are an emerging class of transdermal drug delivery devices that promise a painless and sanitary alternative to syringes; however, prototyping bespoke needle architectures is expensive and requires production of new master templates. Here, we present a new microfabrication technique for MNs using fused deposition modeling (FDM) 3D printing using polylactic acid, an FDA approved, renewable, biodegradable, thermoplastic material. We show how this natural degradability can be exploited to overcome a key challenge of FDM 3D printing, in particular the low resolution of these printers. We improved the feature size of the printed parts significantly by developing a post fabrication chemical etching protocol, which allowed us to access tip sizes as small as 1 μm. With 3D modeling software, various MN shapes were designed and printed rapidly with custom needle density, length, and shape. Scanning electron microscopy confirmed that our method resulted in needle tip sizes in the range of 1 – 55 µm, which could successfully penetrate and break off into porcine skin. We have also shown that these MNs have comparable mechanical strengths to currently fabricated MNs and we further demonstrated how the swellability of PLA can be exploited to load small molecule drugs and how its degradability in skin can release those small molecules over time.

scholarly journals 3D Printing of Mini Tablets for Pediatric Use

2021 ◽  
Vol 14 (2) ◽  
pp. 143
Author(s):  
Julius Krause ◽  
Laura Müller ◽  
Dorota Sarwinska ◽  
Anne Seidlitz ◽  
Malgorzata Sznitowska ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Dosage Forms ◽  
Small Scale ◽  
Fused Deposition ◽  
On Demand ◽  
Pediatric Diseases ◽  
Deposition Modeling ◽  
Manufacturing Techniques ◽  
Pediatric Use

In the treatment of pediatric diseases, suitable dosages and dosage forms are often not available for an adequate therapy. The use of innovative additive manufacturing techniques offers the possibility of producing pediatric dosage forms. In this study, the production of mini tablets using fused deposition modeling (FDM)-based 3D printing was investigated. Two pediatric drugs, caffeine and propranolol hydrochloride, were successfully processed into filaments using hyprolose and hypromellose as polymers. Subsequently, mini tablets with diameters between 1.5 and 4.0 mm were printed and characterized using optical and thermal analysis methods. By varying the number of mini tablets applied and by varying the diameter, we were able to achieve different release behaviors. This work highlights the potential value of FDM 3D printing for the on-demand production of patient individualized, small-scale batches of pediatric dosage forms.

Influence of Part Orientation on the Surface Roughness in the Process of Fused Deposition Modeling

2021 ◽  
Vol 896 ◽  
pp. 29-37
Author(s):  
Ján Milde ◽  
František Jurina ◽  
Jozef Peterka ◽  
Patrik Dobrovszký ◽  
Jakub Hrbál ◽  
...  
Keyword(s):  
Surface Roughness ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Orientation Angle ◽  
Acrylonitrile Butadiene Styrene ◽  
Lower Surface ◽  
Geometrical Model ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Part Orientation

The article focused on the influence of part orientation on the surface roughness of cuboid parts during the process of fabricating by FDM technology. The components, in this case, is simple cuboid part with the dimensions 15 mm x 15mm x 30 mm. A geometrical model is defined that considers the shape of the material filaments after deposition, to define a theoretical roughness profile, for a certain print orientation angle. Five different print orientations in the X-axis of the cuboid part were set: 0°, 30°, 45°, 60°, and 90°. According to previous research in the field of FDM technology by the author, the internal structure (infill) was set at the value of 70%. The method of 3D printing was the Fused Deposition Modeling (FDM) and the material used in this research was thermoplastic ABS (Acrylonitrile butadiene styrene). For each setting, there were five specimens (twenty five prints in total). Prints were fabricated on a Zortrax M200 3D printer. After the 3D printing, the surface “A” was investigated by portable surface roughness tester Mitutoyo SJ-210. Surface roughness in the article is shown in the form of graphs (Fig.7). Results show increase in part roughness with increasing degree of part orientation. When the direction of applied layers on the measured surface was horizontal, significant improvement in surface roughness was observed. Findings in this paper can be taken into consideration when designing parts, as they can contribute in achieving lower surface roughness values.

Understanding and improving FDM 3D printing to fabricate high-resolution and optically transparent microfluidic devices

Lab on a Chip ◽  
2021 ◽  
Author(s):  
Reverson Fernandes Quero ◽  
Gessica Domingos Silveira ◽  
Jose Alberto Fracassi da Silva ◽  
Dosil Pereira de Jesus
Keyword(s):  
High Resolution ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Microfluidic Devices ◽  
Fused Deposition ◽  
Optically Transparent ◽  
Deposition Modeling

The fabrication of microfluidic devices through Fused Deposition Modeling (FDM) 3D printing has faced several challenges, mainly regarding obtaining microchannels with suitable transparency and sizes. Thus, the use of this...

Hochproduktiver fertigungsangepasster 3D-Druck/Productive and manufacturing adjusted 3D printing

2017 ◽  
Vol 107 (07-08) ◽  
pp. 520-523
Author(s):  
J. Prof. Bliedtner ◽  
M. Schilling
Keyword(s):  
3D Printing ◽  
Research And Development ◽  
Fused Deposition Modeling ◽  
Dynamic Properties ◽  
Development Project ◽  
Efficient Production ◽  
Large Format ◽  
Printing Process ◽  
Fused Deposition ◽  
Deposition Modeling

Das FDM (Fused Deposition Modeling)-Verfahren ist aufgrund der Vielzahl von industriellen und privaten Anwendungen gegenwärtig das erfolgreichste 3D-Druck-Verfahren. Ziel des Forschungs- und Entwicklungsprojektes „HP3D“ ist die effiziente Herstellung von großformatigen Bauteilen in einem echten 3D-Verfahren aus frei wählbaren thermoplastischen Kunststoffen. An die Umsetzung des Projekts wurde sehr komplex herangegangen, um zu garantieren, dass die mechanischen und dynamischen Eigenschaften der aufgebauten Teile den konzipierten Eigenschaften entsprechen.   The FDM process is currently the most successful 3D printing process due to the multitude of industrial and private applications. The aim of the research and development project HP3D is the efficient production of large-format components in a real 3D process made of freely selectable thermoplastics. The implementation of the project has been very complex in order to ensure that the mechanical and dynamic properties of the assembled parts correspond to the designed properties.

Sign in / Sign up

Export Citation Format

Share Document