Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer

2018 ◽  
Vol 6 (15) ◽  
pp. 6455-6462 ◽  
Author(s):  
Mahmoud M. Abdelnaby ◽  
Ahmed M. Alloush ◽  
Naef A. A. Qasem ◽  
Bassem A. Al-Maythalony ◽  
Rached B. Mansour ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Organic Materials ◽  
Carbon Dioxide Capture ◽  
Porous Polymer ◽  
Gas Mixture

A new cross-linked porous polymer was synthesized and its performance in the capture of carbon dioxide from a ternary gas mixture was demonstrated, and properties retained for over 45 cycles. This report represents one of the top performing porous organic materials for carbon capture.

The Evaluation and Comparison of Carbon Dioxide Capture Technologies Applied to FCC Flue Gas

2011 ◽  
Vol 347-353 ◽  
pp. 1479-1482 ◽  
Author(s):  
Pu Peng ◽  
Yi Zhuang
Keyword(s):  
Carbon Dioxide ◽  
Flue Gas ◽  
Co2 Emission ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Carbon Capture And Storage ◽  
Commercial Success ◽  
Green House ◽  
Co2 Capturing ◽  
And Storage

The CO2 capturing technologies as applied to FCC flue gas in order to reduce GHG (green house gases) were evaluated and compared in this review. Although the CCS (carbon capture and storage) idea has been proposed for more than 30 years, there has been little commercial success of CCS projects. The largest issue is where to store the massive amount of captured pure CO2 every year. Therefore, the review will focus on the efficient use of power or heat to reduce CO2 emission and how to recycle the use of produced CO2 before it is emitted to the atmosphere rather than being captured and stored. The scenarios with oxyfiring, microalgae-cofiring or biogas burning to treat FCC flue gas are introduced and discussed.

Greener Solvent Selection and Solvent Recycling for Carbon Dioxide Capture

2012 ◽  
Vol 5 (1) ◽  
Author(s):  
G. Hachem ◽  
J. Salazar ◽  
U. Dixekar
Keyword(s):  
Carbon Dioxide ◽  
Simulated Annealing ◽  
Carbon Capture ◽  
Power Plants ◽  
Carbon Dioxide Capture ◽  
Carbon Capture And Storage ◽  
Aspen Plus ◽  
Solvent Selection ◽  
Carbon Dioxide Co2 ◽  
And Storage

Carbon capture and storage (CCS) constitutes an extremely important technology that is constantly being improved to minimize the amounts of carbon dioxide (CO2) entering the atmosphere. According to the Global CCS Institute, there are more than 320 worldwide CCS projects at different phases of progress. However, current CCS processes are accompanied with a large energy and efficiency penalty. This paper models and simulates a post-combustion carbon capture system, that uses absorption as a method of separation, in Aspen Plus V7.2. Moreover, the CAPE-OPEN Simulated Annealing (SA) Capability is implemented to minimize the energy consumed by this system, and allow coal-fired power plants to use similar carbon capture systems without losing 20 to 40 % of the plant's output.

Hydrate-Based Carbon Capture Process: Assessment of Various Packed Bed Systems for Boosted Kinetics of Hydrate Formation

2020 ◽  
Vol 143 (3) ◽  
Author(s):  
Amit Arora ◽  
Asheesh Kumar ◽  
Gaurav Bhattacharjee ◽  
Chandrajit Balomajumder ◽  
Pushpendra Kumar
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Fixed Bed ◽  
Hydrate Formation ◽  
Packed Bed ◽  
Fixed Bed Reactor ◽  
Capture Process ◽  
Novel Technologies ◽  
Kinetics Of

Abstract The case for developing novel technologies for carbon dioxide (CO2) capture is fast gaining traction owing to increasing levels of anthropogenic CO2 being emitted into the atmosphere. Here, we have studied the hydrate-based carbon dioxide capture and separation process from a fundamental viewpoint by exploring the use of various packed bed media to enhance the kinetics of hydrate formation using pure CO2 as the hydrate former. We established the fixed bed reactor (FBR) configuration as a superior option over the commonly used stirred tank reactor (STR) setups typically used for hydrate formation studies by showing enhanced hydrate formation kinetics using the former. For the various packing material studied, we have observed silica gel with 100 nm pore size to return the best kinetic performance, corresponding to a water to hydrate conversion of 28 mol% for 3 h of hydrate growth. The fundamental results obtained in the present study set up a solid foundation for follow-up works with a more applied perspective and should be of interest to researchers working in the carbon dioxide capture and storage and gas hydrate fields alike.

Carbon capture and conversion using metal–organic frameworks and MOF-based materials

2019 ◽  
Vol 48 (10) ◽  
pp. 2783-2828 ◽  
Author(s):  
Meili Ding ◽  
Robinson W. Flaig ◽  
Hai-Long Jiang ◽  
Omar M. Yaghi
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structure Property ◽  
Property Relationship ◽  
Recent Advances ◽  
Structure Property Relationship ◽  
Metal Organic

This review summarizes recent advances and highlights the structure–property relationship on metal–organic framework-based materials for carbon dioxide capture and conversion.

Carbon Dioxide Capture Using Sorbent-Loaded Hollow-Fiber Modules for Coal-Fired Power Plants

2021 ◽  
pp. 1-28
Author(s):  
Bachir El Fil ◽  
Dhruv C. Hoysall ◽  
Srinivas Garimella
Keyword(s):  
Carbon Dioxide ◽  
Power Plant ◽  
Hollow Fiber ◽  
Carbon Capture ◽  
Power Plants ◽  
Carbon Dioxide Capture ◽  
Electrical Energy ◽  
Parasitic Load ◽  
Temperature Swing Adsorption ◽  
The Impact

Abstract The impact of post-combustion carbon dioxide capture on the performance of a power plant is evaluated. A model of a coal power plant with post-combustion temperature swing adsorption CO2 capture using sorbent-loaded hollow fibers is presented. The resulting performance and cost of carbon capture are compared with those of other adsorption-based technologies. A parametric analysis of the performance of the power plant with respect to key parameters in the hollow fiber module operation is presented. It is found that electrical energy consumption for the compression of CO2 is a major parasitic load common to all absorption technologies and accounts for almost half of the total parasitic load. The effect of source temperature, flue gas fan and coupling fluid pump flow rates on overall system performance is presented. The impacts of different carbon capture technologies on the same coal-fired power plant are compared. Hollow fiber modules had the lowest parasitic load on the power plant, followed by KS-2 based carbon capture.

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas

2012 ◽  
Vol 124 (30) ◽  
pp. 7598-7602 ◽  
Author(s):  
Weigang Lu ◽  
Julian P. Sculley ◽  
Daqiang Yuan ◽  
Rajamani Krishna ◽  
Zhangwen Wei ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Flue Gas ◽  
Carbon Dioxide Capture ◽  
Polymer Networks ◽  
Porous Polymer

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas

2012 ◽  
Vol 51 (30) ◽  
pp. 7480-7484 ◽  
Author(s):  
Weigang Lu ◽  
Julian P. Sculley ◽  
Daqiang Yuan ◽  
Rajamani Krishna ◽  
Zhangwen Wei ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Flue Gas ◽  
Carbon Dioxide Capture ◽  
Polymer Networks ◽  
Porous Polymer

Development Status and Energy Penalty of Carbon Dioxide Capture Technologies

2013 ◽  
Vol 864-867 ◽  
pp. 1598-1601 ◽  
Author(s):  
Ji Yong Liu ◽  
Xiao Feng Zhang ◽  
Ji Fa Zhang ◽  
Huan Liu ◽  
Fang Qin Li
Keyword(s):  
Carbon Dioxide ◽  
Global Warming ◽  
Greenhouse Gases ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Total Cost ◽  
Development Status ◽  
Energy Penalty

Carbon dioxide is claimed to be responsible for 60 percent of the global warming caused by greenhouse gases. CCS is important for reducing CO2emissions. Most technologies are in demonstration stage. Carbon capture accounts for two thirds of total cost of CCS. The trend of CCS is also described.

scholarly journals Synthesis of FeCo-MIL-88B and Investigate Its Potential for CO2 Capture

2019 ◽  
Vol 35 (1) ◽  
Author(s):  
Le Minh Cam ◽  
Le Van Khu ◽  
Nguyen Thi Thu Ha ◽  
Nguyen Ngoc Ha
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Mesoporous Materials ◽  
Co2 Capture ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Cobalt dopping Fe-MIL-88B were successfully synthesized -in solvothermal procedure using DMF as solvent and with/without NaOH. The samples were characterized using SEM, BET and TGA techniques. The partly substitution of Fe by Co does not change the octahedral shape of their parent Fe-MIL-88B. Crystallizations conducted in NaOH medium, however, results in rod like with 2-end octahedral shape crystals. The BET specific surface area is 139cm2/g. The TGA data indicated that the presence of Co resulted in an increase in thermal stability of synthesized samples compared to parent Fe-MIL-88B. The CO2 adsorption isotherms in Fe-MIL-88B-Co samples were measured volumetrically at five temperatures:278K, 288K, 298K, 308K, 318K. The obtained results showed that Fe-MIL-88B-Co is a potential adsorbent with a maximum adsortption capacity of 1.2312 mmol/g (at T= 278K). The sample synthesized in alkali medium exhibited a better adsorbent for CO2 storage. Keywords MIL, adsorption, CO2 References [1] S. Chu, Carbon Capture and Sequestration, Science325(2009)1599 [2] R.S. Haszeldine,Carbon Capture and Storage: How Green Can Black Be?, Science325(2009) 1647[3] D.M. D’Alessandro, B. Smit, J.R. Long,Carbon Dioxide Capture: Prospects for New Materials, Angewandte Chemie International Edition. 49(2010) 6058[4] S. Bai, J. Liu, J. Gao, Q. Yang Can Li,Hydrolysis controlled synthesis of amine-functionalized hollow ethane–silica nanospheres as adsorbents for CO2 capture, Microporous and Mesoporous Materials151(2012) 474[5] K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R.[6] Long,Carbon Dioxide Capture in Metal–Organic Frameworks, Chemical Reviews, 112(2012) 724[7] J.D. Carruthers, M.A. Petruska, E.A. Sturm, S.M. Wilson,Molecular sieve carbons for CO2 capture, Microporous and Mesoporous Materials,154 (2012) 62[8] X. Yan, L. Zhang, Y. Zhang, K. Qiao, Z. Yan, S. Komarneni,Amine-modified mesocellular silica foams for CO2 capture, Chemical Engineering Journal,168 (2011), 918[9] A. Zukal, C.O. Arean, M.R. Delgado, P. Nachtigall, A. Pulido, J. Mayerova, J. Cˇejka,Combined volumetric, infrared spectroscopic and theoretical investigation of CO2 adsorption on Na-A zeolite,Microporous and Mesoporous Materials 146 (2011) 97[10] S. Keskin, T.M. van Heest, D.S. Sholl, Can Metal–Organic Framework Materials Play a Useful Role in Large‐Scale Carbon Dioxide Separations?, ChemSusChem3 (2010) 879[11] T.M. McDonald, W.R. Lee, J.A. Mason, B.M. Wiers, C.S. Hong, J.R. Long, Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc), Journal of the American Chemical Society134 (2012) 7056[12] X. Yan, S. Komarneni, Z. Zhang, Z. Yan(2014),Extremely enhanced CO2 uptake by HKUST-1 metal–organic framework via a simple chemical treatment, Microporous and Mesoporous Materials183 (2014) 69–73[13] Gia-Thanh Vuong, Minh-Hao Pham and Trong-On Do*, Direct synthesis and mechanism of the formation of mixed metal Fe2Ni-MIL-88B†, CrystEngComm, DOI: 10.1039/c3ce41453a[14] Lê Văn Khu, Nguyễn Quốc Anh, Nguyễn Ngọc Hà, Lê Minh Cầm, Tổng hợp, đặc trưng và khảo sát khả năng hấp phụ CO2 của Fe-MIL-88B, Tạp chí xúc tác và hấp phụ 4 (1) (2015) 52[15] K. S. W. Sing, D. H. Everett, R. A. W. Hau et.al, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chemistry 57 (1985) 603

Carbon Dioxide Capture from Air Using Amine-Grafted Porous Polymer Networks

2013 ◽  
Vol 117 (8) ◽  
pp. 4057-4061 ◽  
Author(s):  
Weigang Lu ◽  
Julian P. Sculley ◽  
Daqiang Yuan ◽  
Rajamani Krishna ◽  
Hong-Cai Zhou
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Polymer Networks ◽  
Porous Polymer
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