Thermal transport in electrospun vinyl polymer nanofibers: effects of molecular weight and side groups

Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9534-9541 ◽  
Author(s):  
Yin Zhang ◽  
Xin Zhang ◽  
Lin Yang ◽  
Qian Zhang ◽  
Matthew L. Fitzgerald ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Molecular Weight ◽  
Chain Length ◽  
Thermal Transport ◽  
Molecular Chain ◽  
Polymer Nanofibers ◽  
Vinyl Polymer

Thermal conductivity increases with molecular chain length for PE nanofibers, and is higher for vinyl polymer nanofibers with lighter and more symmetric side groups.

Chain length effect on thermal transport in amorphous polymers and a structure–thermal conductivity relation

2019 ◽  
Vol 21 (28) ◽  
pp. 15523-15530 ◽  
Author(s):  
Xingfei Wei ◽  
Tengfei Luo
Keyword(s):  
Thermal Conductivity ◽  
Chain Length ◽  
Thermal Transport ◽  
Heat Exchangers ◽  
Amorphous Polymers ◽  
Electronics Packaging ◽  
Length Effect

The physics of thermal transport in polymers is important in many applications, such as in heat exchangers and electronics packaging.

scholarly journals Decoupling electron and phonon transport in single-nanowire hybrid materials for high-performance thermoelectrics

2021 ◽  
Vol 7 (20) ◽  
pp. eabe6000
Author(s):  
Lin Yang ◽  
Madeleine P. Gordon ◽  
Akanksha K. Menon ◽  
Alexandra Bruefach ◽  
Kyle Haas ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Transport ◽  
Electrical Transport ◽  
High Performance ◽  
Figure Of Merit ◽  
Phonon Transport ◽  
Core Shell ◽  
Nanowire Diameter ◽  
High Performing ◽  
Polycrystalline Thin Films

Organic-inorganic hybrids have recently emerged as a class of high-performing thermoelectric materials that are lightweight and mechanically flexible. However, the fundamental electrical and thermal transport in these materials has remained elusive due to the heterogeneity of bulk, polycrystalline, thin films reported thus far. Here, we systematically investigate a model hybrid comprising a single core/shell nanowire of Te-PEDOT:PSS. We show that as the nanowire diameter is reduced, the electrical conductivity increases and the thermal conductivity decreases, while the Seebeck coefficient remains nearly constant—this collectively results in a figure of merit, ZT, of 0.54 at 400 K. The origin of the decoupling of charge and heat transport lies in the fact that electrical transport occurs through the organic shell, while thermal transport is driven by the inorganic core. This study establishes design principles for high-performing thermoelectrics that leverage the unique interactions occurring at the interfaces of hybrid nanowires.

scholarly journals Impact of Macrodiols on the Morphological Behavior of H12MDI/HDO-Based Polyurethane Elastomer

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2060
Author(s):  
Shazia Naheed ◽  
Mohammad Zuber ◽  
Mahwish Salman ◽  
Nasir Rasool ◽  
Zumaira Siddique ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Contact Angle ◽  
Chain Length ◽  
Microphase Separation ◽  
Soft Segment ◽  
Group Identification ◽  
Degree Of Crystallinity ◽  
Polyurethane Elastomers ◽  
Hard Segments ◽  
Morphological Behavior

In this study, we evaluated the morphological behavior of polyurethane elastomers (PUEs) by modifying the soft segment chain length. This was achieved by increasing the soft segment molecular weight (Mn = 400–4000 gmol−1). In this regard, polycaprolactone diol (PCL) was selected as the soft segment, and 4,4′-cyclohexamethylene diisocyanate (H12MDI) and 1,6-hexanediol (HDO) were chosen as the hard segments. The films were prepared by curing polymer on Teflon surfaces. Fourier transform infrared spectroscopy (FTIR) was utilized for functional group identification in the prepared elastomers. FTIR peaks indicated the disappearance of −NCO and −OH groups and the formation of urethane (NHCOO) groups. The morphological behavior of the synthesized polymer samples was also elucidated using scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The AFM and SEM results indicated that the extent of microphase separation was enhanced by an increase in the molecular weight of PCL. The phase separation and degree of crystallinity of the soft and hard segments were described using X-ray diffraction (XRD). It was observed that the degree of crystallinity of the synthesized polymers increased with an increase in the soft segment’s chain length. To evaluate hydrophilicity/hydrophobicity, the contact angle was measured. A gradual increase in the contact angle with distilled water and diiodomethane (38.6°–54.9°) test liquids was observed. Moreover, the decrease in surface energy (46.95–24.45 mN/m) was also found to be inconsistent by increasing the molecular weight of polyols.

scholarly journals Study of anisotropic thermal conductivity in textured thermoelectric alloys by Raman spectroscopy

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 24456-24465
Author(s):  
Rapaka S. C. Bose ◽  
K. Ramesh
Keyword(s):  
Crystal Structure ◽  
Thermal Conductivity ◽  
Raman Spectroscopy ◽  
Transport Properties ◽  
Thermal Transport ◽  
Layered Crystal ◽  
Layered Crystal Structure ◽  
Thermal Transport Properties ◽  
Anisotropic Thermal Conductivity ◽  
P Type

Polycrystalline p-type Sb1.5Bi0.5Te3 (SBT) and n-type Bi2Te2.7Se0.3 (BTS) compounds possessing layered crystal structure show anisotropic electronic and thermal transport properties.

La2O3 Doped Y2O3 Stabilized ZrO2 TBC Prepared by EB-PVD

2006 ◽  
Vol 317-318 ◽  
pp. 501-504 ◽  
Author(s):  
Mineaki Matsumoto ◽  
Norio Yamaguchi ◽  
Hideaki Matsubara
Keyword(s):  
Thermal Conductivity ◽  
High Temperature ◽  
High Resistance ◽  
Thermal Transport ◽  
Temperature Stability ◽  
High Temperature Stability ◽  
Microstructural Observation ◽  
Low Thermal Conductivity ◽  
Ysz Coating

Effect of La2O3 addition on thermal conductivity and high temperature stability of YSZ coating produced by EB-PVD was investigated. La2O3 was selected as an additive because it had a significant effect on suppressing densification of YSZ. The developed coating showed extremely low thermal conductivity as well as high resistance to sintering. Microstructural observation revealed that the coating had fine feather-like subcolumns and nanopores, which contributed to limit thermal transport. These nanostructures were thought to be formed by suppressing densification during deposition.

Constructing Three-dimensional Nano-crystalline Diamond Network within Polymer Composites for Enhanced Thermal Conductivity

Nanoscale ◽  
2021 ◽  
Author(s):  
Shaoyang Xiong ◽  
Yue Qin ◽  
Linhong Li ◽  
Guoyong Yang ◽  
Maohua Li ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Polymer Composites ◽  
Thermal Performance ◽  
Thermal Transport ◽  
High Performance ◽  
Rapid Development ◽  
Electronic Devices ◽  
Three Dimensional ◽  
Nano Crystalline ◽  
Enhanced Thermal Conductivity

In order to meet the requirement of thermal performance with the rapid development of high-performance electronic devices, constructing a three-dimensional thermal transport skeleton is an effective method for enhancing thermal...

scholarly journals Comparative study of thermal transport in Zea mays straw and Zea mays heartwood (cork) boards

2010 ◽  
Vol 14 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Sunday Etuk ◽  
Louis Akpabio ◽  
Ita Akpan
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Zea Mays ◽  
Thermal Diffusivity ◽  
Comparative Study ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Thermal Transport ◽  
Insulation Material ◽  
Thermal Absorptivity

Thermal conductivity values at the temperature of 301-303K have been measured for Zea mays straw board as well as Zea mays heartwood (cork) board. Comparative study of the thermal conductivity values of the boards reveal that Zea mays heartwood board has a lower thermal conductivity value to that of the straw board. The study also shows that the straw board is denser than the heartwood board. Specific heat capacity value is less in value for the heartwood board than the straw board. These parameters also affect the thermal diffusivity as well as thermal absorptivity values for the two types of boards. The result favours the two boards as thermal insulators for thermal envelop but with heartwood board as a preferred insulation material than the straw board.

scholarly journals Impact of Noble-Gas Filler Atoms on the Lattice Thermal Conductivity of CoSb3 Skutterudites: First-Principles Modelling

2020 ◽  
Author(s):  
Jianqin Tang ◽  
Jonathan Skelton
Keyword(s):  
Thermal Conductivity ◽  
First Principles ◽  
Thermal Transport ◽  
Noble Gas ◽  
Detailed Balance ◽  
Resonant Scattering ◽  
Acoustic Mode ◽  
Cage Compounds ◽  
Mode Dispersion ◽  
Group Velocities

We present a systematic first-principles modelling study of the structural dynamics and thermal transport in the CoSb<sub>3</sub> skutterudites with a series of noble-gas filler atoms. A range of analysis techniques are proposed to estimate the filler rattling frequencies, to quantify the separate impacts of filling on the phonon group velocities and lifetimes, and to show how changes to the phonon spectra and interaction strengths lead to suppressed lifetimes. The fillers are found to reduce the thermal conductivity of the CoSb<sub>3</sub> framework by up to 15 % primarily by suppressing the group velocities of low-lying optic modes. Calculations show that the filler rattling frequencies are determined by a detailed balance of increasing atomic mass and stronger interactions with the framework, and are a good predictor of their impact on the heat transport. Lowering the rattling frequency below ~1.5 THz by selecting heavy fillers that interact weakly with the framework is predicted to produce a much larger suppression of the thermal transport, by inducing avoided crossings in the acoustic-mode dispersion and facilitating resonant scattering with a consequent large reduction in the lifetimes. Approximate rattling frequencies determined from the harmonic force constants may therefore provide a useful metric for selecting filler atoms to optimise the thermal transport in skutterudites and other cage compounds such as clathrates.

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