Size-dependent penetrant diffusion in polymer glasses

Soft Matter ◽  
2018 ◽  
Vol 14 (21) ◽  
pp. 4226-4230 ◽  
Author(s):  
Dong Meng ◽  
Kai Zhang ◽  
Sanat K. Kumar
Keyword(s):  
Diffusion Coefficients ◽  
Scaling Behavior ◽  
Polymer Glasses ◽  
Universal Scaling ◽  
Size Dependent ◽  
Penetrant Diffusion

The universal scaling behavior of the diffusion coefficients D/T as a function of the “effective” penetrant size (σs − σc)/(α − α0).

Universal scaling behavior of entropy and conductivity in ionic liquids

2020 ◽  
Vol 316 ◽  
pp. 113824 ◽  
Author(s):  
S. Cheng ◽  
M. Musiał ◽  
Z. Wojnarowska ◽  
K.L. Ngai ◽  
J. Jacquemin ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Scaling Behavior ◽  
Universal Scaling

Universal Scaling Behavior of Dielectric Dispersion and Its Breakdown in Glycerol, Propyleneglycol and Trimethyleneglycol

1994 ◽  
Vol 63 (11) ◽  
pp. 4200-4205 ◽  
Author(s):  
Ryuji Abe ◽  
Masakiyo Horioka ◽  
Izumi Sakumiya ◽  
Satoshi Nakamura
Keyword(s):  
Dielectric Dispersion ◽  
Scaling Behavior ◽  
Universal Scaling

On the concentration dependence of surface diffusion coefficients in capillary porous materials

1991 ◽  
Vol 434 (1891) ◽  
pp. 317-340 ◽  
Keyword(s):  
Experimental Data ◽  
Carbon Dioxide ◽  
Pore Size ◽  
Surface Diffusion ◽  
Diffusion Coefficients ◽  
Physical Adsorption ◽  
Structural Heterogeneity ◽  
Size Dependent ◽  
Chemical Potentials ◽  
Uniform Pore Size

The influence of structural heterogeneity, in the form of a non-uniform pore size distribution, on the isotherms and surface diffusion coefficients for monolayer physical adsorption is studied. A pore size dependent langmuirian isotherm is used along with consideration of equality of chemical potentials at the pore mouths at an intersection. The diffusion is modelled by a recently developed random walk formulation. It is found that the surface diffusion coefficients are strongly influenced by the heterogeneity and have a stronger increase with overall coverage than that predicted by the Darken equation. The results are found to match the experimental data of P. C. Carman and F. A. Raal on the diffusion of carbon dioxide in carbon black without the use of a fitting parameter.

Universal scaling behavior of polymer chains at the percolation threshold

Soft Matter ◽  
2018 ◽  
Vol 14 (41) ◽  
pp. 8249-8252 ◽  
Author(s):  
Piotr Polanowski ◽  
Andrzej Sikorski
Keyword(s):  
Percolation Threshold ◽  
Scaling Behavior ◽  
Polymer Chains ◽  
Universal Scaling

A universal scaling behavior of chain size at the percolation threshold is presented.

Universal scaling behavior under pressure in the heavy-fermion antiferromagnet CeRh2Si2 : Si29 NMR study

2021 ◽  
Vol 103 (8) ◽  
Author(s):  
H. Sakai ◽  
Y. Matsumoto ◽  
Y. Haga ◽  
Y. Tokunaga ◽  
S. Kambe
Keyword(s):  
Heavy Fermion ◽  
Scaling Behavior ◽  
Universal Scaling ◽  
Nmr Study
Sign in / Sign up

Export Citation Format

Share Document