scholarly journals Lindqvist polyoxometalates as electrolytes in p-type dye sensitized solar cells

2019 ◽  
Vol 3 (1) ◽  
pp. 96-100 ◽  
Author(s):  
Tijmen M. A. Bakker ◽  
Simon Mathew ◽  
Joost N. H. Reek
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Open Circuit Voltage ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Redox Couples ◽  
P Type ◽  
Sensitized Solar Cells

The development of new redox couples provides a clear strategy to improve power conversion efficiency (PCE) in p-type dye-sensitized solar cells (p-DSSCs) through enabling improvements in open-circuit voltage (VOC).

Synthesis and Characterization of MgO by Microwave-Assisted Thermal Oxidation for Dye-Sensitized Solar Cells

2016 ◽  
Vol 675-676 ◽  
pp. 158-162 ◽  
Author(s):  
Sanpet Nilphai ◽  
Meechai Thepnurat ◽  
Niyom Hongsith ◽  
Pipat Ruankham ◽  
Surachet Phadungdhitidhada ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Open Circuit Voltage ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Microwave Assisted ◽  
Sensitized Solar Cells

Magnesium oxide (MgO) nanostructures were synthesized by microwave-assisted thermal oxidation at various amount of activated carbon additive. The MgO nanostructures were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffractrometry (XRD) and UV-Visible spectroscopy, respectivly. It was observed that, the obtained MgO have nanocube shape. The MgO nanostructures were applied as a blocking layer in ZnO dye-sensitized solar cells (DSSC). The photovoltage, photocurrent, and power conversion efficiency characteristics of DSSCs were measured under illumination of simulated sunlight obtained from a solar simulator with the radiant power of 100 mW/cm2. The DSSCs with MgO layer exhibited higher current density, open circuit voltage and photoconversion efficiency than those without MgO layer The optimum power conversion efficiency (PCE) was 2.49 % with short circuit current (Jsc) of 6.61 mA/cm2, the open circuit voltage (Voc) of 0.66 V and the fill factor (FF) of 0.59, respectively.

Organic Sensitizers Containing Julolidine Moiety for Dye-Sensitized Solar Cells

2008 ◽  
Vol 8 (9) ◽  
pp. 4761-4766 ◽  
Author(s):  
Dong Wook Kim ◽  
Jin Joo Choi ◽  
Man Ku Kang ◽  
Yongku Kang ◽  
Changjin Lee
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Short Circuit ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Organic Sensitizers

We prepared organic sensitizers (S1 and S2) containing julolidine moiety as a donor, phenyl or phenylene thiophene units as a conjugation bridge, and cyano acetic acid as an acceptor for dye sensitized solar cells. S1 exhibited two absorption maxima at 441 nm (ε = 26 200) and 317 nm (ε = 15 500) due to the π–π* transition of the dye molecule. S2 dyes with an additional thiophene unit showed the absorption maximum extended by 18 nm. DSSCs based on S1 dye achieved 2.66% of power conversion efficiency with 8.3 mA cm−2 of short circuit current, 576 mV of open circuit voltage, and 0.56 of fill factor. DSSCs using S2 dye with a longer conjugation attained only 1.48% of power conversion efficiency. The 0.21 V lower driving force for regeneration of the S2 dye compared to the S1 dye is one of the reasons for low conversion efficiency of the S2 dye.

Iodide-Free Ionic Liquid with Dual Redox Couples for Dye-Sensitized Solar Cells with High Open-Circuit Voltage

ChemSusChem ◽  
2015 ◽  
Vol 8 (7) ◽  
pp. 1244-1253 ◽  
Author(s):  
Chun-Ting Li ◽  
Chuan-Pei Lee ◽  
Chi-Ta Lee ◽  
Sie-Rong Li ◽  
Shih-Sheng Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solar Cells ◽  
Open Circuit Voltage ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Redox Couples ◽  
Sensitized Solar Cells

scholarly journals Engineering Processes at the Interface of p-Semiconductor for Enhancing the Open Circuit Voltage in p-Type Dye-Sensitized Solar Cells

2017 ◽  
Vol 7 (12) ◽  
pp. 1601776 ◽  
Author(s):  
Ludovic Favereau ◽  
Yann Pellegrin ◽  
Lionel Hirsch ◽  
Adèle Renaud ◽  
Aurélien Planchat ◽  
...  
Keyword(s):  
Solar Cells ◽  
Open Circuit Voltage ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
P Type ◽  
Sensitized Solar Cells

Spontaneous Enhancement of Power Conversion Efficiency in SnO2-Based Dye-Sensitized Solar Cells

2021 ◽  
Vol 11 (3) ◽  
pp. 674-678
Author(s):  
Shibing Zou ◽  
Lingting Song ◽  
Junhong Duan ◽  
Le Huang ◽  
Weiqing Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Donor-π-acceptor, triazine-linked porphyrin dyads as sensitizers for dye-sensitized solar cells

2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Carboxylic Acid ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Orbital Energy ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.

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