scholarly journals Hydrogen production from formic acid decomposition in the liquid phase using Pd nanoparticles supported on CNFs with different surface properties

2018 ◽  
Vol 2 (12) ◽  
pp. 2705-2716 ◽  
Author(s):  
Felipe Sanchez ◽  
Mohammad Hayal Alotaibi ◽  
Davide Motta ◽  
Carine Edith Chan-Thaw ◽  
Andrianelison Rakotomahevitra ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Liquid Phase ◽  
Hydrogen Production ◽  
Formic Acid ◽  
Surface Properties ◽  
Pd Nanoparticles ◽  
Acid Decomposition ◽  
Storage Materials ◽  
Formic Acid Decomposition

The development of safe and efficient H2 generation/storage materials toward a fuel-cell-based H2 economy as a long-term solution has recently received much attention.

scholarly journals Preformed Pd-Based Nanoparticles for the Liquid Phase Decomposition of Formic Acid: Effect of Stabiliser, Support and Au–Pd Ratio

2020 ◽  
Vol 10 (5) ◽  
pp. 1752 ◽  
Author(s):  
Felipe Sanchez ◽  
Ludovica Bocelli ◽  
Davide Motta ◽  
Alberto Villa ◽  
Stefania Albonetti ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Formic Acid ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Atomic Ratio ◽  
Phase Decomposition ◽  
Acid Effect ◽  
Formic Acid Decomposition ◽  
Structure Morphology

Hydrogen is one of the most promising energy carriers for the production of electricity based on fuel cell hydrogen technology. Recently, hydrogen storage chemicals, such as formic acid, have been proposed to be part of the long-term solution towards hydrogen economy for the future of our planet. Herein we report the synthesis of preformed Pd nanoparticles using colloidal methodology varying a range of specific experimental parameters, such as the amount of the stabiliser and reducing agent, nature of support and Pd loading of the support. The aforementioned parameters have shown to affect mean Pd particle size, Pd oxidation, atomic content of Pd on the surface as well as on the catalytic performance towards formic acid decomposition. Reusability studies were carried out using the most active monometallic Pd material with a small loss of activity after five uses. The catalytic performance based on the Au–Pd atomic ratio was evaluated and the optimum catalytic performance was found to be with the Au/Pd atomic ratio of 1/3, indicating that the presence of a small amount of Pd is essential to promote significantly Au activity for the liquid phase decomposition of formic acid. Thorough characterisation has been carried out by means of XPS, SEM-EDX, TEM and BET. The observed catalytic performance is discussed in terms of the structure/morphology and composition of the supported Pd and Au–Pd nanoparticles.

scholarly journals Strategic examination of the classical catalysis of formic acid decomposition for intermittent hydrogen production, storage and supply: A review

2021 ◽  
Vol 45 ◽  
pp. 101078
Author(s):  
Samuel Eshorame Sanni ◽  
Peter Adeniyi Alaba ◽  
Emeka Okoro ◽  
Moses Emetere ◽  
Babalola Oni ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

2011 ◽  
Vol 6 (5) ◽  
pp. 302-307 ◽  
Author(s):  
Karaked Tedsree ◽  
Tong Li ◽  
Simon Jones ◽  
Chun Wong Aaron Chan ◽  
Kai Man Kerry Yu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Room Temperature ◽  
Core Shell ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Core–Shell Engineering of Pd–Ag Bimetallic Catalysts for Efficient Hydrogen Production from Formic Acid Decomposition

ACS Catalysis ◽  
2018 ◽  
Vol 9 (2) ◽  
pp. 819-826 ◽  
Author(s):  
Bu-Seo Choi ◽  
Jaeeun Song ◽  
Minjin Song ◽  
Bon Seung Goo ◽  
Young Wook Lee ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Bimetallic Catalysts ◽  
Core Shell ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Recent progress in hydrogen production from formic acid decomposition

2018 ◽  
Vol 43 (14) ◽  
pp. 7055-7071 ◽  
Author(s):  
Xian Wang ◽  
Qinglei Meng ◽  
Liqin Gao ◽  
Zhao Jin ◽  
Junjie Ge ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Recent Progress ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

scholarly journals Support effect for nanosized Au catalysts in hydrogen production from formic acid decomposition

2016 ◽  
Vol 6 (18) ◽  
pp. 6853-6860 ◽  
Author(s):  
Monika Zacharska ◽  
Andrey L. Chuvilin ◽  
Vladimir V. Kriventsov ◽  
Sergey Beloshapkin ◽  
Miguel Estrada ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Support Effect ◽  
Particle Sizes ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Au catalysts with the same particle sizes demonstrate the following order of activity in formic acid decomposition: Au/Al2O3 > Au/ZrO2 ∼ Au/CeO2 > Au/La2O3 > Au/MgO.

scholarly journals Single Isolated Pd2+ Cations Supported on N-Doped Carbon as Active Sites for Hydrogen Production from Formic Acid Decomposition

ACS Catalysis ◽  
2015 ◽  
Vol 6 (2) ◽  
pp. 681-691 ◽  
Author(s):  
Dmitri A. Bulushev ◽  
Monika Zacharska ◽  
Elena V. Shlyakhova ◽  
Andrey L. Chuvilin ◽  
Yina Guo ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Active Sites ◽  
Acid Decomposition ◽  
Formic Acid Decomposition
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