scholarly journals Cobalt-bridged secondary building units in a titanium metal–organic framework catalyze cascade reduction of N-heteroarenes

2019 ◽  
Vol 10 (7) ◽  
pp. 2193-2198 ◽  
Author(s):  
Xuanyu Feng ◽  
Yang Song ◽  
Justin S. Chen ◽  
Zhe Li ◽  
Emily Y. Chen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Titanium Metal ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework ◽  
Oxo Ligands

We report here the synthesis of a robust Ti–MOF with novel SBUs and its use as oxo ligands to chelate Co-hydrides for cascade reduction of N-heteroarenes.

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

A new Co-based metal–organic framework constructed from infinite sinusoidal-like rod-shaped secondary building units

2014 ◽  
Vol 47 ◽  
pp. 67-70 ◽  
Author(s):  
Yun-Wu Li ◽  
Sui-Jun Liu ◽  
Tong-Liang Hu ◽  
Da-Cheng Li ◽  
Jian-Min Dou ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Bioinspired chemistry at MOF secondary building units

2020 ◽  
Vol 11 (7) ◽  
pp. 1728-1737 ◽  
Author(s):  
James R. Bour ◽  
Ashley M. Wright ◽  
Xin He ◽  
Mircea Dincă
Keyword(s):  
Metal Organic Framework ◽  
Bioinorganic Chemistry ◽  
Future Directions ◽  
Biomimetic Catalysis ◽  
Recent Developments ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

This perspective describes recent developments and future directions in bioinorganic chemistry and biomimetic catalysis centered at metal–organic framework secondary building units.

A New Open Metal-Organic Framework [Zn8(GeO4)(C8H4O4)6]n, Constructed by Heterometallic Cluster Zn8(GeO4) Secondary Building Units

2003 ◽  
Vol 32 (5) ◽  
pp. 474-475 ◽  
Author(s):  
Jinxi Chen ◽  
Zhicheng Liu ◽  
Ting Yu ◽  
Zhenxia Chen ◽  
Jinyu Sun ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Heterometallic Cluster ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Two Exceptional Patterns of Helical Secondary Building Units Found in Metal–Organic Framework Structures

2017 ◽  
Vol 17 (6) ◽  
pp. 2941-2944 ◽  
Author(s):  
Eugeny V. Alexandrov ◽  
Andrey V. Goltsev ◽  
Michael O’Keeffe ◽  
Davide M. Proserpio
Keyword(s):  
Metal Organic Framework ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

A Microporous Co(II)-Based 3-D Metal Organic Framework Built from Magnetic Infinite Rod-Shaped Secondary Building Units

2019 ◽  
Vol 2019 (38) ◽  
pp. 4056-4062
Author(s):  
Andreas Kourtellaris ◽  
Eleni E. Moushi ◽  
Ioannis Spanopoulos ◽  
Pantelis N. Trikalitis ◽  
Michael Pissas ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework
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