scholarly journals Bimetallic nickel–cobalt hydrides in H2 activation and catalytic proton reduction

2019 ◽  
Vol 10 (3) ◽  
pp. 761-767 ◽  
Author(s):  
Xiaoxiao Chu ◽  
Jihao Jin ◽  
Bangrong Ming ◽  
Maofu Pang ◽  
Xin Yu ◽  
...  
Keyword(s):  
Redox Properties ◽  
Proton Reduction ◽  
Nickel Cobalt

The synergism of the redox properties of nickel and cobalt enables bimetallic NiCo complexes to process H2.

scholarly journals Influence of nitro substituents on the redox, electronic, and proton reduction catalytic behavior of phenolate-based [N2O3]-type cobalt(iii) complexes

2019 ◽  
Vol 48 (39) ◽  
pp. 14669-14677 ◽  
Author(s):  
Debashis Basu ◽  
Shivnath Mazumder ◽  
Kenneth K. Kpogo ◽  
Cláudio N. Verani
Keyword(s):  
Redox Properties ◽  
Proton Reduction ◽  
Catalytic Behavior ◽  
Cobalt Species

The electronic and redox properties of two new nitro-substituted cobalt species are investigated towards proton reduction.

Modulation of electronic and redox properties in phenolate-rich cobalt(iii) complexes and their implications for catalytic proton reduction

2015 ◽  
Vol 44 (7) ◽  
pp. 3454-3466 ◽  
Author(s):  
Debashis Basu ◽  
Marco M. Allard ◽  
Fernando R. Xavier ◽  
Mary Jane Heeg ◽  
H. Bernhard Schlegel ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cobalt Complexes ◽  
Redox Properties ◽  
Proton Reduction

The redox, spectroscopic and catalytic activity of a series of cobalt complexes with phenolate-rich environments was investigated. The complex [CoIII(LCl)MeOH] shows considerable proton reduction in MeCN:HOAc with TON = 10.8.

MAGNETIC PROPERTIES OF NICKEL-COPPER AND NICKEL-COBALT ALLOYS

1988 ◽  
Vol 49 (C8) ◽  
pp. C8-1937-C8-1938 ◽  
Author(s):  
D. C. Jiles ◽  
T. T. Chang ◽  
D. R. Hougen ◽  
R. Ranjan
Keyword(s):  
Magnetic Properties ◽  
Cobalt Alloys ◽  
Nickel Cobalt ◽  
Nickel Copper

An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin

2020 ◽  
Author(s):  
Peter T. Smith ◽  
Sophia Weng ◽  
Christopher Chang
Keyword(s):  
Proton Transfer ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Redox Mediators ◽  
Reservoir Properties ◽  
Proton Reduction ◽  
Electrochemical Co2 Reduction ◽  
Starting Point ◽  
Rate Improvement ◽  
Molecular Catalysts

We present a bioinspired strategy for enhancing electrochemical carbon dioxide reduction catalysis by cooperative use of base-metal molecular catalysts with intermolecular second-sphere redox mediators that facilitate both electron and proton transfer. Functional synthetic mimics of the biological redox cofactor NADH, which are electrochemically stable and are capable of mediating both electron and proton transfer, can enhance the activity of an iron porphyrin catalyst for electrochemical reduction of CO<sub>2</sub> to CO, achieving a 13-fold rate improvement without altering the intrinsic high selectivity of this catalyst platform for CO<sub>2</sub> versus proton reduction. Evaluation of a systematic series of NADH analogs and redox-inactive control additives with varying proton and electron reservoir properties reveals that both electron and proton transfer contribute to the observed catalytic enhancements. This work establishes that second-sphere dual control of electron and proton inventories is a viable design strategy for developing more effective electrocatalysts for CO<sub>2</sub> reduction, providing a starting point for broader applications of this approach to other multi-electron, multi-proton transformations.

K-42-B

Alloy Digest ◽  
1954 ◽  
Vol 3 (12) ◽  
Keyword(s):  
Elevated Temperatures ◽  
Iron Alloy ◽  
Heat Treating ◽  
Cobalt Chromium ◽  
Nickel Cobalt ◽  
Creep Characteristics ◽  
Westinghouse Electric Corporation ◽  
Westinghouse Electric ◽  
Hardening Heat Treatment ◽  
Resistance To Heat

Abstract K-42-B is a nickel-cobalt-chromium-iron alloy having high resistance to heat and corrosion. It responds to a precipitation-hardening heat treatment producing high tensile and creep characteristics at elevated temperatures. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep and fatigue. It also includes information on high temperature performance and corrosion resistance as well as heat treating, machining, and joining. Filing Code: Ni-13. Producer or source: Westinghouse Electric Corporation.

UGI KC35N

Alloy Digest ◽  
2014 ◽  
Vol 63 (12) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Shear Strength ◽  
Physical Properties ◽  
Heat Treating ◽  
Molybdenum Alloy ◽  
Cobalt Chromium ◽  
Austenitic Structure ◽  
Nickel Cobalt ◽  
Cobalt Chromium Molybdenum

Abstract UGI KC35N is a nonmagnetic nickel-cobalt-chromium-molybdenum alloy with a fully austenitic structure. This datasheet provides information on composition, physical properties, elasticity, and shear strength. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Co-124. Producer or source: Schmolz + Bickenbach USA Inc..

Sign in / Sign up

Export Citation Format

Share Document