scholarly journals A porous, electrically conductive hexa-zirconium(iv) metal–organic framework

2018 ◽  
Vol 9 (19) ◽  
pp. 4477-4482 ◽  
Author(s):  
Subhadip Goswami ◽  
Debmalya Ray ◽  
Ken-ichi Otake ◽  
Chung-Wei Kung ◽  
Sergio J. Garibay ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Framework ◽  
Electrically Conductive ◽  
Metal Organic ◽  
Organic Framework

Electrical conductivity is engendered in a pyrene containing hexa-zirconium(iv) metal–organic framework by physically encapsulating fullerenes within MOF cavity.

scholarly journals High Electrical Conductivity in Three-Dimensional Porphyrin-Phosphonate Metal Organic-Frameworks

2021 ◽  
Author(s):  
Yunus Zorlu ◽  
Patrik Tholen ◽  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Yield ◽  
Electrically Conductive ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Indirect Band Gap ◽  
Organic Framework

<p>Herein, we report the design and synthesis of a highly electrically conductive and microporous three-dimensional zinc-phosphonate metal-organic framework [Zn(Cu-<i>p</i>-H<sub>4</sub>TPPA)] ⋅2 (CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup> (designated as GTUB3), constructed using the 5,10,15,20‐tetrakis [<i>p</i>‐phenylphosphonic acid] porphyrin (<i>p</i>-H<sub>8</sub>TPPA) organic linker. GTUB3 has an indirect band gap of 1.64 eV and a high average electrical conductivity of<b> </b>4 S/m, making it a rare example of an electrically conductive zinc metal-organic framework. The N<sub>2</sub>-accessible geometric surface area of GTUB3, as predicted by molecular simulations, is 671 m<sup>2</sup>/g. Owing to its simple, high-yield synthesis at low temperatures, porosity, and electrical conductivity, GTUB3 may be used as a low-cost electrode material in next generation phosphonate-supercapacitors. </p>

scholarly journals High Electrical Conductivity in Three-Dimensional Porphyrin-Phosphonate Metal Organic-Frameworks

2021 ◽  
Author(s):  
Yunus Zorlu ◽  
Patrik Tholen ◽  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Yield ◽  
Electrically Conductive ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Indirect Band Gap ◽  
Organic Framework

<p>Herein, we report the design and synthesis of a highly electrically conductive and microporous three-dimensional zinc-phosphonate metal-organic framework [Zn(Cu-<i>p</i>-H<sub>4</sub>TPPA)] ⋅2 (CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup> (designated as GTUB3), constructed using the 5,10,15,20‐tetrakis [<i>p</i>‐phenylphosphonic acid] porphyrin (<i>p</i>-H<sub>8</sub>TPPA) organic linker. GTUB3 has an indirect band gap of 1.64 eV and a high average electrical conductivity of<b> </b>4 S/m, making it a rare example of an electrically conductive zinc metal-organic framework. The N<sub>2</sub>-accessible geometric surface area of GTUB3, as predicted by molecular simulations, is 671 m<sup>2</sup>/g. Owing to its simple, high-yield synthesis at low temperatures, porosity, and electrical conductivity, GTUB3 may be used as a low-cost electrode material in next generation phosphonate-supercapacitors. </p>

scholarly journals Switchable electrical conductivity in a three-dimensional metal–organic framework via reversible ligand n-doping

2020 ◽  
Vol 11 (5) ◽  
pp. 1342-1346 ◽  
Author(s):  
Hanna C. Wentz ◽  
Grigorii Skorupskii ◽  
Ana B. Bonfim ◽  
Jenna L. Mancuso ◽  
Christopher H. Hendon ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Redox Active Ligands ◽  
Redox Active ◽  
N Doping ◽  
Metal Organic ◽  
Organic Framework

Redox-active ligands are used to reversibly tune electrical conductivity in a porous 3D metal–organic framework (MOF).

scholarly journals Micro-spectroscopy of HKUST-1 metal–organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host–guest chemistry and electrical conductivity

2019 ◽  
Vol 21 (46) ◽  
pp. 25678-25689 ◽  
Author(s):  
Miguel Rivera-Torrente ◽  
Matthias Filez ◽  
Christian Schneider ◽  
Ewout C. van der Feltz ◽  
Konrad Wolkersdörfer ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spatial Distribution ◽  
Water Vapor ◽  
Metal Organic Framework ◽  
Next Generation ◽  
Metal Organic ◽  
Spectroscopy Studies ◽  
Organic Framework ◽  
Guest Chemistry

Guest@MOF materials have potential in next-generation materials for electroconductive devices. Micro-spectroscopy studies of TCNQ@HKUST-1 electroconductive composites revealed the effects of spatial distribution and water vapor on this material.

Metal–organic-frameworks-derived NaTi2(PO4)3/carbon composites for efficient hybrid capacitive deionization

2019 ◽  
Vol 7 (19) ◽  
pp. 12126-12133 ◽  
Author(s):  
Kai Wang ◽  
Yong Liu ◽  
Zibiao Ding ◽  
Yuquan Li ◽  
Ting Lu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Porous Structure ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Carbon Composites ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
Organic Framework

Metal–organic-framework-derived NaTi2(PO4)3/carbon composites with unique porous structure and improved electrical conductivity exhibit high desalination performance for hybrid capacitive deionization.

Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing

2015 ◽  
Vol 127 (14) ◽  
pp. 4423-4426 ◽  
Author(s):  
Michael G. Campbell ◽  
Dennis Sheberla ◽  
Sophie F. Liu ◽  
Timothy M. Swager ◽  
Mircea Dincă
Keyword(s):  
Metal Organic Framework ◽  
Electrically Conductive ◽  
Chemiresistive Sensing ◽  
Metal Organic ◽  
Organic Framework

Electrically Conductive, Monolithic Metal–Organic Framework–Graphene (MOF@G) Composite Coatings

2019 ◽  
Vol 11 (6) ◽  
pp. 6442-6447 ◽  
Author(s):  
Mohamed H. Hassan ◽  
Rana R. Haikal ◽  
Tawheed Hashem ◽  
Julia Rinck ◽  
Franz Koeniger ◽  
...  
Keyword(s):  
Composite Coatings ◽  
Metal Organic Framework ◽  
Electrically Conductive ◽  
Metal Organic ◽  
Organic Framework
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