scholarly journals Ultrafast interligand electron transfer in cis-[Ru(4,4′-dicarboxylate-2,2′-bipyridine)2(NCS)2]4− and implications for electron injection limitations in dye sensitized solar cells

2018 ◽  
Vol 9 (41) ◽  
pp. 7958-7967 ◽  
Author(s):  
Belinda Pettersson Rimgard ◽  
Jens Föhlinger ◽  
Jonas Petersson ◽  
Marcus Lundberg ◽  
Burkhard Zietz ◽  
...  

Using IR absorption anisotropy, interligand energy transfer in N712 is shown to occur on a sub-ps time scale, and is thus unlikely to limit injection in DSSCs.

2021 ◽  
Author(s):  
Giribabu Lingamallu ◽  
Venkata Suman Krishna Jonnadula ◽  
Seelam Prasanthkumar ◽  
Iva Dzeba ◽  
Challuri Vijay Kumar ◽  
...  

Donor-π-Acceptor (D-π-A) porphyrin based photo-sensitizers are extensively utilized in dye sensitized solar cells (DSSCs). However, investigation on how the intramolecular photoinduced energy/electron transfer influences the device performance is still limited....


2014 ◽  
Vol 43 (4) ◽  
pp. 1493-1497 ◽  
Author(s):  
Chun-Chen Yuan ◽  
Shi-Ming Wang ◽  
Wei-Lin Chen ◽  
Lin Liu ◽  
Chao Qin ◽  
...  

2012 ◽  
Vol 155 ◽  
pp. 165-176 ◽  
Author(s):  
Seung-Hyun Anna Lee ◽  
Yixin Zhao ◽  
Emil A. Hernandez-Pagan ◽  
Landy Blasdel ◽  
W. Justin Youngblood ◽  
...  

2019 ◽  
Vol 233 (9) ◽  
pp. 1247-1259
Author(s):  
Madhu Prakasam

Abstract In this work, we systematically investigate the impacts of electron-donor based on Triphenylamine (TPA). The Geometry structure, energy levels, light-harvesting ability and ultraviolet-visible absorption spectra were calculated by using Density Functional Theory (DFT) and Time-Dependent-DFT. The electron injection rate of the TPA-N(CH3)2 based dyes has 0.71 eV for high among the dye sensitizer. The First and Second order Hyperpolarizability of the 11.95 × 10−30 e.s.u and 12195.54 a.u, respectively for TPA-N(CH3)2 based dye. The calculated absorption spectra were showed in the ultra-violet visible region for power conversion region. The study reveals that the electron transfer character of TPA-N(CH3)2 based dyes can be made suitable for applications in Dye-Sensitized Solar Cells.


2017 ◽  
Vol 53 (49) ◽  
pp. 6629-6632 ◽  
Author(s):  
Vediappan Sudhakar ◽  
Arulraj Arulkashmir ◽  
Kothandam Krishnamoorthy

A polymer–graphene blocking layer decreases back electron transfer and increases dye regeneration that improved the DSSC efficiency to 10.4%.


ChemSusChem ◽  
2014 ◽  
Vol 7 (10) ◽  
pp. 2805-2810 ◽  
Author(s):  
Ippei Inoue ◽  
Kiyoshi Watanabe ◽  
Hirofumi Yamauchi ◽  
Yasuaki Ishikawa ◽  
Hisashi Yasueda ◽  
...  

ACS Nano ◽  
2014 ◽  
Vol 8 (3) ◽  
pp. 2261-2268 ◽  
Author(s):  
Aravind Kumar Chandiran ◽  
Mojtaba Abdi-Jalebi ◽  
Mohammad K. Nazeeruddin ◽  
Michael Grätzel

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