scholarly journals Near infrared two-photon-excited and -emissive dyes based on a strapped excited-state intramolecular proton-transfer (ESIPT) scaffold

2018 ◽  
Vol 9 (10) ◽  
pp. 2666-2673 ◽  
Author(s):  
Naoya Suzuki ◽  
Kayo Suda ◽  
Daisuke Yokogawa ◽  
Hirotaka Kitoh-Nishioka ◽  
Stephan Irle ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Intramolecular Proton Transfer ◽  
Infrared Emission ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Near Infrared Emission

Strapped acceptor–π–donor–π–acceptor type fluorophores exhibit intense near infrared emission, together with near infrared two-photon absorption.

scholarly journals Two-photon excited deep-red and near-infrared emissive organic co-crystals

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yu Wang ◽  
Huang Wu ◽  
Penghao Li ◽  
Su Chen ◽  
Leighton O. Jones ◽  
...  
Keyword(s):  
Cross Sections ◽  
Optical Materials ◽  
Near Infrared ◽  
Infrared Emission ◽  
Photon Absorption ◽  
Electromagnetic Spectrum ◽  
Absorption Bands ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Near Infrared Emission

Abstract Two-photon excited near-infrared fluorescence materials have garnered considerable attention because of their superior optical penetration, higher spatial resolution, and lower optical scattering compared with other optical materials. Herein, a convenient and efficient supramolecular approach is used to synthesize a two-photon excited near-infrared emissive co-crystalline material. A naphthalenediimide-based triangular macrocycle and coronene form selectively two co-crystals. The triangle-shaped co-crystal emits deep-red fluorescence, while the quadrangle-shaped co-crystal displays deep-red and near-infrared emission centered on 668 nm, which represents a 162 nm red-shift compared with its precursors. Benefiting from intermolecular charge transfer interactions, the two co-crystals possess higher calculated two-photon absorption cross-sections than those of their individual constituents. Their two-photon absorption bands reach into the NIR-II region of the electromagnetic spectrum. The quadrangle-shaped co-crystal constitutes a unique material that exhibits two-photon absorption and near-infrared emission simultaneously. This co-crystallization strategy holds considerable promise for the future design and synthesis of more advanced optical materials.

Benzoindolic squaraine dyes with a large two-photon absorption cross-section

2017 ◽  
Vol 5 (5) ◽  
pp. 1224-1230 ◽  
Author(s):  
Chun-Lin Sun ◽  
Shao-Kai Lv ◽  
Yan-Ping Liu ◽  
Qing Liao ◽  
Hao-Li Zhang ◽  
...  
Keyword(s):  
Near Infrared ◽  
Infrared Emission ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Squaraine Dyes ◽  
Two Photon ◽  
Squaraine Dye ◽  
New Strategy ◽  
Near Infrared Emission

Assisted by a new strategy of non-conjugated modifications, we designed a benzoindolic squaraine dye with δ > 12 000 GM and high near-infrared emission, which is ideal for in vitro bioimaging applications.

New two-photon absorption benzotriazole–coumarin dyads: the evidence of internal proton transfer in the excited state

2015 ◽  
Vol 56 (1) ◽  
pp. 236-242 ◽  
Author(s):  
Yulong Gong ◽  
Yao Lu ◽  
Zhenqiang Wang ◽  
Shengtao Zhang ◽  
Ziping Luo ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon

Two-photon absorption spectra of a near-infrared 2-azaazulene polymethine dye: solvation and ground-state symmetry breaking

2013 ◽  
Vol 15 (20) ◽  
pp. 7666 ◽  
Author(s):  
Honghua Hu ◽  
Olga V. Przhonska ◽  
Francesca Terenziani ◽  
Anna Painelli ◽  
Dmitry Fishman ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Polymethine Dye

scholarly journals Polyfluorenylacetylene for near-infrared laser protection: polymer synthesis, optical limiting mechanism and relationship between molecular structure and properties

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53785-53796 ◽  
Author(s):  
Gang Zhao ◽  
Yan Feng ◽  
Shanyi Guang ◽  
Hongyao Xu ◽  
Naibo Lin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Near Infrared ◽  
Optical Limiting ◽  
High Thermal Stability ◽  
Photon Absorption ◽  
Structure And Properties ◽  
Absorption Mechanism ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Good Solubility

The incorporation of styryl/stilbene–fluorene into polyacetylenes not only endowed the polymers with novel near-infrared optical limiting properties based on a two-photon absorption mechanism but good solubility and high thermal stability.

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