scholarly journals DNA quadruplexes as molecular scaffolds for controlled assembly of fluorogens with aggregation-induced emission

2018 ◽  
Vol 9 (9) ◽  
pp. 2559-2566 ◽  
Author(s):  
Longyi Zhu ◽  
Jun Zhou ◽  
Guohua Xu ◽  
Conggang Li ◽  
Pinghua Ling ◽  
...  
Keyword(s):  
Light Emission ◽  
Molecular Scaffolds ◽  
Aggregation Induced Emission ◽  
Controlled Assembly ◽  
Dna Quadruplexes

Tetrapod DNA quadruplexes were designed for assembly and precise modulation of light emission of an oligonucleotide-grafted fluorogen with aggregation-induced emission.

Synthesis and Spectroscopic Characteristics of Ligands Based on Quinolin-8-Ol as Useful Precursors for Alq3 Type Complexes

2021 ◽  
Vol 903 ◽  
pp. 168-173
Author(s):  
Elmārs Zariņš ◽  
Deins Alksnis ◽  
Patricija Paulsone ◽  
Karlis Balodis ◽  
Aivars Vembris ◽  
...  
Keyword(s):  
Solid State ◽  
Light Emission ◽  
Emission Property ◽  
Blue Luminescence ◽  
Reaction Conditions ◽  
Aggregation Induced Emission ◽  
Chemical Structures ◽  
Emission Enhancement ◽  
Spectroscopic Characteristics ◽  
Reliable Methods

In order to develop reliable methods for the synthesis of various 5-substituted-8-oxyquinoline derivatives for the preparation of Alq3-type complexes, we have improved the reaction conditions on some syntheses described in the literature, successfully synthesized new ligands based on quinolin-8-ol and characterized their chemical structures by NMR. Some of the synthesized quinolin-8-ol derivatives containing incorporated bulky triphenyl or tert-butyl groups showed blue luminescence in the solid state due to the possible aggregation induced emission enhancement (AIEE) with a maximum wavelength around 510 nm. More detailed light-emission property investigation of the mentioned bulky group containing compounds is currently underway.

A new strategy for achieving single-molecular white-light emission: using vibration-induced emission (VIE) plus aggregation-induced emission (AIE) mechanisms as a two-pronged approach

2019 ◽  
Vol 55 (13) ◽  
pp. 1879-1882 ◽  
Author(s):  
Huan Wang ◽  
Yiru Li ◽  
Yiyao Zhang ◽  
Ju Mei ◽  
Jianhua Su
Keyword(s):  
White Light ◽  
Light Emission ◽  
White Light Emission ◽  
Aggregation Induced Emission ◽  
New Strategy

Single-molecular white-light emissions were achieved through the simple but judicious combination of vibration-induced emission (VIE) and aggregation-induced emission (AIE) mechanisms.

Light emission properties and self-assembly of a tolane-based luminogen

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38690-38695 ◽  
Author(s):  
Ying Zang ◽  
Yi Li ◽  
Baozong Li ◽  
Hongkun Li ◽  
Yonggang Yang
Keyword(s):  
Charge Transfer ◽  
Self Assembly ◽  
Light Emission ◽  
Intramolecular Charge Transfer ◽  
Aggregation Induced Emission ◽  
Emission Properties

Fluorescent micro/nanostructures were formed by self-assembly of a tolane derivative with intramolecular charge transfer and aggregation-induced emission properties.

scholarly journals An Unexpected Dual-Emissive Luminogen: Tunable Aggregation-Induced Emission with Cyan-White-Red Colors, Stable Inherent Chirality, and Enhanced Chiroptical Property

2022 ◽  
Author(s):  
Pingwu Du ◽  
Xinyu Zhang ◽  
Huiqing Liu ◽  
Guilin Zhuang ◽  
Shangfeng Yang
Keyword(s):  
Light Emission ◽  
Dual Emission ◽  
Aggregation Induced Emission ◽  
Quenching Effect ◽  
Chiroptical Property ◽  
Synthesis Strategy ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence ◽  
Luminescent Behavior ◽  
High Strain Energy

Herein we report a novel chiral bismacrocycle with unexpected dual emission and tunable aggregation-induced emission colors. A facile four-step synthesis strategy is developed to construct this rigid bismacrocycle, (1,4)[8]cycloparaphenylenophane (SCPP[8]), which possesses a 1,2,4,5-tetraphenylbenzene core locked by two intersecting polyphenylene-based macrocycles. The luminescent behavior of SCPP[8] shows the unique characteristics of both aggregation-caused quenching effect and aggrega-tion-induced emission (AIE) effect, inducing remarkable redshift emission including near white-light emission. SCPP[8] is configurationally stable and possesses a novel shape-persistent bismacrocycle scaffold with a high strain energy (up to 127.83 kcal/mol). In addition, SCPP[8] displays enhanced circularly polarized luminescence properties due to AIE effect.

scholarly journals Triboluminescence of Centrosymmetric Lanthanide β-Diketonate Complexes with Aggregation-Induced Emission

Molecules ◽  
2019 ◽  
Vol 24 (4) ◽  
pp. 662 ◽  
Author(s):  
Ho-Yin Wong ◽  
Wesley Chan ◽  
Ga-Lai Law
Keyword(s):  
Symmetric Space ◽  
Structural Properties ◽  
Light Emission ◽  
Molecular Packing ◽  
Mechanical Forces ◽  
Space Group ◽  
Aggregation Induced Emission ◽  
Crystal Structural

Triboluminescence (TL) is a form of light emission induced upon mechanical forces on the material. However, our understanding of this phenomenon is still unclear and more examples are therefore needed in order to elucidate its mechanism. In this work, two types of TL complexes, [Eu(pp-dbm-Cl2)3phen] and [Eu(mm-dbm-Cl2)3phen], which also displays aggregation-induced emission (AIE) were synthesized and investigated for its photo-physical and crystal structural properties. These complexes were crystallized in a centro-symmetric space group P21/n, and remarkably, displayed TL upon grinding that may be due to the presence of extensive π···π, C-H···π and C-H···Cl-C interactions in the close molecular packing of its structure. This rare example deviates from the widely accepted mechanism of TL, hence widening the scope of our understanding in the area.

Solvent-controlled assembly of pillar[5]arene-based supramolecular networks via π–π interactions for white light modulation

2020 ◽  
Vol 7 (2) ◽  
pp. 399-404
Author(s):  
Qi Li ◽  
Yuezhou Liu ◽  
Peiren Liu ◽  
Liqing Shangguan ◽  
Huangtianzhi Zhu ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Solvent Polarity ◽  
White Light Emission ◽  
Supramolecular Network ◽  
Light Modulation ◽  
Controlled Assembly ◽  
Π Interactions ◽  
Supramolecular Networks

A supramolecular network based on pyrene-containing pillar[5]arene and a red emissive Eu(iii) complex was constructed, whose assembly and emission can be controlled by solvent polarity, eventually achieving white light emission.

Sign in / Sign up

Export Citation Format

Share Document