Structure, characterization, and catalytic properties of open-metal sites in metal organic frameworks

2019 ◽  
Vol 4 (2) ◽  
pp. 207-222 ◽  
Author(s):  
Jacklyn N. Hall ◽  
Praveen Bollini
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structure Characterization ◽  
Current Understanding ◽  
Framework Materials ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

This review provides an overview of the current understanding of structure–catalytic properties of open-metal sites in metal organic framework materials.

Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook

2017 ◽  
Vol 46 (47) ◽  
pp. 16381-16386 ◽  
Author(s):  
Chengliang Xiao ◽  
Mark A. Silver ◽  
Shuao Wang
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

137Cs, 90Sr, 238U, 79Se, and 99Tc sequestrations from aqueous solution by metal–organic framework materials are summarized in this Frontier article.

A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal–Organic Framework Materials HKUST-1 and Cu-MOF-2

2015 ◽  
Vol 137 (31) ◽  
pp. 10009-10015 ◽  
Author(s):  
Hong Ki Kim ◽  
Won Seok Yun ◽  
Min-Bum Kim ◽  
Jeung Yoon Kim ◽  
Youn-Sang Bae ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Chemical Route ◽  
Framework Materials ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Novel metal–organic framework materials: blends, liquids, glasses and crystal–glass composites

2019 ◽  
Vol 55 (60) ◽  
pp. 8705-8715 ◽  
Author(s):  
Joshua M. Tuffnell ◽  
Christopher W. Ashling ◽  
Jingwei Hou ◽  
Shichun Li ◽  
Louis Longley ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Crystal Glass ◽  
Zeolitic Imidazolate Framework ◽  
Feature Article ◽  
Glass Composites ◽  
Framework Materials ◽  
Recent Advances ◽  
Metal Organic ◽  
Organic Framework

This Feature Article reviews a range of amorphisation mechanisms of Metal–Organic Frameworks (MOFs) and presents recent advances to produce novel MOF materials including porous MOF glasses, MOF crystal–glass composites, flux melted MOF glasses and blended zeolitic imidazolate framework glasses.

Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

2017 ◽  
Vol 46 (8) ◽  
pp. 2462-2470 ◽  
Author(s):  
Ghazale Gholami ◽  
Giorgio Baggi ◽  
Kelong Zhu ◽  
Stephen J. Loeb
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

A mechanically interlocked ligand which combines an H-shaped axle containing four terminal 3-carboxyphenyl groups and a macrocyclic wheel with two 4-pyridyl groups was used to create Zn(ii) and Cu(ii) metal–organic framework materials that contain unique frameworks threaded solely due to the interpenetrated nature of the linker.

Excellent photoreduction performance of Cr(vi) over (WO4)2−-doped metal organic framework materials

2020 ◽  
Vol 44 (47) ◽  
pp. 20704-20714
Author(s):  
Xinyun Zhao ◽  
Lamei Wu ◽  
Xi Chen ◽  
Juncheng Hu ◽  
Tsung-hsueh Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

Negatively charged (WO4)2− anions doped into 2D layered metal organic frameworks bismuth terephthalate provides a valuable strategy for excellent photoreduction of Cr(vi).

Morphology regulation of metal–organic framework-derived nanostructures for efficient oxygen evolution electrocatalysis

2020 ◽  
Vol 8 (35) ◽  
pp. 18215-18219 ◽  
Author(s):  
Yuwen Li ◽  
Mengting Lu ◽  
Yuhang Wu ◽  
Qinghong Ji ◽  
Hui Xu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Organic Framework

A series of morphology-regulated oxygen-evolution electrocatalysts including nanosheets, nanoflowers, nanotubes and aggregations derived from Hofmann-type metal–organic frameworks have been developed and demonstrated efficient catalytic properties.

Rational construction of metal–organic frameworks for heterogeneous catalysis

2014 ◽  
Vol 1 (10) ◽  
pp. 721-734 ◽  
Author(s):  
Sha Ou ◽  
Chuan-De Wu
Keyword(s):  
Heterogeneous Catalysis ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Short Review ◽  
Metal Organic ◽  
Rational Construction ◽  
Designed Synthesis ◽  
Organic Framework

The recently developed strategies on designed synthesis of porous metal–organic framework catalysts and their interesting catalytic properties are summarized in this short review.

Water interactions in metal organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 247-260 ◽  
Author(s):  
Kui Tan ◽  
Nour Nijem ◽  
Yuzhi Gao ◽  
Sebastian Zuluaga ◽  
Jing Li ◽  
...  
Keyword(s):  
Structural Variation ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Insight into the structural variation of metal organic framework materials upon hydration.

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