scholarly journals A green approach of preparation of fine active alumina with high specific surface area from sodium aluminate solution

RSC Advances ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 5628-5638
Author(s):  
Guoyu Wu ◽  
Guihua Liu ◽  
Xiaobin Li ◽  
Zhihong Peng ◽  
Qiusheng Zhou ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Phase Evolution ◽  
Sodium Aluminate ◽  
High Specific Surface Area ◽  
Aluminate Solution ◽  
Green Approach ◽  
Active Alumina ◽  
Sodium Aluminate Solution

A green preparation of fine active alumina from saturated sodium aluminate solution by phase evolution is presented. High capillary pressure, numerous mesopores, and the inhibition of aggregation produced FAA with an extremely high specific surface area.

scholarly journals Obtaining of transition phases of alumina starting from sodium aluminate in Bayer process

2011 ◽  
Vol 65 (3) ◽  
pp. 271-277
Author(s):  
Zoran Obrenovic ◽  
Radislav Filipovic ◽  
Marija Milanovic ◽  
Ivan Stijepovic ◽  
Ljubica Nikolic
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Ph Value ◽  
Sodium Aluminate ◽  
High Specific Surface Area ◽  
Heterogeneous Structure ◽  
Aluminate Solution ◽  
Bayer Liquor ◽  
Sodium Aluminate Solution

Transition (active) phases of alumina were synthesized starting from sodium aluminate solution prepared out of Bayer liquor. The neutralisation of sodium aluminate solution was performed by sulphuric acid. Powder X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and low-temperature nitrogen absorption studies were employed to trace the formation of the transition phases of alumina. The results show that the properties of the powders (phase composition, morphology and specific surface area) are strongly influenced by the initial pH value of the system, as well as by the duration of neutralisation step. It is possible to obtain powders with heterogeneous structure with dominant phase of bayerite, gibbsite or boehmit by tuning the pH and concentration of the starting sodium aluminate solution. The transition (active) phases of alumina (?- and ?-alumina) with high specific surface area (264-373 m2/g) are formed through the thermal dehydratation of aluminium hydroxide (bayerite and gibbsite) and aluminium oxyhydroxide (boehmite or pseudoboehmite) at the temperature of 500?C. Namely, bayerite and pseudoboehmite transforms to ?-phase of alumina upon heating, while gibbsite transforms to ?-phase, maintaining the parent morphology.

scholarly journals Nanoporous Quasi-High-Entropy Alloy Microspheres

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
High Entropy Alloy ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Hierarchical Porous

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

KCl-assisted activation: Moringa oleifera branch-derived porous carbon for high performance supercapacitor

2021 ◽  
Vol 45 (12) ◽  
pp. 5712-5719
Author(s):  
Yongxiang Zhang ◽  
Peifeng Yu ◽  
Mingtao Zheng ◽  
Yong Xiao ◽  
Hang Hu ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
High Performance ◽  
Moringa Oleifera ◽  
High Specific Surface Area ◽  
Porous Carbons

Porous carbons with a high specific surface area (2314–3470 m2 g−1) are prepared via a novel KCl-assisted activation strategy for high-performance supercapacitor.

Carbon material with high specific surface area and high pseudocapacitance: Possible application in supercapacitors

2021 ◽  
Vol 319 ◽  
pp. 111063
Author(s):  
Yury M. Volfkovich ◽  
Valentin E. Sosenkin ◽  
Alexei Y. Rychagov ◽  
Alexandr V. Melezhik ◽  
Alexei G. Tkachev ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Carbon Material ◽  
High Specific Surface Area

Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts

2019 ◽  
Vol 43 (33) ◽  
pp. 13217-13224 ◽  
Author(s):  
Xieyi Huang ◽  
Peng Wang ◽  
Zhichao Zhang ◽  
Shaoning Zhang ◽  
Xianlong Du ◽  
...  
Keyword(s):  
Thin Layer ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Geometric Structure ◽  
Nickel Catalysts ◽  
High Specific Surface Area ◽  
Efficient Conversion

Thin-layer SiOx matrix anchored nickel catalysts with high specific surface area and a unique electronic/geometric structure were fabricated for efficient CO2 methanation.

High specific surface area LaFeCo perovskites—Synthesis by nanocasting and catalytic behavior in the reduction of NO with CO

2009 ◽  
Vol 90 (3-4) ◽  
pp. 441-450 ◽  
Author(s):  
R.K.C. de Lima ◽  
M.S. Batista ◽  
M. Wallau ◽  
E.A. Sanches ◽  
Y.P. Mascarenhas ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
Catalytic Behavior ◽  
Reduction Of No
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