scholarly journals An amorphous MoSx modified g-C3N4 composite for efficient photocatalytic hydrogen evolution under visible light

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 15900-15909 ◽  
Author(s):  
Xia Li ◽  
Bo Wang ◽  
Xia Shu ◽  
Dongmei Wang ◽  
Guangqing Xu ◽  
...  

An MoSx/g-C3N4 composite photocatalyst was successfully fabricated by a sonochemical approach, where amorphous MoSx was synthesized using a hydrothermal method, and g-C3N4 nanosheets were produced using a two-step thermal polycondensation method.

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Qingyun Chen ◽  
Cheng Suo ◽  
Shu Zhang ◽  
Yunhai Wang

To investigate the effect of PdS as a cocatalyst for photocatalytic hydrogen evolution, nanostructured PdS/CdS were prepared by an in situ coprecipitation and hydrothermal method, respectively. The as-prepared photocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), UV-visible absorption spectra, and photoluminescence spectra (PL). With PdS highly dispersed in the CdS nanostructures, the photoactivity was evaluated by hydrogen evolution from aqueous solution containing Na2S/Na2SO3as sacrificial reagents under visible light irradiation. When the concentration of PdS was 1% by weight, PdS/CdS, prepared by the in situ coprecipitation, showed the highest photocatalytic activity, while that prepared by hydrothermal method showed the most stability for hydrogen evolution. The effect of highly dispersed PdS on the photoactivity was discussed.


RSC Advances ◽  
2015 ◽  
Vol 5 (121) ◽  
pp. 100123-100128 ◽  
Author(s):  
Shunta Nishioka ◽  
Kazuhiko Maeda

Photocatalytic activity of Rh-doped BaTiO3 nanocrystals for hydrogen evolution from water under visible light (λ > 420 nm) was improved by applying a hydrothermal method for the preparation.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


2020 ◽  
Vol 10 (6) ◽  
pp. 1609-1618 ◽  
Author(s):  
Chao Zhang ◽  
Jiandong Liu ◽  
Xingliang Liu ◽  
Shiai Xu

Reaction mechanism for the higher photocatalytic performance of H2 production of g-C3N4NSs/TC1 under visible light irradiation (λ ≥ 400 nm).


2020 ◽  
Vol 124 (11) ◽  
pp. 5934-5943 ◽  
Author(s):  
Xinlei Guo ◽  
Yanhua Peng ◽  
Guangbo Liu ◽  
Guangwen Xie ◽  
Yanan Guo ◽  
...  

2008 ◽  
Vol 81 (8) ◽  
pp. 927-937 ◽  
Author(s):  
Kazuhiko Maeda ◽  
Hiroaki Terashima ◽  
Kentaro Kase ◽  
Masanobu Higashi ◽  
Masashi Tabata ◽  
...  

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