scholarly journals Determination of the absolute CH4 adsorption using simplified local density theory and comparison with the modified Langmuir adsorption model

RSC Advances ◽  
2018 ◽  
Vol 8 (72) ◽  
pp. 41509-41516
Author(s):  
Yeyu Zhang ◽  
Shaonan Zhang ◽  
Zhicheng Wang ◽  
Hucheng Deng ◽  
Minghui Qi ◽  
...  

Accurately determining the adsorbed amount of CH4 on shale is significant for understanding the mechanisms of shale gas storage and shale methane recovery from shale gas reservoirs.

2014 ◽  
Vol 69 (12) ◽  
pp. 2497-2503 ◽  
Author(s):  
Chen Li ◽  
Yan Fen-xia ◽  
Yang Shuai ◽  
Chai Shu-li ◽  
Ma Pei-qin

This article reports on an investigation into the ability of modified lettuce leaves to extract chromium ions from aqueous solutions. These exciting new materials were prepared via rapid (5 h) environmentally friendly synthesis routes avoiding any secondary pollution. The influence of pH, metal concentration, the adsorption of the added amount, and water temperature on the selectivity and sensitivity of the removal process was investigated. The maximum theoretical adsorption rate of modified lettuce leaves, evaluated by the Langmuir adsorption model, was 99.98%. The proposed method was applied in the determination of Cr6+ in a sample of aqueous solution and was validated by comparison with activated carbon.


2013 ◽  
Vol 787 ◽  
pp. 138-142 ◽  
Author(s):  
De Shuai Sun ◽  
Long Fang ◽  
Tao Liu

Ultrasound can promote the dye-uptake in the dyeing process. The effects of ultrasound on the fiber, dye and dyeing system were investigated by dyeing cotton fabrics with a direct dye. The dye exhaustion exceeded 80% in 30 minutes with the assistant of ultrasound. Langmuir adsorption model could descript the ultrasound dyeing process of direct dye. The area of fiber accessibility of cotton fiber increased 1.68 times under the action of ultrasound. The absorbance of direct dye solution increased remarkably in the first 10 minutes of ultrasound irradiation. Ultrasound accelerated the diffusion of dye on cotton fiber, and then the diffusion coefficient increased 46 times


2007 ◽  
Vol 245 (2) ◽  
pp. 415-427 ◽  
Author(s):  
Y JI ◽  
V KOOT ◽  
A VANDEREERDEN ◽  
B WECKHUYSEN ◽  
D KONINGSBERGER ◽  
...  

2021 ◽  
Author(s):  
Ahmed F. Molouk ◽  
Mohamed F. Atia ◽  
Abd El-Aziz S. Fouda

Abstract Aizoon extract used as anti-corrosion for stainless steel430 (SS430) in 2M hydrochloric acid solution. The mass reduction, electrochemical impedance, and potentiodynamic polarization were carried out to demonstrate the performance of Aizoon extract as corrosion resistance for SS430. Polarization revealed that the Aizoon extract is mixed type inhibitor with superiority to inhibiting the cathodic reaction. The inhibition percentage reaches 93% at 300 ppm extract. Adsorption of the extract on SS430 surface is regular with Langmuir adsorption model. Thermodynamic factors for adsorption and activation processes for SS430 dissolution were estimated and discussed. Furthermore, the SS430 surface is characterized using different techniques. The surface morphology of SS430 was tested utilizing several techniques. The experimental data were supported by the theoretical data.


Author(s):  
Bo Zhang ◽  
Akira Nakajima

Numerical analysis of the adsorbed film thickness at the air bearing surface is conducted using the non-Langmuir adsorption model. It is found that the adsorbed film at the air bearing surface becomes significant when the viscosity of adsorbed film is higher than about 1 Pa s. The adsorbed contaminant will accumulate at the rear end of the slider, and it is possible that the accumulated liquid-like contaminant may form a liquid tail which will directly contact with the disk surface, resulting in a crush of the head/disk interface.


Author(s):  
S. M. Yang ◽  
T. I. Yin ◽  
C. Chang

A 1 cm × 1 cm biosensor chip for analyzing DNA hybridization is developed by CMOS process. The sensor chip has 6 measurement regions, each region with 3 pairs of parallel microcantilever of 125 × 60 × 0.75μm. The microcantilever is a 4-layer structure composed of an immobilized surface layer, a top insulation layer, an embedded piezoresistive layer, and a bottom insulation layer to measure the nano-deformation induced by the surface-assemble monolayer of alkanethiols on Au. By the Langmuir adsorption model, the estimated adsorption rate of the ssDNA is 0.005sec−1. The design has intrinsic sensitivity needed in biochemical applications such as detecting nucleotide polymorphism and single base mutation to sequence DNA. The capability of in-situ, multipoint measurement promise many frontiers to be explored.


2010 ◽  
Vol 8 (3) ◽  
pp. 314-319 ◽  
Author(s):  
Muzakky Muzakky

Prediction of adsorption model of Mn2+, Cd2+ and Hg2+ in water-sediment systems along Code River, Yogyakarta has been experimentally investigated. The aim of this investigation is to predict the transfer models based on isotherm adsorption of Mn2+, Cd2+ and Hg2+ metal ions from water into sediment. In addition, this investigation is expected to be able to inform the initial condition of Code River, dynamics, and the fate of Mn2+, Cd2+ and Hg2+ ions from upstream to downstream. Based on the investigation the transfer of Mn2+, and Cd2+ ions into sediment follows Langmuir adsorption model, with the coefficient determination (R2) of 0,9916 and 0,9799, while the value of the adsorption energy are 20,95 kJ/mol and 16,85 kJ/mol. The transfer of Hg2+ ion tend to follow Freundlich adsorption model. From the adsorption energies, it is proven  that Mn2+ ion was chemically sorpted into the sediment, while Cd2+ ion will tend to be physically sorpted into the sediment. The binding strength of which ise in the order of Mn2+ > Cd2+ and the adsorption energy of Hg2+ ion could not be determined.   Keywords: adsorption model, chemically sorpted, physically sorpted


2021 ◽  
pp. 101244
Author(s):  
Shangbin Chen ◽  
Zhuo Gong ◽  
Xueyuan Li ◽  
Huijun Wang ◽  
Yang Wang ◽  
...  

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