scholarly journals A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers

RSC Advances ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 4157-4161 ◽  
Author(s):  
Kun He ◽  
Pu Xie ◽  
Chengkui Zu ◽  
Yanhang Wang ◽  
Baoying Li ◽  
...  

A flexible lithium ion conductive Li1.5Al0.5Ge1.5(PO4)3 glass-ceramic fiber was prepared by melt-spun method.

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 395 ◽  
Author(s):  
Shuo Yang ◽  
Hanna Heyl ◽  
Daniel Homa ◽  
Gary Pickrell ◽  
Anbo Wang

In this paper we report the fabrication of glass-clad BaO-TiO2-SiO2 (BTS) glass–ceramic fibers by powder-in-tube reactive molten-core drawing and successive isothermal heat treatment. Upon drawing, the inserted raw powder materials in the fused silica tubing melt and react with the fused silica tubing (housing tubing) via dissolution and diffusion interactions. During the drawing process, the fused silica tubing not only serves as a reactive crucible, but also as a fiber cladding layer. The formation of the BTS glass–ceramic structure in the core was verified by micro-Raman spectroscopy after the successive isothermal heat treatment. Second-harmonic generation and blue-white photoluminescence were observed in the fiber using 1064 nm and 266 nm picosecond laser irradiation, respectively. Therefore, the BTS glass–ceramic fiber is a promising candidate for all fiber based second-order nonlinear and photoluminescence applications. Moreover, the powder-in-tube reactive molten core method offers a more efficient and intrinsic contamination-free approach to fabricate glass–ceramic fibers.


2002 ◽  
Vol 27 (15) ◽  
pp. 1309 ◽  
Author(s):  
B. N. Samson ◽  
L. R. Pinckney ◽  
J. Wang ◽  
G. H. Beall ◽  
N. F. Borrelli
Keyword(s):  

RSC Advances ◽  
2019 ◽  
Vol 9 (54) ◽  
pp. 31699-31707 ◽  
Author(s):  
G. Gorni ◽  
Jose J. Velázquez ◽  
M. Kochanowicz ◽  
D. Dorosz ◽  
R. Balda ◽  
...  

Novel glass-ceramic optical fibers containing NaLuF4 nanocrystals doped with 0.5ErF3 and 2YbF3 (mol%) have been prepared by the rod-in-tube method and controlled crystallization.


2008 ◽  
Vol 368-372 ◽  
pp. 1007-1009
Author(s):  
M.T. Tsai ◽  
P.J. Tsai ◽  
H.C. Chang

Homogeneous and transparent enstatite fibers were prepared via the sol-gel process of metal alkoxide precursors. The gel-to-ceramic conversion was characterized. The solution compositions had a significant influence on the microstructural evolution of gel fibers. Infrared studies indicated that bidentate bridging ligands were formed between acetate and metal ions, which enhanced spinnability remarkably. The as-drawn fibers were essentially microporous. On heating to 800 oC, enstatite ceramic fibers exhibited mesoporous structures with nanocrystals in size. The optical transmittance of enstatite ceramic fiber in the visible range was around 90 % after heating at 800 oC.


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