scholarly journals Polymer–silica hybrid self-healing nano/microcapsules with enhanced thermal and mechanical stability

RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 1782-1791 ◽  
Author(s):  
Xin Zhou ◽  
Weiping Li ◽  
Liqun Zhu ◽  
Hui Ye ◽  
Huicong Liu

Robust polymer–silica hybrid nano/microcapsules are prepared and characterized; they have excellent mechanical property and self-healing ability in a coating.

2018 ◽  
Vol 26 (4) ◽  
pp. 365-373 ◽  
Author(s):  
Lei Ling ◽  
Jinhui Li ◽  
Guoping Zhang ◽  
Rong Sun ◽  
Ching-Ping Wong

2020 ◽  
Author(s):  
Lun Zhang ◽  
Dong Wang ◽  
Liqiang Xu ◽  
Aimin Zhang

Supramolecular elastomer, possessing excellent mechanical property, reusable adhesivity, and rapid self-healing, is essential in various applications. Herein, we developed a novel polyamide-urea elastomer with metal-ligand interaction, hydrogen bonds synergetic double...


Author(s):  
Fangfang Xue ◽  
Yangyang Li ◽  
Chen Liu ◽  
Zhigang Zhang ◽  
Jun Lin ◽  
...  

Constructing suitable electrode materials with high capacity and excellent mechanical property is indispensable for flexible lithium-ion batteries (LIBs) to satisfy the growing flexible and wearable electronic devices. Herein, a necklace-like...


2016 ◽  
Vol 7 (47) ◽  
pp. 7278-7286 ◽  
Author(s):  
Jian Zhao ◽  
Rui Xu ◽  
Gaoxing Luo ◽  
Jun Wu ◽  
Hesheng Xia

The poly(siloxane-urethane) elastomers with microphase separation structure and Diels–Alder bonds show high healing efficiency, good mechanical property and good biocompatibility.


2021 ◽  
Vol 146 ◽  
pp. 110258
Author(s):  
Lipei Yue ◽  
Xiaoyong Zhang ◽  
Yijing Wang ◽  
Weidong Li ◽  
Ying Tang ◽  
...  

2022 ◽  
Vol 23 (2) ◽  
pp. 842
Author(s):  
Ahmed Ali Nada ◽  
Anita Eckstein Andicsová ◽  
Jaroslav Mosnáček

Electrically conductive materials that are fabricated based on natural polymers have seen significant interest in numerous applications, especially when advanced properties such as self-healing are introduced. In this article review, the hydrogels that are based on natural polymers containing electrically conductive medium were covered, while both irreversible and reversible cross-links are presented. Among the conductive media, a special focus was put on conductive polymers, such as polyaniline, polypyrrole, polyacetylene, and polythiophenes, which can be potentially synthesized from renewable resources. Preparation methods of the conductive irreversible hydrogels that are based on these conductive polymers were reported observing their electrical conductivity values by Siemens per centimeter (S/cm). Additionally, the self-healing systems that were already applied or applicable in electrically conductive hydrogels that are based on natural polymers were presented and classified based on non-covalent or covalent cross-links. The real-time healing, mechanical stability, and electrically conductive values were highlighted.


2020 ◽  
Vol 246 ◽  
pp. 118480 ◽  
Author(s):  
Peng He ◽  
Jianying Yu ◽  
Ruiyang Wang ◽  
Wei Du ◽  
Xiaobin Han ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 487
Author(s):  
Yusheng Liu ◽  
Yigang Liu ◽  
Qiuxia Wang ◽  
Yugui Han ◽  
Hao Chen ◽  
...  

The incorporation of double dynamic bonds into hydrogels provides an effective strategy to engineer their performance on demand. Herein, novel hydrogels were PREPARED by combining two kinetically distinct dynamic covalent bonds, boronate ester and acylhydrazone bonds, and the synergistic properties of the hydrogels were studied comprehensively. The functional diblock copolymers P(N-isopropyl acrylamide-co-N-acryloyl-3-aminophenylboronic acid)-b-(N-isopropyl acrylamide-co-diacetone acrylamide) (PAD) were prepared via reversible addition−fragmentation chain transfer (RAFT) polymerization. The hydrogel was constructed by exploiting dynamic reaction of phenyboronic acid moieties with polyvinyl alcohol (PVA) and ketone moieties with adipic dihydrazide (ADH) without any catalyst. The active boronate ester linkage endows the hydrogel with fast gelation kinetics and self-healing ability, and the stable acylhydrazone linkage can enhance the mechanical property of the hydrogel. The difference in kinetics endows that the contribution of each linkage to mechanical strength of the hydrogel can be accurately estimated. Moreover, the mechanical property of the hydrogel can be readily engineered by changing the composition and solid content, as well as by controlling the formation or dissociation of the dynamic linkages. Thus, we provide a promising strategy to design and prepare multi-responsive hydrogels with tunable properties.


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