scholarly journals Structure and luminescence properties of La6Ba4(SiO4)6F2:Dy3+ phosphor with apatite structure

RSC Advances ◽  
2018 ◽  
Vol 8 (68) ◽  
pp. 38883-38890 ◽  
Author(s):  
Jialei Zhang ◽  
Qingfeng Guo ◽  
Libing Liao ◽  
Yongjie Wang ◽  
Mingyue He ◽  
...  
Keyword(s):  
Thermal Stability ◽  
White Light ◽  
Single Phase ◽  
Luminescence Properties ◽  
Apatite Structure ◽  
Light Emitting ◽  
Good Thermal Stability

Single-phase white light emitting La6Ba4(SiO4)6F2:Dy3+ phosphors with good thermal stability were obtained.

scholarly journals A novel single-phase white light emitting phosphor Ca9La(PO4)5(SiO4)F2:Dy3+: synthesis, crystal structure and luminescence properties

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24577-24583 ◽  
Author(s):  
Haikun Liu ◽  
Libing Liao ◽  
Maxim S. Molokeev ◽  
Qingfeng Guo ◽  
Yuanyuan Zhang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Temperature ◽  
Solid State ◽  
White Light ◽  
Single Phase ◽  
Luminescence Properties ◽  
Light Emitting ◽  
State Technology

A novel single-phase white light emitting phosphor Ca9La(PO4)5(SiO4)F2:Dy3+ was prepared through traditional high-temperature solid state technology.

scholarly journals Crystal Structure and Luminescence Properties of a Thermally Stable Single-Phase White Emitting Phosphor CaSr2(PO4)2: Dy3+, Li+

2021 ◽  
Author(s):  
Qingfeng Guo ◽  
Yuying Chen ◽  
Qiang Hao ◽  
Stefan Lis ◽  
Haikun Liu ◽  
...  
Keyword(s):  
White Light ◽  
Single Phase ◽  
Emission Spectra ◽  
Luminescence Properties ◽  
Solid State Method ◽  
Excellent Thermal Stability ◽  
Light Emitting ◽  
Diffraction Patterns ◽  
White Light Emitting Diodes ◽  
White Luminescence

Abstract Single-phase CaSr2(PO4)2:Dy3+,Li+ phosphors were prepared using the high-temperature solid-state method in the air. To characterize the luminescence properties of the synthesized phosphors, Powder X-ray diffraction patterns (XRD), scanning electron microscopy images (SEM), photoluminescence spectra, and concentration-dependent emission spectra were measured to characterize the luminescence properties of the synthesized phosphors. The results showed that the CaSr2(PO4)2:Dy3+,Li+ phosphors exhibited white luminescence, and the emission spectra of the phosphors consisted of two sharp peaks at ≈486 and ≈578 nm (the most intense one). The optimum concentration of Dy3+ doping was determined to 0.06 mol.%. On the basis of the Dexter's theory, the mechanism of energy transfer between the Dy3+ ions was determined to dipole–dipole interactions. The results of the temperature-dependent luminescence confirmed that the as-prepared phosphors are proved to be promising UV-convertible material capable of white light emitting in UV-LEDs due to its excellent thermal stability and luminescence properties. Luminescence intensity and decay time of the CaSr2(PO4)2:Dy3+,Li+ phosphors were improved remarkably with the addition of charge compensators (Li+ ions), which would promote their applications in white light-emitting diodes based on the near-UV chip.

A single-phase white light emitting phosphor Ba3Y(PO4)3:Ce3+/Eu2+/Mn2+: Luminescence, energy transfer and thermal stability

2019 ◽  
Vol 210 ◽  
pp. 322-334 ◽  
Author(s):  
Yun Chen ◽  
Zhijun Wang ◽  
Wenge Ding ◽  
Xue Li ◽  
Qi Bao ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Energy Transfer ◽  
White Light ◽  
Single Phase ◽  
Light Emitting

A New Blue-Emitting Mg2Al4Si5O18:Ce3+ Phosphor for White Light Emitting Diodes

2016 ◽  
Vol 16 (4) ◽  
pp. 3506-3510 ◽  
Author(s):  
Jian Chen ◽  
Hongyun Ma ◽  
Yangai Liu
Keyword(s):  
Thermal Stability ◽  
White Light ◽  
Light Emitting Diodes ◽  
Broad Band ◽  
Blue Emission ◽  
Solid State Reaction Method ◽  
Light Emitting ◽  
Good Thermal Stability ◽  
Near Ultraviolet ◽  
White Light Emitting Diodes

A series of blue-emitting Mg2Al4Si5O18:Ce3+ phosphors were prepared via the conventional high temperature solid-state reaction method. The phase structure, photoluminescence (PL) properties, PL thermal stability, and fluorescence decay curves of the samples were investigated for the first time. Under excitation at 365 nm, the phosphor exhibited a broad band blue emission with peak at 440 nm, which was ascribed to the 4f → 5d transition of Ce3+, and the color coordinate was (0.1602, 0.0849). When the temperature increased to 150 °C, the luminescence intensity of the Mg2Al4Si5O18:0.06Ce3+ phosphor was 55.73% of the initial value at room temperature. The activation energy ΔE was calculated to be 0.25 eV, which proved the good thermal stability of the sample. The energy transfer critical distance between Ce3+ ions in Mg2Al4Si5O18 host were also calculated. The above results indicate that the Mg2Al4Si5O18:Ce3+ is a promising candidate as a blue-emitting near ultraviolet convertible phosphor for application in white light emitting diodes (WLEDs).

scholarly journals A single-phase white light emitting phosphor Ba3Y(PO4)3:Ce3+/Tb3+/Mn2+: luminescence, energy transfer and thermal stability

RSC Advances ◽  
2019 ◽  
Vol 9 (52) ◽  
pp. 30406-30418 ◽  
Author(s):  
Yun Chen ◽  
Wenge Ding ◽  
Panlai Li ◽  
Xue Li ◽  
Qi Bao ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Energy Transfer ◽  
High Temperature ◽  
Solid State ◽  
White Light ◽  
Single Phase ◽  
Solid State Method ◽  
Light Emitting ◽  
State Method

A series of Ce3+/Tb3+, Tb3+/Mn2+ and Ce3+/Tb3+/Mn2+ doped Ba3Y(PO4)3 were synthesized by the high temperature solid state method.

scholarly journals High Thermal Stability Apatite Phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ for White Light Emission: Synthesis, Structure, Luminescence Properties and Energy Transfer

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Libing Liao ◽  
Jie Fu ◽  
Dan Yang
Keyword(s):  
Thermal Stability ◽  
Energy Transfer ◽  
White Light ◽  
Single Phase ◽  
Light Emission ◽  
High Thermal Stability ◽  
White Light Emission ◽  
Luminescence Properties ◽  
Potential Candidate ◽  
Co Doped

Abstract What ideal w-LED phosphors always aim to do is to achieve a single phase near-sunlight emission phosphor simultaneously with both high luminescence efficiency and high thermal stability at operation temperature. And It is well known that apatite compound phosphors are one of the most promising optical materials to realize those above because of their unique structure enhanced luminescence properties and thermal stability. Here, we synthesized a co-doped single phase apatite phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ (CLSO:Dy3+/Sm3+) for white light emission, which was provided with excellent thermal stability and of which luminescence intensity at 150 °C still was 92 percentage of that at room temperature. Moreover, X-ray diffraction technique, Fourier transform infrared spectroscopy, scanning electron microscope were employed to characterization of phase structure and morphology, and consequently pure apatite structure and gravel-like morphology of phosphors were proved. Analysis of photoluminescence spectra indicated that concentration quenching effect exist in single-doped CLSO:Dy3+ phosphors owing to dipole-dipole interaction between Dy3+ ions. It is revealed that maybe exist Dy3+ ↔ Sm3+ bilateral non-radiative energy transfer processes in Dy3+/Sm3+ co-doped CLSO system by PL spectra and decay curves. And variation of Sm3+ ion concentration can control color emission, namely CIE chromaticity coordinates and correlated color temperature, finally to achieve white light emission (0.309,0.309) with CCT 6848 K, able to be a potential candidate for commercial lighting applications.

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