scholarly journals Conversion of levulinic acid to γ-valerolactone over Ru/Al2O3–TiO2 catalyst under mild conditions

RSC Advances ◽  
2018 ◽  
Vol 8 (71) ◽  
pp. 40989-40995 ◽  
Author(s):  
Ruifeng Wang ◽  
Lungang Chen ◽  
Xinghua Zhang ◽  
Qi Zhang ◽  
Yuping Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Levulinic Acid ◽  
Hydrothermal Stability ◽  
High Catalytic Activity ◽  
Tio2 Catalyst ◽  
Mild Conditions ◽  
Efficient Conversion ◽  
Catalytic Material

Novel catalytic material with high catalytic activity and hydrothermal stability plays a key role in the efficient conversion of levulinic acid (LA) to γ-valerolactone (GVL) in water.

scholarly journals Immobilization of an Iridium(I)-NHC-Phosphine Catalyst for Hydrogenation Reactions under Batch and Flow Conditions

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 656
Author(s):  
Henrietta Kovács ◽  
Krisztina Orosz ◽  
Gábor Papp ◽  
Ferenc Joó ◽  
Henrietta Horváth
Keyword(s):  
Catalytic Activity ◽  
Ion Exchange ◽  
Heterogeneous Catalyst ◽  
Aqueous Phase ◽  
Levulinic Acid ◽  
Flow Reactor ◽  
High Catalytic Activity ◽  
Flow Conditions ◽  
Hydrogenation Reactions ◽  
Excellent Selectivity

Na2[Ir(cod)(emim)(mtppts)] (1) with high catalytic activity in various organic- and aqueous-phase hydrogenation reactions was immobilized on several types of commercially available ion-exchange supports. The resulting heterogeneous catalyst was investigated in batch reactions and in an H-Cube flow reactor in the hydrogenation of phenylacetylene, diphenylacetylene, 1-hexyne, and benzylideneacetone. Under proper conditions, the catalyst was highly selective in the hydrogenation of alkynes to alkenes, and demonstrated excellent selectivity in C=C over C=O hydrogenation; furthermore, it displayed remarkable stability. Activity of 1 in hydrogenation of levulinic acid to γ-valerolactone was also assessed.

Single-atom transition metals supported on black phosphorene for electrochemical nitrogen reduction

Nanoscale ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 4903-4908 ◽  
Author(s):  
Kang Liu ◽  
Junwei Fu ◽  
Li Zhu ◽  
Xiaodong Zhang ◽  
Hongmei Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transition Metals ◽  
Reduction Reaction ◽  
Single Atom ◽  
High Catalytic Activity ◽  
Nitrogen Reduction ◽  
Mild Conditions ◽  
Black Phosphorene

Electrochemical nitrogen reduction reaction (NRR) is a promising route to produce ammonia under mild conditions. Single-atom W supported on BP was screened as a promising electrocatalyst with high catalytic activity, stability, and selectively for NRR.

Facile fabrication of a heterogeneous Co-modified pyridinecarboxaldehyde-polyethylenimine catalyst for efficient CO2 conversion under mild conditions

2020 ◽  
Vol 7 (5) ◽  
pp. 1140-1147
Author(s):  
Chao Liu ◽  
Li Yang ◽  
Jiaxu Zhang ◽  
Jianmin Sun
Keyword(s):  
Catalytic Activity ◽  
Ambient Temperature ◽  
High Catalytic Activity ◽  
Co2 Conversion ◽  
Mild Conditions ◽  
Active Metal ◽  
Facile Fabrication ◽  
Amine Groups

A heterogeneous Co-modified pyridinecarboxaldehyde-polyethylenimine catalyst with active metal sites and amine groups exhibited high catalytic activity for CO2 conversion under mild conditions, even at ambient temperature.

Tin sulfide and selenide clusters soluble in organic solvents with the core structures of Sn4S6 and Sn4Se6

2015 ◽  
Vol 44 (46) ◽  
pp. 19800-19804 ◽  
Author(s):  
Mingdong Zhong ◽  
Zhi Yang ◽  
Yafei Yi ◽  
Dongxiang Zhang ◽  
Kening Sun ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Organic Solvents ◽  
High Catalytic Activity ◽  
Tin Sulfide ◽  
Chalcogenide Clusters ◽  
Mild Conditions ◽  
The Core

Reactions of LSnCl (1) (L = N(2,6-iPr2C6H3)(SiMe3)) with sulfur and selenium, respectively under mild conditions yielded two tin chalcogenide clusters. The two products show high catalytic activity in ROP catalysis.

Towards rational design of core–shell catalytic nanoreactor with high performance catalytic hydrogenation of levulinic acid

2016 ◽  
Vol 6 (13) ◽  
pp. 5102-5115 ◽  
Author(s):  
Biplab Banerjee ◽  
Ramana Singuru ◽  
Sudipta K. Kundu ◽  
Karnekanti Dhanalaxmi ◽  
Linyi Bai ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Hydrogenation ◽  
Levulinic Acid ◽  
High Performance ◽  
Rational Design ◽  
Core Shell ◽  
High Catalytic Activity

Core–shell catalytic nanoreactor was designed, exhibiting high catalytic activity for levulinic acid hydrogenation.

scholarly journals Low temperature oxidation of o-xylene with hydrogen peroxide in the presence of vanadium xerogels

2017 ◽  
pp. 26-31
Author(s):  
Nurlykyz Yesmurzaeva ◽  
Roza Tursunova ◽  
Bagadat Selenova ◽  
Daulet Kaldybekov ◽  
Sarkyt Kudaibergenov
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Titanium Oxide ◽  
Oxidation Process ◽  
High Catalytic Activity ◽  
Vanadium Catalyst ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Mild Conditions ◽  
Physicochemical Methods

The present work is dedicated to investigation of vanadium xerogels deposited on titanium oxide for the oxidation process of o-xylene by hydrogen peroxide under the mild conditions. The structure of deposited vanadium catalyst and sizes of vanadium xerogels nanoparticles were investigated by physicochemical methods. The nano-sized particles (5-8 nm) of xerogel vanadium deposited on titanium oxide exhibit high catalytic activity in the decomposition of hydrogen peroxide and in the oxidation of o-xylene by hydrogen peroxide under mild conditions.

A reconstruction strategy to synthesize mesoporous SAPO molecular sieve single crystals with high MTO catalytic activity

2016 ◽  
Vol 52 (38) ◽  
pp. 6463-6466 ◽  
Author(s):  
Chan Wang ◽  
Miao Yang ◽  
Mingrun Li ◽  
Shutao Xu ◽  
Yue Yang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Single Crystals ◽  
Molecular Sieve ◽  
Hydrothermal Stability ◽  
High Catalytic Activity ◽  
Mto Reaction ◽  
Reconstruction Strategy ◽  
Fast Synthesis

A reconstruction strategy for the fast synthesis of mesoporous SAPO molecular sieve single crystals has been developed. The synthesized mesoporous SAPO-34 single crystals exhibit excellent hydrothermal stability and high catalytic activity in the MTO reaction.

scholarly journals Improving the hydrothermal stability of zeolite Y by La3+ cation exchange as a catalyst for the aqueous-phase hydrogenation of levulinic acid

RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5568-5579
Author(s):  
Hue-Tong Vu ◽  
Michael Goepel ◽  
Roger Gläser
Keyword(s):  
Catalytic Activity ◽  
Formic Acid ◽  
Cation Exchange ◽  
Aqueous Phase ◽  
Levulinic Acid ◽  
Zeolite Y ◽  
Hydrothermal Stability

La3+ cation exchange is shown to improve the hydrothermal stability and catalytic activity of bifunctional zeolite Pt/Y catalysts in the aqueous-phase hydrogenation of levulinic acid (LA) with formic acid (FA) as hydrogen source.

scholarly journals An Efficient Hydration and Tandem Transfer Hydrogenation of Alkynes for the Synthesis of Alcohol in Water

Synthesis ◽  
2020 ◽  
Vol 52 (22) ◽  
pp. 3439-3445
Author(s):  
Lu Ouyang ◽  
Renshi Luo ◽  
Nianhua Luo ◽  
Yuhong Zhong ◽  
Ji-Tian Liu
Keyword(s):  
Catalytic Activity ◽  
Formic Acid ◽  
Efficient Method ◽  
Transfer Hydrogenation ◽  
High Catalytic Activity ◽  
Turnover Frequency ◽  
One Pot ◽  
Mild Conditions ◽  
Tandem Process ◽  
Metal Ligand

A practical and efficient method for the synthesis of alcohols in one pot from readily available alkynes via a tandem process by formic acid promoted hydration and metal-ligand bifunctional iridium-catalyzed­ transfer hydrogenation under mild conditions has been described. This transformation is simple, efficient, and can be performed with a variety of alkynes in good yields and with excellent stereoselectivities. Experimental results showed high catalytic activity, and turnover frequency (TOF) up to 25000. Importantly, this transformation can be conducted in water, and is thus green and environmentally friendly.

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