scholarly journals Green and facile production of high-quality graphene from graphite by the combination of hydroxyl radical and electrical exfoliation

RSC Advances ◽  
2018 ◽  
Vol 8 (71) ◽  
pp. 40621-40631 ◽  
Author(s):  
Xin Wang ◽  
Long Zhang
Keyword(s):  
Hydroxyl Radical ◽  
Hydroxyl Radicals ◽  
Efficient Method ◽  
High Quality ◽  
Green Production ◽  
First Time

A novel, simple and efficient method, involving the combination of hydroxyl radicals and electrical exfoliation of graphite for the green production of high-quality graphene from graphite, was developed for the first time.

scholarly journals Green and facile production of high-quality graphene from graphite by the combination of hydroxyl radicals and electrical exfoliation in different electrolyte systems

RSC Advances ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 3693-3703 ◽  
Author(s):  
Xin Wang ◽  
Long Zhang
Keyword(s):  
Hydroxyl Radicals ◽  
Efficient Method ◽  
High Quality ◽  
Green Production

A novel, simple and efficient method by the combination of hydroxyl radicals and electrical exfoliation of graphite for the green production of high-quality graphene from graphite was first developed in our self-manufactured exfoliation apparatus.

scholarly journals Hydroxyl radical production induced by plasma hydrogenated nanodiamonds under X-ray irradiation

2017 ◽  
Vol 53 (7) ◽  
pp. 1237-1240 ◽  
Author(s):  
Magdalena Kurzyp ◽  
Hugues A. Girard ◽  
Yannis Cheref ◽  
Emilie Brun ◽  
Cecile Sicard-Roselli ◽  
...  
Keyword(s):  
Hydroxyl Radical ◽  
Hydroxyl Radicals ◽  
Detonation Nanodiamonds ◽  
X Ray ◽  
Radical Production ◽  
First Time

For the first time, overproduction of hydroxyl radicals (HO˙) induced by plasma hydrogenated detonation nanodiamonds (H-NDs) under X-ray irradiation is reported.

scholarly journals Kinetic study of hydroxyl radical formation in a continuous hydroxyl generation system

RSC Advances ◽  
2018 ◽  
Vol 8 (71) ◽  
pp. 40632-40638 ◽  
Author(s):  
Xin Wang ◽  
Long Zhang
Keyword(s):  
Hydroxyl Radical ◽  
Kinetic Study ◽  
Hydroxyl Radicals ◽  
Radical Formation ◽  
Generation System ◽  
Simple Apparatus ◽  
System P ◽  
Continuous Generation ◽  
First Time

A novel and simple apparatus for the continuous generation of hydroxyl radicals has been constructed for the first time.

Disability as a social phenomenon

2020 ◽  
pp. 22-38
Author(s):  
Natalia Guseva ◽  
Vitaliy Berdutin
Keyword(s):  
Social Protection ◽  
Russian Society ◽  
Stage Model ◽  
High Quality ◽  
Rehabilitation Programs ◽  
Current State ◽  
The Social ◽  
Consistent Solution ◽  
First Time

At present, the problem of establishing disability is a point at issue in Russia. Despite the fact that medical criteria for disability are being developed very actively, high-quality methods for assessing social hallmarks are still lacking. Since disability is a phenomenon inherent in any society, each state forms a social and economic policy for people with disabilities in accordance with its level of development, priorities and opportunities. We have proposed a three-stage model, which includes a system for the consistent solution of the main tasks aimed at studying the causes and consequences of the problems encountered today in the social protection of citizens with health problems. The article shows why the existing approaches to the determination of disability and rehabilitation programs do not correspond to the current state of Russian society and why a decrease in the rate of persons recognized as disabled for the first time does not indicate an improvement in the health of the population. The authors proposed a number of measures with a view to correcting the situation according to the results of the study.

Enhancement of hydroxyl radical generation by phenols and their reaction intermediates during ozonation

1998 ◽  
Vol 38 (6) ◽  
pp. 147-154 ◽  
Author(s):  
Hideo Utsumi ◽  
Sang-Kuk Han ◽  
Kazuhiro Ichikawa
Keyword(s):  
Hydroxyl Radical ◽  
Hydroxyl Radicals ◽  
Spin Trapping ◽  
Active Species ◽  
Generation Rate ◽  
Peak Height Ratio ◽  
Dependent Manner ◽  
Concentration Dependent Manner ◽  
Phenol Derivatives ◽  
Semiquinone Radicals

Generation of hydroxyl radicals, one of the major active species in ozonation of water was directly observed with a spin-trapping/electron spin resonance (ESR) technique using 5,5-dimethyl-1-pyrrolineN-oxide (DMPO) as a spin-trapping reagent. Hydroxyl radical were trapped with DMPO as a stable radical, DMPO-OH. Eighty μM of ozone produced 1.08 X 10-6M of DMPO-OH, indicating that 1.4% of •OH is trapped with DMPO. Generation rate of DMPO-OH was determined by ESR/stopped-flow measurement. Phenol derivatives increased the amount and generation rate of DMPO-OH, indicating that phenol derivatives enhance •OH generation during ozonation of water. Ozonation of 2,3-, 2,5-, 2,6-dichlorophenol gave an ESR spectra of triplet lines whose peak height ratio were 1:2:1. ESR parameters of the triplet lines agreed with those of the corresponding dichloro-psemiquinone radical. Ozonation of 2,4,5- and 2,4,6-trichlorophenol gave the same spectra as those of 2,5- and 2,6-dichlorophenol, respectively, indicating that a chlorine group in p-position is substituted with a hydroxy group during ozonation. Amounts of the radical increased in an ozone-concentration dependent manner and were inhibited by addition of hydroxyl radical scavengers. These results suggest that p-semiquinone radicals are generated from the chlorophenols by hydroxyl radicals during ozonation. The p-semiquinone radicals were at least partly responsible for enhancements of DMPO-OH generation.

Precursor engineering for high-quality Cs2AgBiBr6 films toward efficient lead-free double perovskite solar cells

2021 ◽  
Author(s):  
Ping Hou ◽  
Wenxiang Yang ◽  
Ning Wan ◽  
Zhi Fang ◽  
Jinju Zheng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Control Sample ◽  
Double Perovskite ◽  
Lead Free ◽  
High Quality ◽  
Precursor Engineering ◽  
First Time

We report a facile BiBr3(DMSO)2 adduct process to produce high-quality Cs2AgBiBr6 films with large grains for the first time, which leads to an enhancement of over 40% on the PCE of Cs2AgBiBr6-based solar cells compared to that of the control sample.

scholarly journals A Novel and Efficient High-Yield Method for Preparing Bacterial Ghosts

Toxins ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 420
Author(s):  
Yi Ma ◽  
Liu Cui ◽  
Meng Wang ◽  
Qiuli Sun ◽  
Kaisheng Liu ◽  
...  
Keyword(s):  
Large Scale ◽  
Expression System ◽  
High Yield ◽  
Wild Type ◽  
High Quality ◽  
Efficient Protection ◽  
Bacterial Ghosts ◽  
Cell Envelopes ◽  
Extracellular Structures ◽  
First Time

Bacterial ghosts (BGs) are empty cell envelopes possessing native extracellular structures without a cytoplasm and genetic materials. BGs are proposed to have significant prospects in biomedical research as vaccines or delivery carriers. The applications of BGs are often limited by inefficient bacterial lysis and a low yield. To solve these problems, we compared the lysis efficiency of the wild-type protein E (EW) from phage ΦX174 and the screened mutant protein E (EM) in the Escherichia coli BL21(DE3) strain. The results show that the lysis efficiency mediated by protein EM was improved. The implementation of the pLysS plasmid allowed nearly 100% lysis efficiency, with a high initial cell density as high as OD600 = 2.0, which was higher compared to the commonly used BG preparation method. The results of Western blot analysis and immunofluorescence indicate that the expression level of protein EM was significantly higher than that of the non-pLysS plasmid. High-quality BGs were observed by SEM and TEM. To verify the applicability of this method in other bacteria, the T7 RNA polymerase expression system was successfully constructed in Salmonella enterica (S. Enterica, SE). A pET vector containing EM and pLysS were introduced to obtain high-quality SE ghosts which could provide efficient protection for humans and animals. This paper describes a novel and commonly used method to produce high-quality BGs on a large scale for the first time.

STATISTICAL CHARACTERISTICS OF SLANT ANGLES IN HANDWRITTEN NUMERAL STRINGS AND EFFECTS OF SLANT CORRECTION ON SEGMENTATION

2010 ◽  
Vol 24 (01) ◽  
pp. 97-116 ◽  
Author(s):  
JAVAD SADRI ◽  
CHING Y. SUEN ◽  
TIEN D. BUI
Keyword(s):  
Efficient Method ◽  
Weighted Average ◽  
Correction Method ◽  
Statistical Characteristics ◽  
Geometric Features ◽  
Correction Algorithm ◽  
Connected Component ◽  
Slant Angle ◽  
Segmentation Accuracy ◽  
First Time

A novel and efficient method for correction of slant angles in handwritten numeral strings is proposed. For the first time, the statistical distribution of slant angles in handwritten numerals is investigated and the effects of slant correction on the segmentation of handwritten numeral strings are shown. In our proposed slant correction method, utilizing geometric features, a Component Slant Angle (CSA) is estimated for each connected component independently. A weighted average is then used to compute the String Slant Angle (SSA), which is applied uniformly to correct the slant of all the components in numeral strings. Our experimental results have revealed novel statistics for slant angles of handwritten numeral strings, and also showed that slant correction can significantly improve extraction of segmentation features and segmentation accuracy of touching numerals. Comparison between our slant correction algorithm and similar algorithms in the literature show that our algorithm is more efficient, and on average it has a faster running time.

scholarly journals Unraveling the long-pursued Au144 structure by x-ray crystallography

2018 ◽  
Vol 4 (10) ◽  
pp. eaat7259 ◽  
Author(s):  
Nan Yan ◽  
Nan Xia ◽  
Lingwen Liao ◽  
Min Zhu ◽  
Fengming Jin ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
Weak Interactions ◽  
Gold Nanoclusters ◽  
Atomic Level ◽  
High Quality ◽  
X Ray ◽  
X Ray Crystallography ◽  
Quantum Size ◽  
First Time

The transition from nanocluster to nanocrystal is a central issue in nanoscience. The atomic structure determination of metal nanoparticles in the transition size range is challenging and particularly important in understanding the quantum size effect at the atomic level. On the basis of the rationale that the intra- and interparticle weak interactions play critical roles in growing high-quality single crystals of metal nanoparticles, we have reproducibly obtained ideal crystals of Au144(SR)60 and successfully solved its structure by x-ray crystallography (XRC); this structure was theoretically predicted a decade ago and has long been pursued experimentally but without success until now. Here, XRC reveals an interesting Au12 hollow icosahedron in thiolated gold nanoclusters for the first time. The Au–Au bond length, close to that of bulk gold, shows better thermal extensibility than the other Au–Au bond lengths in Au144(SR)60, providing an atomic-level perspective because metal generally shows better thermal extensibility than nonmetal materials. Thus, our work not only reveals the mysterious, long experimentally pursued structure of a transition-sized nanoparticle but also has important implications for the growth of high-quality, single-crystal nanoparticles, as well as for the understanding of the thermal extensibility of metals from the perspective of chemical bonding.

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