scholarly journals Regression, kinetics and isotherm models for biosorption of organic pollutants, suspended and dissolved solids by environmentally friendly and economical dried Phragmites australis

RSC Advances ◽  
2018 ◽  
Vol 8 (71) ◽  
pp. 40511-40528
Author(s):  
Abeer El Shahawy ◽  
Ghada Heikal
Keyword(s):  
Functional Groups ◽  
Phragmites Australis ◽  
Organic Pollutants ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Isotherm Models ◽  
Dissolved Solids

Low cost adsorbents such as P. australis have received considerable interest owing to their low cost, large amount of functional groups and easy availability.

Removal of Organic Pollutants in Solution by Bamboo Charcoal

2013 ◽  
Vol 699 ◽  
pp. 554-556 ◽  
Author(s):  
Zi Lin Meng ◽  
Yi He Zhang ◽  
Qi An ◽  
Feng Zhu Lv ◽  
Qian Zhang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Kinetic Model ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Organic Pollutants ◽  
Organic Contaminants ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Bamboo Charcoal ◽  
Key Factors

Bamboo charcoal (BC) as an environmentally friendly and low-cost material receives widespread attention. Recently, much attention has been focused on the use of BC as adsorbent to treat wastewater. This paper provides an overview of the adsorption of organic contaminants in solution by using BC. The sorption behaviors of BC with various organic pollutants, and the kinetic model adopted to explain the adsorption rate of organic pollutants from aqueous solution were also reviewed. The adsorption capacity, the isotherm model, and several key factors such as modification, surface area, are discussed in this paper. Possible improvement of BC to treat organic contaminants in aqueous solution is also proposed.

scholarly journals Isotherm models and kinetics of copper adsorption by using hydrochar produced from hydrothermal carbonization of faecal sludge

2017 ◽  
Vol 7 (1) ◽  
pp. 102-110 ◽  
Author(s):  
Thammarat Koottatep ◽  
Krailak Fakkaew ◽  
Nutnicha Tajai ◽  
Chongrak Polprasert
Keyword(s):  
Functional Groups ◽  
Low Cost ◽  
Hydrothermal Carbonization ◽  
Pollutant Removal ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Surface Functional Groups ◽  
Water And Wastewater Treatment ◽  
Copper Adsorption ◽  
Faecal Sludge

Low cost adsorbents have been extensively reported for use as a promising substitution for commercial adsorbents for pollutant removal in water and wastewater treatment. In this study, hydrochar produced from the hydrothermal carbonization (HTC) of faecal sludge (FS) (called HTC-hydrochar) was further chemically modified with KOH (called KOH-hydrochar) to improve its surface functional groups, which were suitable for copper (Cu) removal. The adsorption of Cu was conducted using the produced HTC-hydrochar and KOH-hydrochar as absorbents. Experimental results showed the KOH-hydrochar could adsorb Cu at the maximum adsorption capacity of 18.6 mg-Cu/g-hydrochar with Cu removal efficiency of 93%, relatively higher than the HTC-hydrochar and a commercial powdered activated carbon. The quantity of the surface functional groups of the adsorbents was more effective in Cu removal than the surface area. The Cu adsorption mechanism was found to follow the pseudo-second order and intra-particle diffusion models and fit well with Freundlich and Langmuir isotherms. Application of hydrothermal carbonization could be a novel candidate to convert FS into hydrochar which is pathogen free, and to employ the produced hydrochar as an adsorbent to remove Cu from industrial wastewaters.

Selective determination of non-biodegradable polar, organic pollutants in waste water related to functional groups using flow injection combined with tandem mass spectrometry

1996 ◽  
Vol 34 (7-8) ◽  
pp. 21-28 ◽  
Author(s):  
H. Fr. Schröder
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Functional Groups ◽  
Organic Pollutants ◽  
Molar Mass ◽  
Sewage Treatment ◽  
Tandem Mass ◽  
Screening Process ◽  
Selective Determination ◽  
Characteristic Fragment

Effluents of biological sewage treatment plants mainly contain non-biodegradable, polar, organic pollutants of biogenic and anthropogenic origin. This paper presents a substance-specific determination method for these compounds, which are partly able to reach drinking water during the soil filtration process. Tandem mass spectrometry (MS/MS) combined with softly ionizing interfaces is applied for this purpose. The behaviour of the functional groups of these pollutants - forming characteristic fragment ions under MS/MS conditions and abstracting neutral particles - is used for detection. With help from this screening process on specific functional groups it is possible to establish the presence of substance groups with similar behaviour in the aquatic environment. Additionally this analytical procedure provides information on the molar mass of the pollutants detected. In a second step the compounds characterized by the molar mass and belonging to a group of pollutants with specific functional groups can be identified using MS/MS.

scholarly journals Cycloaddition of Thiourea- and Guanidine-Substituted Furans to Dienophiles: A Comparison of the Environmentally-Friendly Methods

2020 ◽  
Vol 3 (1) ◽  
pp. 57
Author(s):  
Luka Barešić ◽  
Davor Margetić ◽  
Zoran Glasovac
Keyword(s):  
High Pressure ◽  
Functional Groups ◽  
Organic Synthesis ◽  
High Speed ◽  
Environmentally Friendly ◽  
Microwave Assisted ◽  
Pressure Synthesis ◽  
Ultrasound Assisted ◽  
Substituted Furans ◽  
Guanidine Moiety

The cycloaddition strategy was employed in order to obtain a 7-oxanorbornene framework substituted with a guanidine moiety or its precursor functional groups: protected amine or thiourea. In order to optimize the conditions for the cycloaddition, several environmentally-friendly methods—microwave assisted organic synthesis, high pressure synthesis, high speed vibrational milling, and ultrasound assisted synthesis—were employed. The outcomes of the cycloaddition reactions were interpreted in terms of endo/exo selectivity, the conversion of the reactants to the product, and the isolated yields. In general, our results indicated the HP and HSVM approaches as the methods of choice to give good yields and conversions.

scholarly journals Fabrication of TiO2/Fe2O3/CdS systems: effects of Fe2O3 and CdS content on superior photocatalytic activity

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10300-10308
Author(s):  
Hui Feng ◽  
Siqi Feng ◽  
Niu Tang ◽  
Songbai Zhang ◽  
Xiangyang Zhang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photocatalytic Activity ◽  
Organic Pollutants ◽  
High Performance ◽  
Low Cost

New idea for the low cost synthesis of high performance photocatalysts for the photodegradation of organic pollutants in aqueous solution.

scholarly journals Removal of Cadmium(II) from Water using Modified Citrus limettioides Peels: Thermodynamic and Isotherm Studies

2019 ◽  
Vol 32 (1) ◽  
pp. 73-78
Author(s):  
P. Janaki ◽  
R. Sudha ◽  
T.S. Sribharathi ◽  
P. Anitha ◽  
K. Poornima ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Low Cost ◽  
Raw Material ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Adsorption Method ◽  
Chemically Modified ◽  
Adsorption Performance ◽  
Monolayer Adsorption ◽  
Isotherm Equations

The adsorption performance of sulphuric acid treated low cost adsorbent synthesized by using Citrus limettioides peel as an effective raw material for the removal of cadmium(II) from water. The batch adsorption method was carried out to optimize some parameters like contact time, pH and adsorbent dose. The nonlinear isotherm equations were used to calculate the different isotherm constant of five isotherm models namely Freundlich, Langmuir, Dubinin-Radushkevich, Redlich-Peterson and Sips. The Langmuir monolayer adsorption capacity of chemically modified Citrus limettioides peel was found to be 287.60 mg g-1. The negative values of ΔGº and ΔHº showed that the adsorption process is spontaneous and exothermic.

Biosorption of Cadmium onto Pseudomonas fluorescens: Application of Isotherm and Kinetic Models

2010 ◽  
Vol 171-172 ◽  
pp. 49-52 ◽  
Author(s):  
Chang Li Yu ◽  
Zhi Peng Lu ◽  
Fa Zhi Ge ◽  
Er Li Zhao
Keyword(s):  
Pseudomonas Fluorescens ◽  
Functional Groups ◽  
Metal Ion ◽  
Freundlich Isotherm ◽  
Industrial Effluents ◽  
Rate Equations ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Kinetics Of Adsorption ◽  
Isotherm And Kinetic Models

The present study was undertaken to evaluate the feasibility of Pseudomonas fluorescens biomass for the removal of cadmium ions from aqueous solutions. Batch experiments were performed to study the adsorption of cadmium on pH, Pseudomonas fluorescens biomass adsorbent with respect to initial Cd(II) concentration, contact time and biomass dose. The experimental data were modeled by Langmuir and Freundlich isotherm models. Langmuir model resulted in the best fit of the adsorption data. The maximum adsorption capacity for Cd(II) was 66.25 mg/g (pH 5.0 and 5 g/L biomass dose). Kinetics of adsorption followed second-order rate equations. The FTIR results of Pseudomonas fluorescens biomass showed that biomass has different functional groups and these functional groups are able to react with metal ion in aqueous solution. The results of the present study suggest that Pseudomonas fluorescens biomass can be used beneficially in treating industrial effluents containing heavy metal ions.

scholarly journals Application and Development of an Environmentally Friendly Blast Hole Plug for Underground Coal Mines

2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Donghui Yang ◽  
Yixin Zhao ◽  
Zhangxuan Ning ◽  
Zhaoheng Lv ◽  
Huafeng Luo
Keyword(s):  
Split Hopkinson Pressure Bar ◽  
Low Cost ◽  
Blast Hole ◽  
Environmentally Friendly ◽  
Test System ◽  
Industrial Test ◽  
Labor Intensity ◽  
Rock Blasting ◽  
Hopkinson Pressure Bar ◽  
The Impact

Drilling and blasting technology is one of the main methods for pressure relief in deep mining. The traditional method for blasting hole blockage with clay stemming has many problems, which include a large volume of transportation, excess loading time, and high labor intensity. An environmentally friendly blast hole plug was designed and developed. This method is cheap, closely blocks the hole, is quickly loaded, and is convenient for transportation. The impact test on the plug was carried out using an improved split Hopkinson pressure bar test system, and the industrial test was carried out in underground tunnel of coal mine. The tests results showed that, compared with clay stemming, the new method proposed in this paper could prolong the action time of the detonation gas, prevent premature detonation gas emissions, reduce the unit consumption of explosives, improve the utilization ratio, reduce the labor intensity of workers, and improve the effect of rock blasting with low cost of rock breaking.

Conductive 3D sponges for affordable and highly-efficient water purification

Nanoscale ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 4771-4778 ◽  
Author(s):  
Yanbiao Liu ◽  
Fang Li ◽  
Qin Xia ◽  
Jiawei Wu ◽  
Jianshe Liu ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Water Purification ◽  
Low Cost ◽  
Highly Efficient ◽  
Electro Oxidation ◽  
Conductive Nanomaterials ◽  
Filtration Device

We developed a low-cost method to achieve efficient organic pollutants degradation by incorporating conductive nanomaterials to assist electro-oxidation, leading to an efficient conductive nano-sponge filtration device.

LED Light Sources in Organic Synthesis: An Entry to A Novel Approach

2021 ◽  
Vol 18 ◽  
Author(s):  
Aparna Das
Keyword(s):  
Organic Compounds ◽  
Organic Synthesis ◽  
Photochemical Reaction ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Photochemical Reactions ◽  
Light Sources ◽  
Blue Led ◽  
Oxidation Reduction ◽  
Novel Approach

: In recent years, photocatalytic technology has shown great potential as a low-cost, environmentally friendly, and sustainable technology. Compared to other light sources in photochemical reaction, LEDs have advantages in terms of efficiency, power, compatibility, and environmentally-friendly nature. This review highlights the most recent advances in LED-induced photochemical reactions. The effect of white and blue LEDs in reactions such as oxidation, reduction, cycloaddition, isomerization, and sensitization is discussed in detail. No other reviews have been published on the importance of white and blue LED sources in the photocatalysis of organic compounds. Considering all the facts, this review is highly significant and timely.

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