scholarly journals Structural characteristics, analytical techniques and interactions with organic contaminants of dissolved organic matter derived from crop straw: a critical review

RSC Advances ◽  
2018 ◽  
Vol 8 (64) ◽  
pp. 36927-36938
Author(s):  
Bin Wang ◽  
Chang Liu ◽  
Yuwei Chen ◽  
Faqin Dong ◽  
Shu Chen ◽  
...  
Keyword(s):  
Organic Matter ◽  
Dissolved Organic Matter ◽  
Critical Review ◽  
Organic Contaminants ◽  
Structural Characteristics ◽  
Fate And Transport ◽  
Analytical Techniques ◽  
Crop Straw

Analytical techniques for structural characteristics of dissolved organic matter derived from crop straw (CDOM), and the effect of CDOM on the fate and transport of organic contaminants (OCs).

scholarly journals Photochemistry after fire: Structural transformations of pyrogenic dissolved organic matter elucidated by advanced analytical techniques

2020 ◽  
Vol 290 ◽  
pp. 271-292
Author(s):  
Aleksandar I. Goranov ◽  
Andrew S. Wozniak ◽  
Kyle W. Bostick ◽  
Andrew R. Zimmerman ◽  
Siddhartha Mitra ◽  
...  
Keyword(s):  
Organic Matter ◽  
Dissolved Organic Matter ◽  
Analytical Techniques ◽  
Structural Transformations

Effects of dissolved organic matter on sorption of benzotriazole to soil

2020 ◽  
Author(s):  
Lin Wu ◽  
Jin’e Dai ◽  
Erping Bi
Keyword(s):  
Molecular Weight ◽  
Organic Matter ◽  
Dissolved Organic Matter ◽  
Organic Contaminants ◽  
Low Molecular Weight ◽  
Sorption Equilibrium ◽  
Solution Ph ◽  
Environmental Behaviors ◽  
Unsaturated Zones ◽  
Molecular Weight Fractions

<p>Dissolved organic matter (DOM) plays an important role in affecting the environmental behaviors of organic contaminants. Effects of two representative DOMs (dissolved humic acid (HA) and tannic acid (TA)) on sorption of benzotriazole (BTA) to a reference soil were investigated by batch experiments. The results indicated that TA had stronger sorption to soil than HA (initial solution pH=6.0±0.1). This is because that TA contains more carboxylic and phenolic groups than those of HA. In the solution with DOM, the enhanced sorption of BTA was caused by cumulative sorption resulting from sorbed DOM. Hydrogen bonding was proposed as the main binding mechanism between BTA and the sorbed DOM. When the solution pH at sorption equilibrium increased from 6.5 to 10.5, the electrostatic repulsion inhibited the sorption of BTA in solution with/without HA. In addition, less hydrogren bonds made the effect of HA in promoting BTA sorption decrease when solution pH changed from 6.5 to 10.5. Higher molecular weight fractions of HA could be preferentially sorbed by the soil, its enhancement on BTA sorption was more obvious than that of the low molecular weight fractions. These findings are conducive to a better understanding of environmental behaviors of BTA as well as other organic compounds with similar structure in the unsaturated zones.</p>

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