scholarly journals Cost effective synthesis of p-type Zn-doped MgAgSb by planetary ball-milling with enhanced thermoelectric properties

RSC Advances ◽  
2018 ◽  
Vol 8 (62) ◽  
pp. 35353-35359 ◽  
Author(s):  
Yanyan Zheng ◽  
Chengyan Liu ◽  
Lei Miao ◽  
Hong Lin ◽  
Jie Gao ◽  
...  

Zn doped MgAgSb with improved purity and thermoelectric performance was synthesized via common planetary ball milling and spark plasma sintering.

2006 ◽  
Vol 415 (1-2) ◽  
pp. 251-256 ◽  
Author(s):  
Satoru Furuyama ◽  
Tsutomu Iida ◽  
Shinsuke Matsui ◽  
Masayasu Akasaka ◽  
Keishi Nishio ◽  
...  

2018 ◽  
Vol 281 ◽  
pp. 661-666
Author(s):  
Jia Lin Gao ◽  
Peng Liu ◽  
Jian Zhang ◽  
Xiao Dong Xu ◽  
Ding Yuan Tang

Zinc Selenide ceramic was successfully fabricated by spark plasma sintering in the study. The ZnSe raw powders were handled with two different methods such as grinding and planetary ball milling, respectively. The relative density, microstructure and transmittance of the ZnSe ceramic sintered under the same sintering parameter with two type powders was investigated. The results shown that the performance of the powder processed by ball milling was more effective than that by grinding. Furthermore, the maximum relative density can reach 99.8% when the ZnSe powder treated by ball milling were sintered at 950 oC for 30 min with the heating rate of 10 oC/min under 100 MPa.


2011 ◽  
Vol 415-417 ◽  
pp. 1291-1296 ◽  
Author(s):  
Yun Lu ◽  
Yusuke Matsuda ◽  
Katsuhiro Sagara ◽  
Liang Hao ◽  
Takahito Otomitsu ◽  
...  

In the present study, the TiO2-Ti compacts with Magneli phases TinO2n-1 were fabricated using the mixed powder of TiO2 powder and addition Ti powder by spark plasma sintering (SPS). The composition and the crystal types of Magneli phases TinO2n-1 were examined. The results showed that various Magneli phases TinO2n-1 (single or multi Magneli phases) with the composition of Ti1+yO2-x were obtained. The Magneli phases TinO2n-1 were formed in the transformation from the mother phase rutile TiO2 to TiO with increase in Ti addition fraction. In addition, the thermoelectric properties of the sintered compacts were also measured. The electrical resistivity of the sintered compacts decreased with increase in Ti addition fraction. The thermoelectric performance of the sintered compacts was improved by the formation of Magneli phases TinO2n-1 with the composition of Ti1+yO2-x.


2003 ◽  
Vol 793 ◽  
Author(s):  
Lidong Chen ◽  
Jun Jiang ◽  
Xun Shi

ABSTRACTThermoelectric performance of polycrystalline materials is greatly influenced by their microstructures including grain sizes, grain boundaries, grain orientations in anisotropic compounds, etc. The material microstructures are sensitive to the preparation processes and the starting materials. In the present study, n-type and p-type Bi2Te3-based sintered materials with highly preferred grain orientations have been fabricated through a spark plasma sintering (SPS) technique, by controlling the particle sizes of the starting powder and other sintering process parameters. The obtained textured Bi2Te3-based materials show a high mechanical strength as 80MPa in bending strength, which is 7 to 8 times as that of the melted ingot materials, and a significant anisotropy in thermoelectric transport properties. The optimal figure of merit (ZT) of the sintered materials in the direction perpendicular to the pressing direction (with c-axis preferred orientation) is comparable to that of the zone-melted ingots in the same crystallographic orientation.


2013 ◽  
Vol 06 (05) ◽  
pp. 1340006 ◽  
Author(s):  
JINGSHU XU ◽  
CHENGUANG FU ◽  
JIAN XIE ◽  
XINBING ZHAO ◽  
TIEJUN ZHU

The p-type skutterudite compounds of ( Pr 0.25 Nd 0.75)x Fe 3 CoSb 12 (x = 0.67–0.78) have been successfully synthesized by levitation melting followed by annealing and spark plasma sintering. The thermoelectric properties have been characterized by the measurements of Seebeck coefficient, electrical conductivity and thermal conductivity in the temperature range from 300 K to 850 K. The improvement in the thermoelectric properties was realized due to the reduction in the lattice thermal conductivity when the voids were partially filled by Pr 0.25 Nd 0.75. The maximum ZT value of ~ 0.83 for ( Pr 0.25 Nd 0.75)0.76 Fe 3 CoSb 12 was obtained at 700 K.


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